Electrocatalytic Hydrogenation of Pyrazine by Cu0.95Co2.05O4: Kinetics, Mechanism, and Performance [0.03%]
尖晶石Cu0.95Co2.05O4电催化吡嗪氢化的动力学、机制及性能研究
Xin Zheng,Siyi Chen,Hanyu Li et al.
Xin Zheng et al.
Hydrogen storage remains a key challenge for hydrogen utilization. Liquid organic hydrogen carriers (LOHCs) are promising, but their practical application is limited by the harsh conditions of conventional thermal catalysis. Electrochemical...
Ligand-Centered Redox Driven Zn(II)-Stabilized Azo-Anion Radical Enabled Dehydrogenative Synthesis of Azines and Quinoxalines [0.03%]
基于配体的氧化还原驱动的亚胺基阴离子自由基锌配合物用于叠氮𬭩化合物与芳胺脱氢合成偶氮化合物和喹唑啉类化合物反应的研究
Subhankar Khanra,Arjun Datta,Nanda Dulal Paul
Subhankar Khanra
Herein, we report a sustainable, one-pot synthetic strategy for the synthesis of aldazines, ketazines, and quinoxalines in air using a cheap, nontoxic, and air-stable Zn-catalyst (1) bearing a redox-active tridentate arylazo pincer, 2-(4-ch...
Biomimicking Haloperoxidase by Two-Dimensional V2O5 Nanosheets for Marine Antifouling Applications [0.03%]
模拟 haloperoxidase 的二维 V2O5 纳米片的海洋防污应用
Navya G Praveen,Mahesh M Lalitha,Jyotirmayee Sahoo et al.
Navya G Praveen et al.
Biofouling caused by the rapid formation of microbial biofilms on submerged surfaces poses severe economic and environmental challenges for the maritime industry. Conventional antifouling coatings, such as biocidal or silicon-based, face en...
Diverse Activation Modes for Ring Opening Reactions of Donor-Acceptor Cyclopropanes [0.03%]
供体-受体环丙烷开环反应的多样化活化模式研究
Diksha Bansal,Pooja Sivaganesan,Chibisree Elanchezhian et al.
Diksha Bansal et al.
Donor-acceptor cyclopropanes (DACs) have emerged as exceptionally powerful and versatile building blocks in modern synthetic chemistry, owing to the synergistic interplay of ring strain and vicinal electronic polarization. Upon suitable act...
An Efficient and Highly Stable Ruthenium-Based Organic Polymer Catalyst for CO2 Hydrogenation to Formate [0.03%]
一种高效的高稳定的钌系有机聚合物催化剂用于二氧化碳氢化制甲酸反应
Boyu Zhu,Xinrong Wang,Li Luo et al.
Boyu Zhu et al.
CO2 hydrogenation to formic acid is a high-atom-economy and environmentally friendly process. However, the short lifespan of current catalysts necessitates frequent replacement, generating significant solid waste and increasing energy costs...
Engineering Porphyrin Donor-Triazine Acceptor Frameworks From 5,10,15,20-Tetrakis(4-Cyanophenyl)Porphyrin for Electrochemical Applications [0.03%]
用于电化学应用的基于四（4-氰基苯基）卟啉的金属有机工程多孔材料捐赠者-三嗪受体框架
Aruntima Das,Arijit Maity,Sinthia Saha et al.
Aruntima Das et al.
The growing global population, limited resources, and increasing technological demands highlight the urgent need for advanced energy-storage solutions. In this context, designing covalent triazine-based frameworks (CTFs) at low temperature ...
Phase-Transition-Induced Fluorescence Changes in a Calamitic Liquid Crystal With an AIEgen Mesogen [0.03%]
具有AIE发光基元的 calamitics 液晶中的相变诱导荧光变化
Yuuto Iida,Riki Iwai,Hiroyuki Yoshida et al.
Yuuto Iida et al.
Aggregation-induced emission (AIE) luminogens have attracted considerable attention because of their environmental responsiveness. In particular, combining AIE with liquid crystals holds promise for multifunctional materials, but this area ...
Dual Macrocycle Strategy: CB[7]/CB[8] Encapsulation Unlocks Enhanced RTP in Aqueous Bromophenyl Pyridinium Cationic System [0.03%]
双大环策略：CB[7]/CB[8]包封在水相溴苯毗啶
Sk Samsul Ghaus,Mridusmita Nath,Bikram Das et al.
Sk Samsul Ghaus et al.
Developing efficient room-temperature phosphorescence (RTP) in aqueous, metal-free systems remains a significant challenge. This work demonstrates a supramolecular host-guest approach to activate and amplify RTP from a metal-free brominated...
From Sparse Nanoparticles to Graded Interfaces: Beyond Classical Descriptions of LiF Growth on Organic Semiconductors [0.03%]
从稀疏纳米粒子到梯度界面：有机半导体上LiF生长的经典描述超越
Pedro Oliviera,Felix Maye,Ayse Turak
Pedro Oliviera
Small-molecule π $/pi$ -conjugated semiconductors provide an ordered platform for probing interfacial mechanisms in organic optoelectronics, where device performance and stability are dominated by interface effects. Lithium fluoride, ...
Exploration of Spectrodynamic Behavior of a Naphthalene-Based Schiff Base (E)-2-((Naphthalen-1-ylimino)methyl)-4-nitrophenol: Synergistic Effects of ESIPT and Excimers [0.03%]
萘并希夫碱(E)-2-((萘-1-亚氨基)甲基)-4-硝基苯酚的光谱动力学行为研究：ESIPT与excimer的协同效应
Akash Das,Nikhil Guchhait
Akash Das
Excited-state intramolecular proton transfer (ESIPT) and excimer formation are unimolecular and bimolecular reactions, respectively. It is not frequent to observe coupling between these two excited-state processes. In this work, we have sho...