A living library concept to capture the dynamics and reactivity of mixed-metal clusters for catalysis [0.03%]
用于催化作用的杂金属簇的动态和反应性的活体文献概念捕获
Raphael Bühler,Max Schütz,Karla F Andriani et al.
Raphael Bühler et al.
The exploration of ligated metal clusters' chemical space is challenging, partly owing to an insufficiently targeted access to reactive clusters. Now, dynamic mixtures of clusters, defined as living libraries, are obtained through organomet...
Ali Miserez
Ali Miserez
Yingji Zhao,Yusuke Yamauchi
Yingji Zhao
Author Correction: Discovery of the selenium-containing antioxidant ovoselenol derived from convergent evolution [0.03%]
作者更正：发现硒含量抗氧化剂卵硒醇来源于汇聚进化
Chase M Kayrouz,Kendra A Ireland,Vanessa Y Ying et al.
Chase M Kayrouz et al.
Published Erratum
Nature chemistry. 2025 Jan 21. DOI:10.1038/s41557-025-01739-6 2025
Author Correction: Cytoskeleton-functionalized synthetic cells with life-like mechanical features and regulated membrane dynamicity [0.03%]
作者更正：具有类似生活的机械特性与调节膜动态性的细胞骨架功能化合成细胞
Sebastian Novosedlik,Felix Reichel,Thijs van Veldhuisen et al.
Sebastian Novosedlik et al.
Published Erratum
Nature chemistry. 2025 Jan 21. DOI:10.1038/s41557-025-01740-z 2025
Publisher Correction: Protocells by spontaneous reaction of cysteine with short-chain thioesters [0.03%]
出版更正：半胱氨酸与短链硫酯自发反应生成原细胞
Christy J Cho,Taeyang An,Yei-Chen Lai et al.
Christy J Cho et al.
Published Erratum
Nature chemistry. 2025 Jan 21. DOI:10.1038/s41557-025-01736-9 2025
An open-shell Ir(II)/Ir(IV) redox couple outperforms an Ir(I)/Ir(III) pair in olefin isomerization [0.03%]
开壳层Ir(II)/Ir(IV)氧化还原对烯烃异构化性能优于Ir(I)/Ir(III)对
Alejandra Pita-Milleiro,Nereida Hidalgo,Juan J Moreno et al.
Alejandra Pita-Milleiro et al.
Open-shell systems based on first-row transition metals and their involvement in various catalytic processes are well explored. By comparison, mononuclear open-shell complexes of precious transition metals remain underdeveloped. This is par...
Synthesis of pillar-layered metal-organic frameworks with variable backbones through sequence control [0.03%]
通过序列控制合成具有可变背骨的柱层金属有机框架
Jingjing Yuan,Ming Yang,Bin Yang et al.
Jingjing Yuan et al.
The properties and functions of metal-organic frameworks (MOFs) can be tailored by tuning their structure, including their shape, porosity and topology. However, the design and synthesis of complex structures in a predictable manner remains...
Tiantian Liang,Zhen Lyu,Ye Wang et al.
Tiantian Liang et al.
Nitroarenes are readily accessible bulk chemicals and can serve as versatile starting materials for a series of synthetic reactions. However, due to the inertness of the CAr-NO2 bond, the direct denitrative substitution reaction with unacti...
Vibrational weak and strong coupling modify a chemical reaction via cavity-mediated radiative energy transfer [0.03%]
腔介导的辐射能量转移通过振动弱耦合和强耦合改变化学反应
Zachary T Brawley,Sindhana Pannir-Sivajothi,Ju Eun Yim et al.
Zachary T Brawley et al.
Controlling reaction outcomes through external influences is a central goal in chemistry. Vibrational coupling between molecular vibrations and cavity modes is rapidly emerging as a distinct strategy compared with conventional thermochemica...