An accurate and efficient framework for modelling the surface chemistry of ionic materials [0.03%]
一种模拟离子材料表面化学的精确而高效的框架
Benjamin X Shi,Andrew S Rosen,Tobias Schäfer et al.
Benjamin X Shi et al.
Quantum-mechanical simulations can offer atomic-level insights into chemical processes on surfaces that are crucial to advancing applications in heterogeneous catalysis, energy storage and greenhouse gas sequestration. Unfortunately, achiev...
Reversible fluorenol photobases that perform CO2 capture and concentration from ambient air [0.03%]
可逆的荧烯醇光碱，从空气中捕获和浓缩二氧化碳
Michael Purdy,Ariel Y Wang,Matthew C Drummer et al.
Michael Purdy et al.
Leading strategies for the capture of CO2 from point sources and directly from the atmosphere face high energy costs for thermal sorbent regeneration. Photochemical processes, driven by sunlight as the sole external stimulus, offer a promis...
Polymer connectivity governs electrophotocatalytic activity in the solid state [0.03%]
固态聚合物连接决定电光催化活性
Jianheng Ling,Amy L Vonder Haar,Kiser Z Colley et al.
Jianheng Ling et al.
The reductive functionalization of inert substrates such as chloroarenes is a critical yet challenging transformation relevant to both environmental remediation and organic synthesis. Combining electricity and light is an emerging strategy ...
Quantitative profiling of lipid transport between organelles enabled by subcellular photocatalytic labelling [0.03%]
亚细胞光催化标记支持的脂质运输的定量分析
Xi Chen,Ru He,Haolin Xiong et al.
Xi Chen et al.
Subcellular lipid composition and transport substantially influence the physiological and pathological functions of both cells and organelles. However, lipid transport and turnover between organelles remain poorly understood due to a lack o...
Immobilized acyl-transfer molecular reactors enable the solid-phase synthesis of sterically hindered peptides [0.03%]
固相合成位阻肽的酰基转移分子反应器的固定化
Siyuan Wei,Xuchun Zhang,Xiaoliang Yang et al.
Siyuan Wei et al.
Incorporating unnatural amino acids, such as hindered N-methylated or α,α-disubstituted amino acid(s), into peptides can improve their properties for application in the pharmaceutical and biomedical fields. However, the current solid-phas...
Zhen Li,Deguang Liu,Gen-Wei Gao et al.
Zhen Li et al.
The escape from flat aromatic architectures towards saturated structures enriched with an increased proportion of sp3 atoms (Fsp3) has been harnessed as a drug design strategy. Chemical synthesis of drug-like saturated cycloalkanes, particu...
Panpan Ma,Zhangkai Cui,Hongjian Lu
Panpan Ma
Primary aliphatic amines are essential components in numerous functional molecules and rank among the most readily available commercial building blocks. Although commonly utilized as nitrogen nucleophiles, their application as alkyl sources...
Synthesis of zero-dimensional octahedral metal halides through solvent incorporation and their photophysical properties [0.03%]
溶剂嵌入法制备零维八面体金属卤素化合物及其光物理性质研究
Nanlong Zheng,Songqi Cao,Tianhao Zhang et al.
Nanlong Zheng et al.
Zero-dimensional (0D) metal halides, which feature discrete metal halide octahedra interspersed with large organoammonium cations, are the building blocks of halide perovskites. The optical properties of these materials make them promising ...
Solid solvation structure design improves all-solid-state organic batteries [0.03%]
固溶结构设计提升全固态有机电池性能
Yang Hu,Han Su,Jiamin Fu et al.
Yang Hu et al.
Organic electrode materials offer a versatile, sustainable approach for next-generation lithium-ion batteries but are limited by low working voltages and poor cycling stability. Here we report a solid-solvation-structure design strategy to ...
Dominic T Chaloner,Michelle Francl,T Ryan Byerly
Dominic T Chaloner