Yeqin Guan,Ping Chen
Yeqin Guan
Vincent Guillerm
Vincent Guillerm
4f-orbital covalency enables a single-crystal-to-single-crystal ring-opening isomerization in a CeIV-cyclopropenyl complex [0.03%]
4f轨道共价性使CeIV-环丙烯配合物单晶到单晶环开异构化成为可能
Brett D Vincenzini,Xiaojuan Yu,Sébastien Paloc et al.
Brett D Vincenzini et al.
Metal-ligand bonding interactions for f-element compounds are typically highly polarized with only minor covalent character. Whereas the 5d/6d orbitals are known to be chemically accessible for dative bonding, recent quantum chemical and sp...
Lanthanide-nickel molecular intermetallic complexes featuring a ligand-free Ni2- anion in endohedral fullerenes [0.03%]
包含无配体Ni2-端心金属富勒烯的稀土-镍分子金属互化物
Panfeng Chuai,Ziqi Hu,Yang-Rong Yao et al.
Panfeng Chuai et al.
Transition metals (TMs) typically exhibit rich redox chemistry and can be found in various oxidation states. In most cases, TMs are positively charged. Strong π-accepting ligands have been shown to stabilize molecular complexes with TMs in...
Synthesis of strained, air-stable boracycles via boron-carbon-centred diradicals [0.03%]
通过硼碳自由基合成应变且稳定的硼杂环化合物
Xinmou Wang,Peiqi Zhang,Zhiyi Yang et al.
Xinmou Wang et al.
Boracycles are important functional scaffolds, often exhibiting superior or unique performance compared with their carbon analogues. Five-membered oxaboracycles are key pharmacophores in Food and Drug Administration-approved boron drugs. Me...
An enzymatic dual-oxa Diels-Alder reaction constructs the oxygen-bridged tricyclic acetal unit of (-)-anthrabenzoxocinone [0.03%]
一种酶促双开环狄尔斯-阿尔德反应构建氧桥三环缩醛单元：(-)-Anthrabenzoxocinone的例子
Xiaoli Yan,Xinying Jia,Zhenyao Luo et al.
Xiaoli Yan et al.
The hetero-Diels-Alder (HDA) reaction is a key method for synthesizing six-membered heterocyclic rings in natural products and bioactive compounds. Despite its importance in synthetic chemistry, naturally occurring enzymatic HDA reactions a...
Small-molecule-catalysed deamination enables transcriptome-wide profiling of N6-methyladenosine in RNA [0.03%]
小分子催化去氨基化实现RNA中N6-甲基腺苷转录组水平检测
Pingluan Wang,Chang Ye,Michelle Zhao et al.
Pingluan Wang et al.
The deamination reaction is important to both fundamental organic chemistry and biochemistry. Traditional chemical methods of deamination rely on the use of aryldiazonium salts under harsh acidic conditions, which limits the application sco...
Reactivity of syn-CH3CHOO with H2O enhanced through a roaming mechanism in the entrance channel [0.03%]
通过入口通道的漫游机制增强syn-CH3CHOO与H2O的反应性
Yiqiang Liu,Lijie Liu,Yanlin Fu et al.
Yiqiang Liu et al.
Criegee intermediates are highly reactive species that play a pivotal role in the chemistry of the atmosphere, substantially impacting global climate and air quality. They are formed through the reaction of ozone with alkenes and considerab...
Author Correction: Synthesis of triple-decker sandwich compounds featuring a M-M bond through cyclo-Bi5 and cyclo-Sb5 rings [0.03%]
作者更正：通过环Bi5和环Sb5合成具有M-M键的三明治化合物
Yu-He Xu,Xing Yang,Ya-Nan Yang et al.
Yu-He Xu et al.
Published Erratum
Nature chemistry. 2025 Apr 15. DOI:10.1038/s41557-025-01825-9 2025
Valence-delocalized trithorium nanocluster superatoms with open-shell exalted diamagnetism [0.03%]
具有开放壳提升型顺磁性的价电子离域三 thorium 纳米团簇超级原子
John A Seed,Xinglan Deng,Josef Tomeček et al.
John A Seed et al.
Quantum-confined nanoclusters can be described by the jellium model, which emphasizes closed-shell electron configurations, but an open-shell variation with jellium aromaticity has been proposed. Such clusters are termed superatoms because ...