Synthesis of polysubstituted azepanes by dearomative ring expansion of nitroarenes [0.03%]
通过硝基芳香族化合物的脱芳环扩环合成多取代氮杂环庚烷
Rory Mykura,Raquel Sánchez-Bento,Esteban Matador et al.
Rory Mykura et al.
The synthesis of functionalized nitrogen heterocycles is integral to discovering, manufacturing and evolving high-value materials. The availability of effective strategies for heterocycle synthesis often biases the frequency of specific rin...
Ludek Sehnal,Libera Lo Presti,Nadine Ziemert
Ludek Sehnal
Ten-electron count rule for the binding of adsorbates on single-atom alloy catalysts [0.03%]
单原子合金催化剂上吸附物结合的十电子规则
Julia Schumann,Michail Stamatakis,Angelos Michaelides et al.
Julia Schumann et al.
Single-atom alloys have recently emerged as highly active and selective alloy catalysts. Unlike pure metals, single-atom alloys escape the well-established conceptual framework developed nearly three decades ago for predicting catalytic per...
Adrian Saura-Sanmartin
Adrian Saura-Sanmartin
Spotlights on blind spots [0.03%]
盲点聚焦
Bruce C Gibb
Bruce C Gibb
Joshua J Woods,Rebecca J Abergel
Joshua J Woods
Kai Wu,Elie Benchimol,Ananya Baksi et al.
Kai Wu et al.
Self-assembled hosts, inspired by biological receptors and catalysts, show application potential in sustainable synthesis, energy conversion and medicine. Implementing multiple functionalities in the form of distinguishable building blocks,...
Guanwei Zhang,Ting F Zhu
Guanwei Zhang
The development of mirror-image biology systems and related applications is hindered by the lack of effective methods to sequence mirror-image (D-) proteins. Although natural-chirality (L-) proteins can be sequenced by bottom-up liquid chro...
James A Bull
James A Bull
Asymmetric synthesis of sulfoximines, sulfonimidoyl fluorides and sulfonimidamides enabled by an enantiopure bifunctional S(VI) reagent [0.03%]
手性S(VI)试剂促进的亚磺酰亚胺，亚磺酰氟和磺二酰胺的不对称合成
Shun Teng,Zachary P Shultz,Chuan Shan et al.
Shun Teng et al.
An increased interest to expand three-dimensional chemical space for the design of new materials and medicines has created a demand for isosteric replacement groups of commonly used molecular functionality. The structural and chemical prope...