Thorium(IV)-antimony complexes exhibiting single, double, and triple polar covalent metal-metal bonds [0.03%]
具有单重，双重和三重重极共价金属-金属键的四价钍-锑配合物
Jingzhen Du,Kevin Dollberg,John A Seed et al.
Jingzhen Du et al.
There is continued burgeoning interest in metal-metal multiple bonding to further our understanding of chemical bonding across the periodic table. However, although polar covalent metal-metal multiple bonding is well known for the d and p b...
A catalytic process enables efficient and programmable access to precisely altered indole alkaloid scaffolds [0.03%]
催化过程实现对精确修饰的吲哚生物碱骨架的有效和可编程访问
Youming Huang,Xinghan Li,Binh Khanh Mai et al.
Youming Huang et al.
A compound's overall contour impacts its ability to elicit biological response, rendering access to distinctly shaped molecules desirable. A natural product's framework can be modified, but only if it is abundant and contains suitably modif...
Highly entangled polyradical nanographene with coexisting strong correlation and topological frustration [0.03%]
高纠缠多自由基纳米石墨烯中强关联与拓扑挫败现象共存
Shaotang Song,Andrés Pinar Solé,Adam Matěj et al.
Shaotang Song et al.
Open-shell nanographenes exhibit unconventional π-magnetism arising from topological frustration or strong electron-electron interaction. However, conventional design approaches are typically limited to a single magnetic origin, which can ...
A metal-catalysed functional group metathesis approach to the carbon isotope labelling of carboxylic acids [0.03%]
用于羧酸碳同位素标记的金属催化的官能团甲酰酯交换方法
R Garrison Kinney,José Zgheib,Pierre-Louis Lagueux-Tremblay et al.
R Garrison Kinney et al.
The distribution, metabolism and ultimate fate of molecules within the body is central to the activity of pharmaceuticals. However, the introduction of radioisotopes into the metabolically stable carbon sites on drugs to probe these feature...
Maja A Dunstan,Anna S Manvell,Nathan J Yutronkie et al.
Maja A Dunstan et al.
The inimitable electronic structures of the lanthanide (Ln) ions are key to advanced materials and technologies involving these elements. The trivalent ions are ubiquitous and are used much more widely than the divalent and tetravalent anal...
Rosemary J Goodwin,Nicholas G White
Rosemary J Goodwin
Diazobutanone-assisted isobaric labelling of phospholipids and sulfated glycolipids enables multiplexed quantitative lipidomics using tandem mass spectrometry [0.03%]
二氮杂丁酮辅助的等压标记磷脂和硫酸糖脂可实现使用串联质谱进行多路复用定量脂质组学分析
Ting-Jia Gu,Peng-Kai Liu,Yen-Wen Wang et al.
Ting-Jia Gu et al.
Mass spectrometry-based quantitative lipidomics is an emerging field aiming to uncover the intricate relationships between lipidomes and disease development. However, quantifying lipidomes comprehensively in a high-throughput manner remains...
A divergent intermediate strategy yields biologically diverse pseudo-natural products [0.03%]
发散的中间策略产生生物多样性的伪天然产物
Sukdev Bag,Jie Liu,Sohan Patil et al.
Sukdev Bag et al.
The efficient exploration of biologically relevant chemical space is essential for the discovery of bioactive compounds. A molecular design principle that possesses both biological relevance and structural diversity may more efficiently lea...
Author Correction: Chemoselective umpolung of thiols to episulfoniums for cysteine bioconjugation [0.03%]
作者更正：选择性颠倒硫醇的化学性质生成环氧硫酸盐，以实现半胱氨酸生物偶联反应
Philipp Hartmann,Kostiantyn Bohdan,Moritz Hommrich et al.
Philipp Hartmann et al.
Published Erratum
Nature chemistry. 2024 Mar;16(3):476. DOI:10.1038/s41557-024-01475-3 2024
Patrick R Melvin
Patrick R Melvin