Solvent-bridged electrolytes for high-energy Li-ion batteries under extreme conditions [0.03%]
溶剂桥接电解质在高能量密度锂电池中的应用研究
Yawei Chen,Fanyang Huang,Qiu Zhang et al.
Yawei Chen et al.
High-capacity anodes are desirable for high-energy lithium-ion batteries but suffer from limited cycle life due to large volume changes during cycling. The LiF-based solid-electrolyte interphase (SEI) has led to prolonged cycling stability....
Deciphering the infrared spectrum of the hydrated proton using full-dimensional quantum dynamics [0.03%]
利用全维量子动力学解密水合质子的红外光谱
David Mendive-Tapia,Christoph Schran,Banshi Das et al.
David Mendive-Tapia et al.
The nature of the aqueous proton has been traditionally interpreted through two limiting structural motifs: the Zundel and Eigen cations. However, experimental infrared (IR) spectra of the solvated proton reveal a far more dynamic character...
A versatile strategy for oligonucleotide functionalization via on-support phosphitylation [0.03%]
一种通过支载体磷化实现寡核苷酸官能化的通用策略
Ayan Dasgupta,Sebastian Golojuch,Li Xiao et al.
Ayan Dasgupta et al.
Chemically modified nucleic acids such as antisense oligonucleotides, small interfering RNA and CRISPR guide RNA have emerged as transformative modalities in modern medicine, providing new strategies for the treatment of genetic and metabol...
Xueliang Shi,Hai-Bo Yang
Xueliang Shi
Highly chemoselective access to alkyl-sulfur compounds via N2 extrusion of alkyl hydrazines [0.03%]
通过肼的N₂释放高化学选择性地获得含硫化合物的新方法
Shuanghu Wang,David A Cagan,Jet Tsien et al.
Shuanghu Wang et al.
Sulfur(VI)-containing functional groups, such as sulfonamides, sulfinates and sulfonyl fluorides, are ubiquitous in pharmaceuticals, where they confer unique physicochemical properties that enhance metabolic stability, solubility and bioact...
A photogenerated triplet aura-nitrene for gold-mediated nitrene transfer [0.03%]
通过金介导的氮烯转移生成光生三重态aura-氮烯
Jaime Martín,Marc Fernández-Sabaté,Bernhard Spingler et al.
Jaime Martín et al.
The isolation and characterization of metal-stabilized, low-valent nitrogen species remain central challenges in advancing nitrogen-atom transfer chemistry. Although gold has emerged as a powerful catalyst in C-N bond formation, proposed me...
Søren S Sørensen,Morten M Smedskjaer
Søren S Sørensen
John A Milligan,Robert J Monroe
John A Milligan