Organic Ion-Mediated Electrostatic Shielding Facilitates Membrane-Free Electrochemical Hydrogen Production Coupling with LiFePO4 Recycling [0.03%]
有机离子介导的静电屏蔽促进无膜电化学制氢并耦合回收LiFePO4电池废料
Lei Dong,Wangxin Ge,Hongliang Jiang et al.
Lei Dong et al.
Electrolytic water splitting is a cornerstone technology for sustainable hydrogen (H2) production. However, conventional methods face substantial challenges due to the slow kinetics of the oxygen evolution reaction (OER) and limitations imp...
Two-Dimensional Heterovalent Alloying Hybrid Double Perovskite Solid Solution for Elevating Ferroelastic Photoelectric Response [0.03%]
二维异价合金化双重钙钛矿固溶体的铁弹光电响应研究
Qiang-Qiang Jia,Gele Teri,Qi-Fang Zhou et al.
Qiang-Qiang Jia et al.
Hybrid double perovskites (HDPs), as the main candidates for lead-free materials, have attracted great attention in the construction of ferroelectrics, ferroelastics, and high-efficiency photodetectors. However, the photoelectronic performa...
Wide-Temperature Operation of High-Capacity Aqueous Chlorine Batteries Enabled by Complexation Chemistry [0.03%]
配位化学使高容量氯水电池可在宽温区运行
Wenjiao Ma,Chun Liu,Yunting Wu et al.
Wenjiao Ma et al.
Rechargeable aqueous batteries based on the chloride/chlorine (Cl-/Cl2) redox couple offer high theoretical energy density but have been limited by the volatility/disproportionation of chlorine gas and its inherently poor electrochemical re...
Strong Electron-Withdrawing Molecules Facilitating π-π Stacking and Charge Transfer Complexes at Buried Interface and Enabling an Inverted PSC with Open-Circuit Voltage of 1.2 V [0.03%]
强吸电子分子促进埋藏界面的π-π堆叠和电荷转移复合，实现开路电压为1.2 V的倒置有机光伏电池
Jiexi Pan,Jihuai Wu,Weichun Pan et al.
Jiexi Pan et al.
To improve the interfacial match between the hole transport layer (HTL) and perovskite active layer (PAL) in inverted perovskite solar cells (PSCs), a strong electron-withdrawing molecule 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane...
Upcycling of Polystyrene to 1,2-Disubstituted Oxygenated Aromatics Through Backbone Rearrangement and Oxidation Reactions [0.03%]
通过骨架重排和氧化反应将聚苯乙烯升级回收为1,2-取代的含氧芳烃
Albert Ong,Zhibo Zhang,Jerald Y Q Teo et al.
Albert Ong et al.
Upcycling polystyrene (PS) into economically-viable, industrially-relevant single-, and multi-substituted oxygenated aromatic compounds is an attractive option to address the current unsustainable end-of-life of this high-volume waste plast...
Triangular Nanotoroids Self-Assembled from Polypeptide Homopolymers: The Formation Route and Mechanisms [0.03%]
多肽均聚物自组装的纳米角锥体：形成机制和途径研究
Yue Du,Yimeng Li,Ruiqi Jin et al.
Yue Du et al.
Polymer nanotoroids have attracted increasing attentions recently. The topology of the nanotoroids is mainly limited to circular form, while noncircular forms are rarely observed. The preparation method and formation mechanism for noncircul...
Sustainable Fluorinated Silicon Dielectric Design for Enhanced Contact-Electro-Chemistry [0.03%]
用于增强接触电化学的可持续氟化硅介电材料设计
Ting Gan,Zhijian Li,Shaoxin Li et al.
Ting Gan et al.
Solid-liquid contact electrification (CE) has recently emerged as a powerful means of initiating interfacial chemical reactions via charge transfer. Fluorinated ethylene propylene (FEP) and polytetrafluoroethylene (PTFE) are frequently empl...
Ion-Dipole Interaction Induced Rigid-Flexible Coupling SEI for Ultrastable Sodium Storage of Microsized Sn Anode [0.03%]
离子-偶极相互作用诱导刚柔耦合SEI膜实现微米级Sn基阳极钠超稳定存储性能
Mingyue Li,Simi Sui,Xunzhu Zhou et al.
Mingyue Li et al.
Tin (Sn) anode has been considered as a promising candidate for sodium-ion batteries due to its high theoretical capacity and suitable operating potential. However, they suffer from substantial volume variation during charge/discharge proce...
The First Ferrocene-Based Molecular Ferroelectric Accompanied by Spatial Symmetry Operation Breaking [0.03%]
首例基于铁烯的分子铁电体及其空间对称性操作破坏现象
Zunqi Liu,Jun-Chao Liu,Shu-Wen Xiong et al.
Zunqi Liu et al.
Ferroelectric materials with switchable spontaneous polarization have attracted significant interest over the past decades. Molecular ferroelectrics particularly offer unique advantages such as structural tunability, inducible intrinsic hom...
Covalent Organic Frameworks Anchoring Single-Atom Pt for Three-Phase Interface-Assisted Photocatalytic Overall Water Splitting [0.03%]
共价有机框架负载单原子Pt用于三相界面辅助光电催化全分解水反应
Ting-Ting Sun,Hao Zhang,Ya Wang et al.
Ting-Ting Sun et al.
Covalent organic frameworks (COFs) are promising photocatalysts for overall water splitting (OWS) due to their high crystallinity, porosity and tunable structures. However, current COF-based systems rely on cocatalysts, which suffer from lo...