Sasan Moradi,Osman Konuray,Javier G Valverde-Bastidas et al.
Sasan Moradi et al.
A family of disulfide (S-S) containing thiol-vinyl-epoxy dynamic networks are presented. The networks are obtained through a dual-curing mechanism wherein a photoinduced thiol-ene reaction at room temperature is followed by a thermally acti...
Francesco Bisio,Sinan Baran Akdemir,Vittorio Bonino et al.
Francesco Bisio et al.
This work presents two fabrication strategies for the development of organic thin-film devices at the micro- and nano-scales. We make use of non-commercial PEDOT synthesized via liquid-phase oxidative chemical polymerization, using vanadium...
From Molecular Structure to Macroscopic Performance: Insights into Polycarbosilane Curing [0.03%]
从中分子结构到宏观性能：聚碳硅烷固化过程的研究与探讨
Tobias Haupt,Vanessa Koch,Florian Rott et al.
Tobias Haupt et al.
Curing protocols critically influence the structure and properties of crosslinked polymer networks, yet their impact on nanoscale structural features remains poorly understood. Here, polycarbosilane (PCS) networks are used as a model system...
High-Yield Synthesis of Molecular Bottlebrushes With Block Copolymer Side Chains by the Copper Superoxido Complex Enabled ATRP via a Grafting-From Approach [0.03%]
通过偶联剂铜超氧化物复台物ATRP从头合成具有嵌段共聚物侧链的高产率分子瓶刷型聚合物
Chenfei Xu,Zheqi Li,Jianping He et al.
Chenfei Xu et al.
The combination of controlled radical polymerization technique and grafting-from strategy has been widely employed for synthesizing molecular bottlebrushes (MBBs); however, this approach always meets challenges at the high monomer conversio...
Chemically and Mechanically Recyclable Polyolefins Incorporating Covalent Adaptable Networks [0.03%]
包含共价适应网络的化学和机械可回收聚烯烃
Andrii Tiiara,Bernadine Daichendt,Sergiy Minko et al.
Andrii Tiiara et al.
We report on the synthesis and characterization of mechanically and chemically recyclable polypropylene-based crosslinked polyolefins (CR-POs) incorporating ester-containing covalent adaptable networks (CANs). To obtain the material, polypr...
Designing Thermally Stable DNA Hydrogels via Entropically-Driven Acridine Intercalation [0.03%]
基于熵驱动的吖啶嵌入设计热稳定的DNA水凝胶
Shaina M Hughes,Amy M DiVito,Patrick F Strobel et al.
Shaina M Hughes et al.
Physically cross-linked hydrogels formed through supramolecular interactions typically relax more rapidly upon heating because reversible bond formation is often exothermic. In contrast, entropy-dominated associations can generate materials...
Functionalization Enhanced Phase Separation in PS-b-PVP Derived Polyzwitterionic Block Copolymers [0.03%]
功能化增强的PS-b-PVP衍生的聚两性离子嵌段共聚物的相分离
Polyxeni P Angelopoulou,Jong K Keum,Marti Checa et al.
Polyxeni P Angelopoulou et al.
Block copolymers with strong tendency for block demixing have attracted significant attention especially for applications in microelectronics and membranes. Enabling technological advances in these areas critically depends on access to well...
Molecular Design of Biobased, Printable Monomers for Two-Photon Polymerization [0.03%]
用于双光子聚合的可打印生物基单体的分子设计
Monika Dabrowska,Brandon Tuck,Evan Shelton et al.
Monika Dabrowska et al.
This study reports the strategic molecular design of a range of novel multi-acrylate monomers derived from the terpenoids nopol and verbenol, and their successful use in two-photon polymerization (2PP). This design process allowed the ident...
Single-Chain Inherent Elasticity Reveals γ-Irradiation-Induced Backbone Reconstruction in Poly(Vinylidene Fluoride) [0.03%]
单链固有弹性揭示了γ射线辐射引发的聚偏二氟乙烯主链重构现象
Yu Bao,Ruixue Li,Yi Han et al.
Yu Bao et al.
γ-Irradiation significantly alters the mechanical properties and functions of poly(vinylidene fluoride) (PVDF), yet the molecular mechanism underlying its property evolution at high irradiation dose remains unclear. Because the single-chai...
Zijing Zhang,Cecilia Pilon,Pimjai Pimbaotham et al.
Zijing Zhang et al.
Here, we aim to clearly define phenomena previously termed unconventional conjugation involving conjugation across Si─O─Si bonds. The goal is to define operative mechanisms and provide general routes to easily accessible Si─O─Si contain...