Seiya Ishizawa,Koki Fujimura,Kounosuke Oisaki et al.
Seiya Ishizawa et al.
Advancement of catalytic transformations in traditional synthetic organic chemistry have made significant impact on development of novel bioconjugation technologies. While a wide range of applications have become possible through catalytic ...
Sophie H Young,James S Andon,Jooyeon Lim et al.
Sophie H Young et al.
Metal-chelating noncanonical amino acids (ncAAs) are uniquely functional building blocks for proteins, peptide catalysts, and small molecule sensors. However, catalytic asymmetric approaches to synthesizing these molecules are hindered by t...
Exploiting Archaeal/Thermostable Enzymes in Synthetic Chemistry: Back to the Future? [0.03%]
考古菌/耐热酶在合成化学中的应用：面向未来而来？
Gaurav P Kudalkar,Virendra K Tiwari,David B Berkowitz
Gaurav P Kudalkar
Billions of years of evolution have led to the selection of (hyper)thermophiles capable of flourishing at elevated temperatures. The corresponding native (hyper)thermophilic enzymes retain their tertiary and quaternary structures at near-bo...
Griffin Stewart,Chris Rapala,Christian A Malapit
Griffin Stewart
Electrosynthesis represents a dynamic field in organic chemistry for the development of important and selective reactions. Among the most interesting electrosynthetic transformations is the non-directed arene C-H amination. Despite increasi...
Vitamin B12 in Photocatalysis - An Underexplored Frontier in Cooperative Catalysis [0.03%]
光催化中的维生素B12——协同催化中一个被忽视的前沿领域
Austin J Moser,Brian E Funk,Julian G West
Austin J Moser
Vitamin B12 (VB12) is a flexible and sustainable catalyst both in nature and the reaction flask, facilitating varied organic transformations of high value to both enzymatic processes and synthetic chemists. Key to this value is the breadth ...
Synergistic Effects of Silica-Supported Iron-Cobalt Catalysts for CO2 Reduction to Prebiotic Organics [0.03%]
负载铁-钴基催化剂催化二氧化碳还原制备生命前有机物中的协同效应研究
Kendra S Belthle,William F Martin,Harun Tüysüz
Kendra S Belthle
To test the ability of geochemical surfaces in serpentinizing hydrothermal systems to catalyze reactions from which metabolism arose, we investigated H2-dependent CO2 reduction toward metabolic intermediates over silica-supported Co-Fe cata...
Probing the Visible Light-Driven Geometrical Isomerization of 4-Arylbut-3-ene-2-amines [0.03%]
探究4-芳基丁-3-烯-2-胺的可见光驱动几何异构化反应
Timothy Schoch,Hannah Wyneken,Megan Despain et al.
Timothy Schoch et al.
A series of thirteen 4-arylbut-3-ene-2-amines were prepared and subjected to photosensitization experiments to interrogate their photostationary state (PS) composition of geometrical olefin isomers (E and Z). The amine PS compositions were ...
The Role of Water in Carbon Dioxide Adsorption in Porphyrinic Metal-Organic Frameworks [0.03%]
含水对金属有机框架材料中二氧化碳吸附行为的影响研究
Bettina Baumgartner,P Tim Prins,Jaap N Louwen et al.
Bettina Baumgartner et al.
Capturing and converting CO2 through artificial photosynthesis using photoactive, porous materials is a promising approach for addressing increasing CO2 concentrations. Porphyrinic Zr-based metal-organic frameworks (MOFs) are of particular ...
Supported Ionic Liquid Phase (SILP) Allylic Alkylation of Amines in Continuous Flow [0.03%]
连续流动下支链脂肪胺的 Supported Ionic Liquid Phase (SILP) 体系 allylic 基化反应
Kristof Stagel,Ádám Márk Pálvölgyi,Clémence Delmas et al.
Kristof Stagel et al.
We present the use of Pd-complex-containing supported ionic liquid phases (SILPs) as a novel approach for continuous-flow allylic alkylation of N-nucleophiles. This immobilization strategy gave simple access to air-tolerating catalyst frame...
Synthesis of Ketonylated Carbocycles via Excited-State Copper-Catalyzed Radical Carbo-Aroylation of Unactivated Alkenes [0.03%]
非活化烯烃的激发态铜催化自由基卡宾芳基化合成酮杂环化合物
Satavisha Sarkar,Arghya Banerjee,Ming-Yu Ngai
Satavisha Sarkar
Carbocycles are core skeletons in natural and synthetic organic compounds possessing a wide diversity of important biological activities. Herein, we report the development of an excited-state copper-catalyzed radical carbo-aroylation of una...