Bruce C Gibb
Bruce C Gibb
Nina M Allen,Guilherme A Marczak Giorio,M Carmen Galan
Nina M Allen
Tobias Randt,Morten Lehmann,Elisabeth Irran et al.
Tobias Randt et al.
The existence and intermediacy of halogen-substituted silylium ions have been the subject of speculation for decades. These elusive reactive intermediates are synthetically attractive because of their computationally predicted super Lewis a...
Flame synthesis achieves compositionally tailorable high-entropy metal-containing nanomaterials [0.03%]
火焰合成实现高熵金属纳米材料的组成可调性
Zhen Liu,Eirini Goudeli,Rui Guo et al.
Zhen Liu et al.
High-entropy metal-containing nanomaterials have garnered interest in diverse fields such as electrocatalysis and energy conversion. Their synthesis typically requires high temperatures (>1,000 K) to facilitate homogeneous mixing and rapid ...
Sandeep Kumar,Kanishk Tomer,Priyabrata Ghana
Sandeep Kumar
Bright triplet and bright charge-separated singlet excitons in organic diradicals enable optical read-out and writing of spin states [0.03%]
有机双自由基中的亮三重态和亮电荷分离单重激发子实现自旋状态的光读出和写入
Rituparno Chowdhury,Petri Murto,Naitik A Panjwani et al.
Rituparno Chowdhury et al.
Optical control of electron spin states is important for quantum sensing and computing applications, as developed with the diamond nitrogen vacancy centre. This requires electronic excitations, excitons, with net spin. Here we report a mole...
Bradley W Gardner,Gojko Lalic
Bradley W Gardner
Organoboron compounds are important intermediates in organic synthesis, commonly used in metal-catalysed cross-coupling reactions. Their unique reactivity also allows modifications of their carbon framework with preservation of the valuable...
Introducing metal-sulfur active sites in metal-organic frameworks via post-synthetic modification for hydrogenation catalysis [0.03%]
通过金属有机框架的后合成修饰引入金属-硫活性位点用于氢化催化
Haomiao Xie,Milad Ahmadi Khoshooei,Mukunda Mandal et al.
Haomiao Xie et al.
Metal-sulfur active sites play a central role in catalytic processes such as hydrogenation and dehydrogenation, yet the majority of active sites in these compounds reside on the surfaces and edges of catalyst particles, limiting overall eff...