Catalytic and stoichiometric stepwise conversion of side-on bound dinitrogen to ammonia mediated by a uranium complex [0.03%]
一个铀配合物催化和定量地将端位键合的氮气逐步转化为氨
Mikhail S Batov,Heather T Partlow,Lucile Chatelain et al.
Mikhail S Batov et al.
The well-defined catalytic conversion of dinitrogen (N2) to ammonia (NH3) by molecular complexes is of fundamental interest and important for providing an atomic-level understanding of reactivity that can be related to industrial and biolog...
The biophysical requirements that govern the efficient endosomal escape of designed mini-proteins [0.03%]
调控设计型迷你蛋白有效逃逸内体的生物物理需求
Jonathan Giudice,Daniel D Brauer,Madeline Zoltek et al.
Jonathan Giudice et al.
The ZF5.3 mini-protein escapes endosomes efficiently to guide proteins into the cytosol and/or nucleus. However, other than the requirement for small or unfoldable cargo and an intact HOPS complex, little is known about how ZF5.3 traverses ...
Davide Zanetti,Cristian De Luca,Davide Bonifazi
Davide Zanetti
Metal-centred states control carrier lifetimes in transition metal oxide photocatalysts [0.03%]
金属掺杂态控制过渡金属氧化物光催化剂的载流子寿命
Michael Sachs,Liam Harnett-Caulfield,Ernest Pastor et al.
Michael Sachs et al.
Efficient sunlight-to-energy conversion requires materials that can generate long-lived charge carriers upon illumination. However, the targeted design of semiconductors possessing intrinsically long lifetimes remains a key challenge. Here ...
Homotypic RNA clustering accompanies a liquid-to-solid transition inside the core of multi-component biomolecular condensates [0.03%]
同型RNA聚集伴随多成分生物分子凝聚体内核从液态到固态的转变
Tharun Selvam Mahendran,Gable M Wadsworth,Anurag Singh et al.
Tharun Selvam Mahendran et al.
RNA-driven condensation plays a central role in organizing and regulating ribonucleoprotein granules within cells. Disruptions to this process-such as the aberrant aggregation of repeat-expanded RNA-are associated with numerous neurological...
Florian R Neururer,Stephan Hohloch
Florian R Neururer
Mechanochemical pathway for converting fluoropolymers to fluorochemicals [0.03%]
用于将氟化聚合物转化为氟化学物质的机械化学途径
Masashi Hattori,Debarshi Saha,Muhamad Zulfaqar Bacho et al.
Masashi Hattori et al.
The growing demand for fluorochemicals has increased the production of toxic hydrogen fluoride (HF)-a widely used fluorination agent-from mineral fluorspar (CaF2). Although potassium fluoride (KF) is a safer alternative fluorination agent, ...
Expedited access to polyunsaturated fatty acids and biofunctional analogues by full solid-phase synthesis [0.03%]
全固相合成方法快速获取多不饱和脂肪酸及生物活性类似物
Yutaro Saito,Mayuko Akita,Azusa Saika et al.
Yutaro Saito et al.
Polyunsaturated fatty acids (PUFAs) represent a fundamental and essential class of lipids that exhibit versatile biofunctions. Lipidomic analysis has identified a growing number of lipid species, including PUFAs with diverse structural vari...
Adaptive dynamic kinetic resolution enables alteration of chiral induction with ring sizes [0.03%]
自适应动态动力学拆分使手性诱导的环大小改变成为可能
Bangkui Yu,Yao Huang,Haocheng Zhang et al.
Bangkui Yu et al.
Dynamic kinetic resolution (DKR) is an efficient chiral induction strategy that transforms both enantiomers of the substrate racemates into the same optically enriched product. Typically, the absolute configurations of the products should b...
Sabina J Maurer,Monica E McCallum
Sabina J Maurer