Mechanochemical Upcycling of Polyvinylidene Fluoride: Lewis Acid Induced Generation of Sodium Aluminium Fluorides [0.03%]
机械化学升级回收聚偏二氟乙烯：路易斯酸促进的氟化钠铝生成
Minh Bui,Jakob Bölle,Jörg Radnik et al.
Minh Bui et al.
A sustainable mechanochemical process for the generation of sodium aluminium fluorides by conversion of polyvinylidene fluoride (PVDF) waste on using ball milling in the presence of a Lewis acid was developed. The generated fluorides can be...
Fe─N5-Induced Coordination Engineering of Mo Single-Atom: Dual Sites Synergistically Enhancing Photocatalytic H2O2 Generation and Activation [0.03%]
铁-氮-five诱导的钼单原子配位工程：双活性位点协同增强光催化过氧化氢生成和活化
Tongjiao Yin,Fei He,Chao Wang et al.
Tongjiao Yin et al.
The photo-Fenton technique is a promising strategy for eliminating recalcitrant organic pollutants, coupling photocatalytic two-electron oxygen reduction (2e- ORR) for hydrogen peroxide (H2O2) generation with subsequent activation of H2O2 t...
1-Dodecyl-3-methylimidazolium bis(trifluoromethanesulfonyl) imide Interface Design for Stable and Effective Perovskite Solar Cells [0.03%]
用于稳定且有效的钙钛矿太阳能电池的1-十二烷基-3-甲基咪唑双(三氟甲烷磺酰亚胺)界面设计
Mengyao Guo,Jinxiong Wan,Jihuai Wu et al.
Mengyao Guo et al.
Power conversion efficiency (PCE) is limited by the high density of defects and poor energy level alignment of the SnO2/perovskite (PVK) buried interface in perovskite solar cells (PSCs). Herein, a synergistic molecular interface engineerin...
Thermal and Photocatalytic Conversion of CO2 to Ethanol: Advances in Catalyst Design, Challenges, and Opportunities [0.03%]
二氧化碳热解和光催化制乙醇：催化剂设计、挑战与机遇的最新进展
Bryan Rocano-Merchan,Alejandro Cañete-Arché,Asier Agrelo-Lestón et al.
Bryan Rocano-Merchan et al.
The transition toward a carbon-neutral energy system requires efficient strategies to convert CO2 into energy-dense liquid fuels capable of decarbonizing sectors where electrification remains impractical. Among emerging renewable synthetic ...
3D-Printed Platforms for Enzyme Immobilisation Screening and Direct Translation into Continuous-Flow Biocatalysis [0.03%]
用于酶固定化筛选和连续流动生物催化的3D打印平台直接转化
Simone Marchetti,Gianluca Palmara,Cristopher Tinajero et al.
Simone Marchetti et al.
The development of immobilised biocatalysts for continuous-flow processes is still largely based on laborious trial-and-error screening, and conditions optimised on conventional carriers are often not directly transferable to structured rea...
Mechanochemical Dehydrogenative Phenochalcogenazination: A Pronounced Water Effect [0.03%]
机械化学去氢化芳烃硫/硒化反应中的显著水效应
Alina Paffen,Calogero Quaranta,Kishor Gavhane et al.
Alina Paffen et al.
A mechanochemical phenochalcogenazination (X = O, S, Se) of phenols and related compounds in the ball mill is reported. The reaction proceeds without a catalyst, and the triarylamine-based products are obtained in up to 99% yield in 60 minu...
Tailoring Co-Catalysts in Pd Quantum-Dots-Functionalized BiFeO3 Nanorods for Enhanced Piezocatalytic Hydrogen Evolution Reaction [0.03%]
用于增强压电催化产氢反应的Pd量子点功能化BiFeO3纳米棒及其协同助催化剂的设计
Wenying Le,Jiale Zhou,Weirang Xu et al.
Wenying Le et al.
Piezocatalytic hydrogen evolution holds significant promise for addressing the global energy crisis by converting mechanical energy directly into chemical fuel. However, developing efficient noble-metal quantum-dot-functionalized piezocatal...
Recovery of Monoethanolammonium Acetate from Ionosolv Liquors Using a γ-Valerolactone-Based Aqueous Two-Phase System [0.03%]
采用γ-戊内酯基水包油型双溶剂体系从离子液中萃取单乙醇胺醋酸盐的研究
Sara Villarino,Victoria Rigual,Francisco Rodríguez et al.
Sara Villarino et al.
Ionic liquids (ILs) enable efficient lignin extraction in the Ionosolv process, but their sustainable implementation requires effective lignin recovery from IL extract to allow IL recycling. Conventional water-based precipitation of lignin ...
Bi/S Co-Doping of CeVO4 for Enhanced Photocatalytic Hydrogen Evolution: Insights into Multivalent Ce/V States and Oxygen Vacancies [0.03%]
通过Bi/S共掺杂CeVO4增强光催化产氢性能：多价态的Ce/V和氧空位的启示
Kening Xiang,Haoyu Wang,Yuhao Hong et al.
Kening Xiang et al.
Herein, a simple and environmentally benign synthetic strategy is developed to construct a hydrazine-regulated Bi/S co-doped CeVO4 trimetallic sulfur-oxide photocatalyst (Bi/S-CeVO4). The resulting material features abundant oxygen vacancy ...
Green Electrosynthesis of Formamide: CN Bond Construction From Plastic Waste and Ammonia [0.03%]
绿色合成甲酰胺：利用塑料废物和氨构建CN键
Kesheng Liu,Yue Li,Hugang Zhang et al.
Kesheng Liu et al.
Formamide is an essential chemical intermediate, yet its industrial synthesis remains fossil-dependent and energy-intensive. Here, we report an electrocatalytic route for directly synthesizing formamide from ammonia and ethylene glycol (EG)...