Daniela M Arias-Rotondo
Daniela M Arias-Rotondo
Quentin Dherbassy,Kamila B Muchowska
Quentin Dherbassy
Trisubstituted triumph [0.03%]
三取代成就
Damian W Young,Srinivas Chamakuri
Damian W Young
Deep learning study of tyrosine reveals that roaming can lead to photodamage [0.03%]
基于深度学习的酪氨酸研究发现游离基会导至光损伤现象
Julia Westermayr,Michael Gastegger,Dóra Vörös et al.
Julia Westermayr et al.
Amino acids are among the building blocks of life, forming peptides and proteins, and have been carefully 'selected' to prevent harmful reactions caused by light. To prevent photodamage, molecules relax from electronic excited states to the...
Low-valent tungsten redox catalysis enables controlled isomerization and carbonylative functionalization of alkenes [0.03%]
低价钨红氧化还原催化剂实现烯烃的可控异构化及羰基化官能团化反应
Tanner C Jankins,William C Bell,Yu Zhang et al.
Tanner C Jankins et al.
The controlled isomerization and functionalization of alkenes is a cornerstone achievement in organometallic catalysis that is now widely used throughout industry. In particular, the addition of CO and H2 to an alkene, also known as the oxo...
Sarah E Jenny,Graham E Dobereiner
Sarah E Jenny
O-GlcNAcylation modulates liquid-liquid phase separation of SynGAP/PSD-95 [0.03%]
O-GlcNAc酰化调控SynGAP/PSD-95液-液相分离
Pinou Lv,Yifei Du,Changdong He et al.
Pinou Lv et al.
Liquid-liquid phase separation (LLPS) of SynGAP and PSD-95, two abundant proteins that interact in the postsynaptic density (PSD) of neurons, has been implicated in modulating SynGAP PSD enrichment in excitatory synapses. However, the under...
Mechanism-based ligand design for copper-catalysed enantioconvergent C(sp3)-C(sp) cross-coupling of tertiary electrophiles with alkynes [0.03%]
基于机制的配体设计在铜催化三级亲电试剂与炔烃交叉偶联反应中的应用研究
Fu-Li Wang,Chang-Jiang Yang,Ji-Ren Liu et al.
Fu-Li Wang et al.
In contrast with the well-established enantioconvergent radical C(sp3)-C cross-coupling of racemic secondary alkyl electrophiles, the corresponding coupling of tertiary electrophiles to forge all-carbon quaternary stereocentres remains unde...
Malte Oppermann,Francesco Zinna,Jérôme Lacour et al.
Malte Oppermann et al.
Iron-based spin-crossover complexes hold tremendous promise as multifunctional switches in molecular devices. However, real-world technological applications require the excited high-spin state to be kinetically stable-a feature that has bee...
Michael G Howlett,Anthonius H J Engwerda,Robert J H Scanes et al.
Michael G Howlett et al.
A key goal of chemistry is to develop synthetic systems that mimic biology, such as self-assembling, self-replicating models of minimal life forms. Oscillations are often observed in complex biological networks, but oscillating, self-replic...