Dynamic amine sorting enables multiselective construction of unsymmetrical chiral diamines [0.03%]
动态胺类排序可实现不对称手性二胺的多选择性构造
Shoule Cai,Zeyu Zhao,Guoqing Yang et al.
Shoule Cai et al.
Precisely differentiating chemicals featuring minor discrepancies is the prerequisite for achieving high selectivities in both chemical synthesis and biological activities. However, efficient strategies to differentiate and sort such congen...
Steven J Malcolmson
Steven J Malcolmson
Pore configuration control in hybrid azolate ultra-microporous frameworks for sieving propylene from propane [0.03%]
用于丙烯/丙烷分离的杂环唑超微孔框架材料中的孔道结构调控
Yong-Jun Tian,Chenghua Deng,Li Zhao et al.
Yong-Jun Tian et al.
Developing porous adsorbents for the complete sieving of propylene/propane mixtures represents an alternative method to energy-intensive cryogenic distillation processes. However, the similar physical properties of these molecules and the i...
Molecular-scale dissipative chemistry drives the formation of nanoscale assemblies and their macroscale transport [0.03%]
分子尺度的耗散化学驱动纳米级组件的形成及其宏观尺度的传输
Kai Liu,Alex W P Blokhuis,Sietse J Dijt et al.
Kai Liu et al.
Fuelled chemical systems have considerable functional potential that remains largely unexplored. Here we report an approach to transient amide bond formation and use it to harness chemical energy and convert it to mechanical motion by integ...
Spatiotemporal protein interactome profiling through condensation-enhanced photocrosslinking [0.03%]
通过凝聚增强型光交联进行时空蛋白质相互作用组分析
Kexin Li,Xiao Xie,Rui Gao et al.
Kexin Li et al.
Resolving protein-protein interactions (PPIs) inside biomolecular condensates is crucial for elucidating their functions and regulation mechanisms. The transient nature of condensates and the multiple localizations of clients, however, have...
Jakob Farnung,Brenda A Schulman
Jakob Farnung
Protocells by spontaneous reaction of cysteine with short-chain thioesters [0.03%]
半胱氨酸与短链硫酯自发反应生成原细胞
Christy J Cho,Taeyang An,Yei-Chen Lai et al.
Christy J Cho et al.
All known forms of life are composed of cells, whose boundaries are defined by lipid membranes that separate and protect cell contents from the environment. It is unknown how the earliest forms of life were compartmentalized. Several models...
Remote chirality transfer in low-dimensional hybrid metal halide semiconductors [0.03%]
低维金属卤化物半导体中的远程手性传递现象研究
Md Azimul Haque,Andrew Grieder,Steven P Harvey et al.
Md Azimul Haque et al.
In hybrid metal halide perovskites, chiroptical properties typically arise from structural symmetry breaking by incorporating a chiral A-site organic cation within the structure, which may limit the compositional space. Here we demonstrate ...
Bruce C Gibb
Bruce C Gibb