Single-particle combinatorial multiplexed liposome fusion mediated by DNA [0.03%]
基于DNA介导的单粒子组合多重脂质体融合技术
Mette Galsgaard Malle,Philipp M G Löffler,Søren S-R Bohr et al.
Mette Galsgaard Malle et al.
Combinatorial high-throughput methodologies are central for both screening and discovery in synthetic biochemistry and biomedical sciences. They are, however, often reliant on large-scale analyses and thus limited by a long running time and...
Stereocontrolled 1,3-nitrogen migration to access chiral α-amino acids [0.03%]
立体专一性1,3-氮迁移以获得手性α-氨基酸
Chen-Xi Ye,Xiang Shen,Shuming Chen et al.
Chen-Xi Ye et al.
α-Amino acids are essential for life as building blocks of proteins and components of diverse natural molecules. In both industry and academia, the incorporation of unnatural amino acids is often desirable for modulating chemical, physical...
Fermi-phase-induced interference in the reaction between Cl and vibrationally excited CH3D [0.03%]
费米相位诱导的Cl与振动激发的CH3D反应中的干涉效应
Huilin Pan,Kopin Liu
Huilin Pan
Mode selectivity is a well-established concept in chemical dynamics. A polyatomic molecule possesses multiple vibrational modes and the mechanical couplings between them can result in complicated anharmonic motions that defy a simple oscill...
Cold photo-carving of halogen-bonded co-crystals of a dye and a volatile co-former using visible light [0.03%]
用于冷光刻的染料和挥发性共formers的卤素键合共晶的冷光刻照片雕刻技术
T H Borchers,F Topić,J-C Christopherson et al.
T H Borchers et al.
The formation of co-crystals by the assembly of molecules with complementary molecular recognition functionalities is a popular strategy to design or improve a range of solid-state properties, including those relevant for pharmaceuticals, p...
Clément Ghiazza,Teresa Faber,Alejandro Gómez-Palomino et al.
Clément Ghiazza et al.
Published Erratum
Nature chemistry. 2022 May;14(5):582. DOI:10.1038/s41557-022-00932-1 2022
Publisher Correction: Stereodefined alkenes with a fluoro-chloro terminus as a uniquely enabling compound class [0.03%]
出版更正：具有氟氯末端的立体定义烯烃作为一种独特有效的化合物类
Qinghe Liu,Yucheng Mu,Tobias Koengeter et al.
Qinghe Liu et al.
Published Erratum
Nature chemistry. 2022 Apr;14(4):474. DOI:10.1038/s41557-022-00930-3 2022
Cobalt(II)-tetraphenylporphyrin-catalysed carbene transfer from acceptor-acceptor iodonium ylides via N-enolate-carbene radicals [0.03%]
催化剂催化下接受体-iodonium ylids通过N-enolate-carbene自由基向羰基的转移反应
Roel F J Epping,Mees M Hoeksma,Eduard O Bobylev et al.
Roel F J Epping et al.
Square-planar cobalt(II) systems have emerged as powerful carbene transfer catalysts for the synthesis of numerous (hetero)cyclic compounds via cobalt(III)-carbene radical intermediates. Spectroscopic detection and characterization of react...
Matthieu Besemer,Guoqiang Tang,Zhi Gao et al.
Matthieu Besemer et al.
For molecular collisions, the deflection of a molecule's trajectory provides one of the most sensitive probes of the interaction potential and there are general rules of thumb that relate the direction of deflection to precollision conditio...
Austin D Marchese,Bijan Mirabi,Colton E Johnson et al.
Austin D Marchese et al.
A widely appreciated principle is that all reactions are fundamentally reversible. Observing reversible transition metal-catalysed reactions, particularly those that include the cleavage of C-C bonds, is more challenging. The development of...
Insights from an information thermodynamics analysis of a synthetic molecular motor [0.03%]
信息热力学分析合成分子马达的见解
Shuntaro Amano,Massimiliano Esposito,Elisabeth Kreidt et al.
Shuntaro Amano et al.
Information is physical, a realization that has transformed the physics of measurement and communication. However, the flow between information, energy and mechanics in chemical systems remains largely unexplored. Here we analyse a minimali...