Mikhail V Vaganov,Nicolas Suaud,François Lambert et al.
Mikhail V Vaganov et al.
Controlling quantum spins using electric rather than magnetic fields promises substantial architectural advantages for developing quantum technologies. In this context, spins in molecular magnets offer tunability of spin-electric couplings ...
Electrostatic atlas of non-covalent interactions built into metal-organic frameworks [0.03%]
基于金属有机骨架的非共价相互作用静电图谱
Zhe Ji,Srijit Mukherjee,Jacopo Andreo et al.
Zhe Ji et al.
Non-covalent interactions are central to the organization of matter and molecular recognition processes, yet they are difficult to characterize. Here we devise a platform strategy to systematically build non-covalent interactions with selec...
Unlocking azole chemical space via modular and regioselective N-alkylation [0.03%]
模块化和区域选择性N烷基化解锁唑类化学空间
Céline Dorval,Adrian D Matthews,Karina Targos et al.
Céline Dorval et al.
Azoles are important synthetic targets due to their diverse applications in areas ranging from human health to food security. Accordingly, access to N-functionalized azoles is an essential goal in modern synthetic chemistry. Surprisingly, h...
Mathis Brändlin,Björn Pfund,Oliver S Wenger
Mathis Brändlin
Photochemistry involves elementary steps in which single electrons are transferred, but artificial photosynthesis requires multi-electron reactions. This discrepancy necessitates light-driven charge accumulation, which has so far proved ver...
He Li,Dan Zhao
He Li
Feifei Xiang,Yanwei Gu,Amogh Kinikar et al.
Feifei Xiang et al.
Graphene nanoribbons (GNRs) with zigzag edges are promising materials for spintronic devices due to tunable bandgaps and spin-polarized edge states. Porphyrins offer complementary benefits such as desirable optoelectronic properties. Here w...
Shaotang Song,Jiong Lu
Shaotang Song
Vibronic coupling-driven symmetry breaking and solvation in the photoexcited dynamics of quadrupolar dyes [0.03%]
四极染料光激发动力学中的振动耦合驱动的对称性破缺和溶剂效应
Katrin Winte,Somayeh Souri,Daniel C Lünemann et al.
Katrin Winte et al.
Quadrupolar dyes, such as acceptor-donor-acceptor molecules, are highly relevant for applications in nonlinear optics and photovoltaics. They are also versatile models for exploring photoinduced charge-transfer dynamics. The interplay betwe...
An unnatural base pair for the detection of epigenetic cytosine modifications in DNA [0.03%]
一种用于检测DNA中表观遗传胞嘧啶修饰的非天然碱基对
David Schmidl,Sidney M Becker,James M Edgerton et al.
David Schmidl et al.
Natural, covalently modified cytosine bases within genomic DNA function as important epigenetic markers. Approaches for single-base-resolution sequencing of cytosine modifications typically deploy chemistry for modification-selective C-to-T...
Nucleoside diphosphate kinase A (NME1) catalyses its own oligophosphorylation [0.03%]
核苷二磷酸激酶A（NME1）催化其自身的寡聚磷酸化
Arif Celik,Felix Schöpf,Christian E Stieger et al.
Arif Celik et al.
Protein phosphorylation is a central signalling mechanism in eukaryotic cells. The scope of this post-translational modification includes protein pyro- and polyphosphorylation. Here we report the discovery of another mode of phosphorylation...