Reaction-induced unsaturated Mo oxycarbides afford highly active CO2 conversion catalysts [0.03%]
反应诱导的不饱和钼氧碳化物具有很高的二氧化碳转化催化性能
Xingtao Sun,Jiafeng Yu,Habib Zada et al.
Xingtao Sun et al.
Sustainable CO2 conversion is crucial in curbing excess emissions. Molybdenum carbide catalysts have demonstrated excellent performances for catalytic CO2 conversion, but harsh carburization syntheses and poor stabilities make studies chall...
Shengchun Wang,Xu Luo,Yuan Wang et al.
Shengchun Wang et al.
Multi-site functionalization of molecules provides a potent approach to accessing intricate compounds. However, simultaneous functionalization of the reactive site and the inert remote C(sp3)-H poses a formidable challenge, as chemical reac...
Zinc and manganese redox potentials in organic solvents and their influence on nickel-catalysed cross-electrophile coupling [0.03%]
有机溶剂中的锌和锰的氧化还原电位及其对镍催化交叉亲电子偶联的影响
Zhi-Ming Su,Ruohan Deng,Shannon S Stahl
Zhi-Ming Su
Zinc and manganese are widely used as reductants in synthetic methods, such as nickel-catalysed cross-electrophile coupling (XEC) reactions, but their redox potentials are unknown in organic solvents. Here we show how open-circuit potential...
Allan Blackman
Allan Blackman
Fullerene on non-iron cluster-matrix co-catalysts promotes collaborative H2 and N2 activation for ammonia synthesis [0.03%]
富勒烯修饰非铁系聚簇-载体共催化体系促进氨合成氢活化与氮活化的协同作用
Yangyu Zhang,Xuanbei Peng,Han-Rui Tian et al.
Yangyu Zhang et al.
Developing highly effective catalysts for ammonia (NH3) synthesis is a challenging task. Even the current, prevalent iron-derived catalysts used for industrial NH3 synthesis require harsh reaction conditions and involve massive energy consu...
The eponymous ethyl alcohol [0.03%]
同名乙醇
Chi Chen,Mahlet Garedew,Stafford W Sheehan
Chi Chen
Balancing volumetric and gravimetric capacity for hydrogen in supramolecular crystals [0.03%]
超分子晶体中氢的体积容量与质量容量的平衡
Ruihua Zhang,Hilal Daglar,Chun Tang et al.
Ruihua Zhang et al.
The storage of hydrogen is key to its applications. Developing adsorbent materials with high volumetric and gravimetric storage capacities, both of which are essential for the efficient use of hydrogen as a fuel, is challenging. Here we rep...
Publisher Correction: Collisional alignment and molecular rotation control the chemi-ionization of individual conformers of hydroquinone with metastable neon [0.03%]
出版更正：碰撞整编和分子旋转控制了对苯二酚个别构象与亚稳态氖的化学离子化过程
L Ploenes,P Straňák,A Mishra et al.
L Ploenes et al.
Published Erratum
Nature chemistry. 2024 Nov;16(11):1915. DOI:10.1038/s41557-024-01644-4 2024
Chemoproteomic profiling unveils binding and functional diversity of endogenous proteins that interact with endogenous triplex DNA [0.03%]
化学蛋白质组学剖析揭示内源性三链DNA相互作用的内源性蛋白及其结合和功能多样性
Hongzhan Xu,Jing Ye,Kui-Xing Zhang et al.
Hongzhan Xu et al.
Triplex DNA structures, formed when a third DNA strand wraps around the major groove of DNA, are key molecular regulators and genomic threats. However, the regulatory network governing triplex DNA dynamics remains poorly understood. Here we...
A metalloenzyme platform for catalytic asymmetric radical dearomatization [0.03%]
一种用于催化不对称自由基去芳香化的金属酶平台
Wenzhen Fu,Yue Fu,Yunlong Zhao et al.
Wenzhen Fu et al.
Catalytic asymmetric dearomatization represents a powerful means to convert flat aromatic compounds into stereochemically well-defined three-dimensional molecular scaffolds. Using new-to-nature metalloredox biocatalysis, we describe an enzy...