Polyoxometalate Electron-Sponge-Mediated Photooxidative Hydroxylation of Arylboronic Acids [0.03%]
多金属氧酸盐电子海绵介导的芳基硼酸光氧化羟基化反应
Ping Wang,Shen-Yue Xu,Song Guo et al.
Ping Wang et al.
Reducing costs while maintaining efficiency in photocatalytic systems remains a major pursuit in the field of solar photocatalysis. Herein, we explore a universal strategy for regulating electronic transfer by employing earth-abundant polyo...
Anisotropic Second-Harmonic Generation in Chiral Hybrid Palladium Halides [0.03%]
手性钯卤化物中各向异性的二次谐波生成
Xin Qiu,Junzi Li,Jiaqi Zhu et al.
Xin Qiu et al.
Chiral hybrid metal halides (HMHs) have attracted considerable attention due to their promising application in various optoelectronic devices. In this work, one kind of zero-dimensional (0D) R/S-methylbenzylammonium)2PdCl4 [(R/S-MBA)2PdCl4]...
Ultraviolet-Controlled Radical Dopants: Suppressing Unpredictable Oxidation and Lithium Migration in Perovskite Solar Cells [0.03%]
紫外线控制自由基掺杂剂：抑制钙钛矿太阳能电池中不可预测的氧化和锂迁移
Zihao Li,Jinzheng Zhao,Yikai Yun et al.
Zihao Li et al.
Perovskite solar cells (PSCs) have achieved parity in efficiency with silicon-based solar cells. This dependency introduces stability challenges and complicates device fabrication due to the traditional air-oxidation doping process, which i...
Impact of Coordination Environment for Designing Ru-Based Alloy Catalysts for Ammonia Decomposition [0.03%]
配位环境对Ru基合金分解氨催化剂设计的影响
Lu Wei,Likang Lv,Tong Han et al.
Lu Wei et al.
Alloying is an effective strategy to modulate a metal catalyst's electronic structure and optimize its performance, but developing a fundamental design principle has been challenging due to the geometric and electronic disturbance between t...
Compact Ion-Pair Aggregates Dominated Electrolytes Enable High-Performance Low-Temperature Lithium-Ion Batteries [0.03%]
紧凑型离子对聚集电解质可实现高性能低温工作锂离子电池
Feng Su,Yiting Lin,Xin Dou et al.
Feng Su et al.
Lithium-ion batteries (LIBs) are widely used due to their high energy density, long cycle life, and environmental friendliness. However, at sub-zero temperatures, the operation of LIBs is constrained by degraded electrolyte ion transport pe...
Strain Energy Prompted Tunable Aggregation-Induced Emission Property of Tetraphenylethylene [0.03%]
应变能调控四苯乙烷的聚集诱导发光性质研究
Kai Lan,Cefei Zhang,Yifei Li et al.
Kai Lan et al.
Organic molecules exhibiting aggregation-induced emission (AIE) have attracted considerable attention due to their exceptional solid-state luminescent properties. Understanding the AIE mechanism has been a focal point of both theoretical an...
Expanding the Repertoire of Photoswitchable Unnatural Amino Acids for Enzyme Engineering [0.03%]
用于酶工程的光控非天然氨基酸应用范围的扩展
Caroline Hiefinger,Michela Marcon,Verena Pape et al.
Caroline Hiefinger et al.
Photoswitchable unnatural amino acids (psUAAs) play a crucial role in the engineering of light-sensitivity in enzymes, which holds significant promise for diverse applications such as biotherapy and biocatalysis. Besides near-quantitative p...
Fluorescent Three-Dimensional Covalent Organic Frameworks with pcu Topology Based on Triangular Antiprism Node [0.03%]
基于三角反棱柱节点的pcu拓扑荧光三维共价有机框架
Sheng Yin,Lin Li,Jiang Han et al.
Sheng Yin et al.
The design of highly connected fluorescent polyhedral building blocks is essential for expanding the structural and functional diversity of three-dimensional covalent organic frameworks (3D COFs) but remains largely underexplored due to syn...
Hydrothermal Processing as an Effective Strategy for Producing Coordinated Non-Aromatic Hydrogels With Persistent and Reversible UV-Activated Room-Temperature Phosphorescence [0.03%]
水热处理制备具有持久和可逆紫外激活室温磷光的非芳香族交联水凝胶的有效策略
Jinsheng Xiao,Junwen Deng,Yunhao Bai et al.
Jinsheng Xiao et al.
The development of non-aromatic hydrogels with unique persistent room-temperature phosphorescent (RTP) through simple preparation methods remains a great challenge. Here, we propose and demonstrate a facile and universal hydrothermal proces...
Crystallization-Driven Self-Assembly-Substrated-Polymerization-Induced Self-Assembly (CDSA-s-PISA). Toward the Next Generation of Supercarriers [0.03%]
结晶驱动自组装-基质聚合诱导的自组装（CDSA-s-PISA）朝向新一代超载体而去
Jiaqian Nie,Jiantian Zhao,Lina Li et al.
Jiaqian Nie et al.
All the objects that surround us can be seen as combinations of elementary shapes like spheres, rods, and squares that perform complex tasks when connected in a well-defined manner. While making a device by assembling those shapes remains r...