Recent advances in the electrochemical synthesis of organophosphorus compounds [0.03%]
有机磷化合物电化学合成研究进展
Babak Kaboudin,Milad Behroozi,Sepideh Sadighi et al.
Babak Kaboudin et al.
In this review, we describe recent advances in electrochemical green methods for the synthesis of various organophosphorus compounds through the formation of phosphorus-carbon, phosphorus-nitrogen, phosphorus-oxygen, phosphorus-sulfur, and ...
Carbon-rich materials: from polyaromatic molecules to fullerenes and other carbon allotropes [0.03%]
富碳材料：从聚芳香烃分子到富勒烯及其他碳同素异形体
Hiroko Yamada,Yoko Yamakoshi
Hiroko Yamada
Radovan Šebesta
Radovan Šebesta
Regioselective formal hydrocyanation of allenes: synthesis of β,γ-unsaturated nitriles with α-all-carbon quaternary centers [0.03%]
全碳四次代饱和β,γ-不饱和腈的区域选择性合成
Seeun Lim,Teresa Kim,Yunmi Lee
Seeun Lim
This study introduces a highly selective hydrocyanation method based on copper-catalyzed hydroalumination of allenes with diisobutylaluminum hydride, followed by the regio- and stereoselective allylation with p-toluenesulfonyl cyanide. The ...
Development and mechanistic studies of calcium-BINOL phosphate-catalyzed hydrocyanation of hydrazones [0.03%]
手性磷酸钙催化异腈的羟氰化反应的发展及机理研究
Carola Tortora,Christian Andreas Fischer,Sascha Kohlbauer et al.
Carola Tortora et al.
Asymmetric hydrocyanation of hydrazones, catalyzed by a calcium-BINOL phosphate complex, has been studied for the first time both experimentally and computationally with DFT methods. A full catalytic cycle for the enantioselective synthesis...
Synthesis of HBC fluorophores with an electrophilic handle for covalent attachment to Pepper RNA [0.03%]
用于与Pepper RNA共价连接的HBC荧光团的亲电手柄合成
Raphael Bereiter,Ronald Micura
Raphael Bereiter
The fluorescent light-up aptamer (FLAP) Pepper can utilize fluorophores that are equipped with an electrophilic handle for the covalent attachment of the surrogate to the RNA. The resulting irreversibly tethered dye-RNA complexes have opene...
Orthogonal photoswitching of heterobivalent azobenzene glycoclusters: the effect of glycoligand orientation in bacterial adhesion [0.03%]
异生物瓣苯甘露聚糖簇的正交光切换：糖配体取向对细菌粘附的影响
Leon M Friedrich,Thisbe K Lindhorst
Leon M Friedrich
Carbohydrate recognition is fundamental to a plethora of cellular processes and hence the elucidation of the structural determinants of the recognition process is a prerequisite for understanding and manipulating carbohydrate-protein intera...
Copper-catalyzed domino cyclization of anilines and cyclobutanone oxime: a scalable and versatile route to spirotetrahydroquinoline derivatives [0.03%]
铜催化苯胺和环丁酮肟串联环化反应：螺四氢喹啉衍生物的大规模合成及其多样性展示
Qingqing Jiang,Xinyi Lei,Pan Gao et al.
Qingqing Jiang et al.
In this study, we report the copper-catalyzed synthesis of tetrahydroquinoline derivatives via a domino reaction of aniline with cyclobutanone oxime. This method demonstrates a selective approach for generating bioactive tetrahydroquinoline...
Christian Akakpo,Peter Y Zavalij,Lyle Isaacs
Christian Akakpo
We report the synthesis and characterization of a new acyclic cucurbit[n]uril (CB[n]) host C1 that features four alkyl sulfate ionic groups. The X-ray crystal structure of the C1·Me 6 CHDA complex is reported. Host C1 is significantly less...
Origami with small molecules: exploiting the C-F bond as a conformational tool [0.03%]
分子折纸术：利用氟碳键作为构象工具
Patrick Ryan,Ramsha Iftikhar,Luke Hunter
Patrick Ryan
When present within an organic molecule, the C-F bond tends to align in predictable ways with neighbouring functional groups, due to stereoelectronic effects such as hyperconjugation and electrostatic attraction/repulsion. These fluorine-de...