Triarylphosphine Ligands with Hemilabile Alkoxy Groups. Ligands for Nickel(II)-Catalyzed Olefin Dimerization Reactions. Hydrovinylation of Vi-nylarenes, 1,3-Dienes, and Cycloisomerization of 1,6-Dienes [0.03%]
含半配位的烷氧基的三芳基膦配体。镍(II)催化烯烃二聚反应中的配体。乙烯基芳烃、1,3-丁二烯和1,6-丁二烯环异构化的加氢反应
Souvagya Biswas,Aibin Zhang,Balaram Raya et al.
Souvagya Biswas et al.
Substitution of one of the phenyl groups of triphenylphosphine with a 2-benzyloxy-, 2-benzyloxymethyl- or 2-benzyloxyethyl-phenyl moiety results in a set of simple ligands, which exhibit strikingly different behaviour in various nickel(II)-...
Biomimetic Aerobic C-H Olefination of Cyclic Enaminones at Room Temperature: Development toward the Synthesis of 1,3,5-Trisubstituted Benzenes [0.03%]
室温下 cyclic enaminone 的仿生有氧C-H olefination反应：用于合成1,3,5-三取代苯的尝试
Yi-Yun Yu,Gunda I Georg
Yi-Yun Yu
A green and mild protocol for the dehydrogenative olefination of cyclic enaminones was devised via palladium catalysis at room temperature using oxygen as the terminal oxidant. The synthetic utility of the olefinated cyclic enaminones affor...
Taku Kitanosono,Shū Kobayashi
Taku Kitanosono
Mukaiyama aldol reactions in aqueous media have been surveyed. While the original Mukaiyama aldol reactions entailed stoichiometric use of Lewis acids in organic solvents under strictly anhydrous conditions, Mukaiyama aldol reactions in aqu...
Gold Catalysed Redox Synthesis of Imidazo[1,2- a]pyridine using Pyridine N-Oxide and Alkynes [0.03%]
金催化氧化还原反应合成吡啶诺克和炔氢的Imidazo[1,2-a]pyridine
Eric P A Talbot,Melodie Richardson,Jeffrey M McKenna et al.
Eric P A Talbot et al.
A mild, catalytic, atom economical synthesis of imidazo[1,2-a]pyridines has been developed: catalytic PicAuCl2 in the presence of an acid produces a range imidazo[1,2-a]pyridines in good yield. This strategy is mild and forseen to be of par...
Asymmetric Aldol Reaction of 3-Acetyl-2 H-chromen-2-ones and Isatins Catalyzed by a Bifunctional Quinidine Urea Catalyst [0.03%]
脯氨酸催化的异山酮和异丁酸衍生的α,β-不饱和酮与异atin的不对称aldol反应
Santhi Abbaraju,John Cong-Gui Zhao
Santhi Abbaraju
The asymmetric aldol reaction of 3-acetyl-2H-chromen-2-ones and isatins has been realized by using a bifunctional quinidine-derived urea as the catalyst. The corresponding 3-hydroxyoxindole derivatives containing a 2H-chromen-2-one moiety w...
Stereocontrol in Palladium-Catalyzed Propargylic Substitutions: Kinetic Resolution to give Enantioenriched 1,5-Enynes and Propargyl Acetates [0.03%]
钯催化炔丙基取代反应中的立体控制：动力学拆分生成富集对映体的1,5-enediyne和炔丙酯类化合物
Michael J Ardolino,Meredith S Eno,James P Morken
Michael J Ardolino
Kinetic resolution during the catalytic allyl-propargyl cross-coupling with chiral starting materials can be accomplished with a chiral Palladium catalyst. These reactions offer ready access to enantiomerically enriched enyne products from ...
Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins [0.03%]
钯催化脂肪酸脱碳酰化脱水生产线性α烯烃反应
Yiyang Liu,Kelly E Kim,Myles B Herbert et al.
Yiyang Liu et al.
A highly efficient palladium-catalyzed decarbonylative dehydration reaction of carboxylic acids is reported. This method transforms abundant and renewable even-numbered natural fatty acids into valuable and expensive odd-numbered alpha olef...
A General and Practical Palladium-Catalyzed Direct α-Arylation of Amides with Aryl Halides [0.03%]
一种通用的钯催化酰胺与aryl halide的直接α-芳基化反应方法
Bing Zheng,Tiezheng Jia,Patrick J Walsh
Bing Zheng
An efficient system for the direct catalytic intermolecular α-arylation of acetamide derivatives with aryl bromides and chlorides is presented. The palladium catalyst is supported by Kwong's indole-based phosphine ligand and provides monoa...
Synthesis and Suzuki-Miyaura Cross-Coupling of Enantioenriched Secondary Potassium β-Trifluoroboratoamides: Catalytic, Asymmetric Conjugate Addition of Bisboronic Acid and Tetrakis(dimethylamino)diboron to α, β-Unsaturated Carbonyl Compounds [0.03%]
富氟手性β-三氟硼酸金属有机导向的钾化胺𬭩盐的合成及其铃木-宮浦交叉偶联反应：双硼酸及四甲基氨基二硼与不饱和羰基化合物的催化动力学拆分加成反应
Gary A Molander,Steven R Wisniewski,Mona Hosseini-Sarvari
Gary A Molander
Enantioenriched potassium β-trifluoroboratoamides have been synthesized via an asymmetric, copper-catalyzed 1,4-addition of tetrahydroxydiboron (BBA) and tetrakis(dimethylamino)diboron to α,β-unsaturated amides. These dibora reagents pro...
Rhodium-Catalyzed Asymmetric 1,4-Additions, in Water at Room Temperature, with In-Flask Catalyst Recycling [0.03%]
在室温水中高效催化环加成反应及催化剂就地回收法
Bruce H Lipshutz,Nicholas A Isley,Ralph Moser et al.
Bruce H Lipshutz et al.
Using the newly introduced designer surfactant polyethyleneglycol ubiquinol sebacate (PQS), as the platform for micellar catalysis, nonracemic BINAP has been covalently attached and rhodium(I) inserted to form PQS-BINAP-Rh. This species, th...