Single-Site Metal-Nonmetal Microenvironment Regulation of Copper Nanoclusters with Atomic Precision for X-Ray Imaging [0.03%]
具有原子精度的单-site金属-非金属微环境调控铜纳米团簇用于放射成像
Chen Zhu,Fei Li,Jingjing Xia et al.
Chen Zhu et al.
The intramolecular microenvironment regulation in metal nanoclusters has typically occurred with the same attribute factors-like metal-to-metal or ligand-to-ligand control-while the regulation with different-attribute factors, e.g., from me...
In-Situ Electrochemical Reconstruction of Copper Single-Sites to Dual-Sites for Ambient Urea Synthesis [0.03%]
原位电化学重建铜单原子为双原子用于环境条件下的尿素合成
Jiafang Liu,Shengbo Zhang,Zhixian Mao et al.
Jiafang Liu et al.
Understanding and uncovering really catalytic active-sites during electrocatalysis is vital for carbon-nitrogen coupling reaction to synthesize urea. Here, we report a Copper (Cu) single-atom catalyst (Cu-N3 SAs) with a Cu-N3 coordination s...
3D Covalent Arsenic Polyoxomolybdate-Organic Polymer with Ultrahigh Photocatalytic Oxidative Ability for Aromatic C─H Activation [0.03%]
用于芳香族C-H活化的超高光催化氧化能力的三维砷钼杂多酸-有机聚合物复合材料
Yingnan Zhao,Liang Pang,Tianyu Qiu et al.
Yingnan Zhao et al.
The photocatalytic activation of inert aromatic C─H bonds under mild conditions remains a major challenge due to the inherent stability of sp2 C─H bonds and the lack of efficient, selective heterogeneous photocatalysts. Herein, by strateg...
Design of Aminophosphine Precursor for Robust Synthesis of InP Quantum Dots with Near-unity Quantum Yield [0.03%]
高量子产率的InP量子点的稳健合成方法及其胺磷配体设计研究
Doheon Yoo,Euk Hyun Kim,Ji-Seoung Jeong et al.
Doheon Yoo et al.
Aminophosphines have emerged as promising phosphorus candidates for the synthesis of InP quantum dots (QDs), offering an alternative to traditional tris(trimethylsilyl) phosphine. However, the relatively low reactivity of conventional amino...
Simultaneous Modulation of Mesoporosity and Al Siting for Superior Performance Zeolite Catalyst in Ethylene Dehydroaromatization to Aromatics [0.03%]
同时调节介孔和铝位置以获得用于乙烯脱氢芳构化制芳烃的优质丝光沸石催化剂
Yanfeng Shen,Zhengxing Qin,Antoine Beuque et al.
Yanfeng Shen et al.
Porosity and Al siting are key levers for optimizing zeolite catalysts, yet they are often addressed independently due to the lack of effective integrated tuning strategies. Herein, we report an integrative methodology for preparing hierarc...
Gang-Wei Wang [0.03%]
王刚威
Gang-Wei Wang
Gang-Wei Wang
"I advise my students to work hard, but to think even harder… The last non-scientific book I read was My Altay, which describes the author Li Juan's deep bond with nature and explores themes of childhood, freedom, and the harmony between h...
Designing Molecular Reactor of Interlayer Dual-Atom Toward Urea Electrosynthesis [0.03%]
用于尿素电合成的层间双原子分子反应器的设计
Kefan Zhang,Yuyan Liu,Xupeng Qin et al.
Kefan Zhang et al.
Electrocatalytic C─N coupling offers a sustainable alternative to energy-intensive industrial processes for urea synthesis. Herein, we design conjugated polymer-based molecular reactors featuring interlayer diatomic Cu-N4 sites and precise...
Engineering Peripheral Metal-Oxide Catalysis: Interparticle Spacing in Cu/ZrO2 Catalysts for Methanol Synthesis by CO2 Hydrogenation [0.03%]
工程化外周金属氧化物催化作用：Cu/ZrO2催化剂中Cu颗粒间距对二氧化碳氢化合成甲醇的影响
Iván López-Luque,Jannis Hack,Tania Ródenas et al.
Iván López-Luque et al.
The periphery surrounding oxide-supported metal nanoparticles plays a crucial role in many catalytic reactions that exhibit strong metal-oxide promotional effects. Engineering this catalytically active periphery, where kinetically relevant ...
Ionic Liquid-Confined Covalent-Organic Framework Pores as Nanoreactors for CO2 Photoconversion [0.03%]
限域于离子液体中的共价有机框架纳米反应器二氧化碳光转化反应
Haochun Yin,Houhou Huang,Linlu Bai et al.
Haochun Yin et al.
The topological nanopores of covalent organic frameworks (COFs) show promise as spatially confined nanoreactors for solar CO2 photoconversion. However, simultaneously increasing the electron density, improving the electron transfer, CO2 cap...
Ionic Hydrogen-Bonded Organic Frameworks: A New Type of Porous Organic Solid Base [0.03%]
离子氢键有机框架：一种新的多孔固体碱类型
Ying Hou,Han-Ru Fang,Yu-Lin Li et al.
Ying Hou et al.
Solid base offers advantages in terms of the ease of handling, environmentally sustainable processes, and tunable interfacial properties. Despite of these benefits, the exploration of new solid bases remains challenging and is an underdevel...