Electrochemical Upgrading Plastic to Organosulfurs Through Fe-N3 Single Atom Catalyst Under Ambient Conditions [0.03%]
环境条件下废旧塑料电催化升级制备有机硫化物：Fe-N3单原子催化剂的作用
Qing Xia,Shanhe Gong,Jie Wu et al.
Qing Xia et al.
Cycling and electrochemical upgrading of plastics present a sustainable approach to transforming waste into high-value chemicals, yet the focus has predominantly been on carbohydrate production, leaving the potential of organosulfur compoun...
Central Dynamic Conversion of Dicyanomethyl Radicals via Intermolecular Charge Transfer for Ultrabright NIR-II Fluorescence Imaging-Guided Mild Photothermal Therapy [0.03%]
基于分子间电荷转移的二氰甲基自由基中心动态转化的近红外Ⅱ区超亮荧光成像及温和光热治疗指导退癌研究
Yixuan Xu,Dalong Yin,Yating Wang et al.
Yixuan Xu et al.
Stable organic radicals have emerged as promising candidates in biotheranostics owing to their unique electronic configurations and tunable photophysical characteristics. Among these, dicyanomethyl radical derivatives stand out as key playe...
Yingxin Ma,Xuyun Guo,Mengxiang Han et al.
Yingxin Ma et al.
Amino acids as fundamental building blocks exhibit versatile applications spanning from food science to pharmaceutical development. Conventional biological and chemical synthetic approaches suffer from low efficiency and elevated energy dem...
Targeted Discovery and Characterization of Type-II PKS-NRPS Hybrid DNA-Alkylating Antibiotics [0.03%]
II型PKS-NRPS杂合DNA烷基化抗生素的靶向发现及表征
Qiu-Yue Nie,Shi-Qi Fang,Lian Wu et al.
Qiu-Yue Nie et al.
DNA alkylating natural products usually exhibit diverse bioactivity and serve as a crucial source of drug leads. Here, we employed genome mining guided by HTH-42 superfamily resistance gene to precisely discover a new class of DNA-alkylatin...
Shimao Deng,Yixian Wang,Tianxiao Sun et al.
Shimao Deng et al.
The micromorphology of composite cathodes is known to play a vital role in determining all-solid-state battery (ASSB) performance. However, much of our current understanding is derived from empirical observations, lacking a deeper mechanist...
Direct Production of Cyclohexanones from Lignin via Chlorine-Mediated Catalytic Hydroprocessing [0.03%]
氯介导催化氢处理制备木质素环己酮类化合物
Qun Yu,Wen Zhao,Yanran Cui et al.
Qun Yu et al.
Cyclohexanones, as critical biopolymer precursors, could be produced from lignin yet rarely reported due to the formidable challenge of simultaneously removing oxygen-containing functional groups (e.g., methoxy, hydroxyl) and achieving sele...
Exo-Selective Intramolecular (4+3) Cycloadditions to Trans-Fused Perhydroazulenes: An Asymmetric Formal Synthesis of (-)-Pseudolaric Acid B [0.03%]
exo-选择性环化构建反共轭螺环骨架：(-)-假白榄酸B的不对称全合成研究
Zengsheng Yin,Yuxuan He,Guo Wei et al.
Zengsheng Yin et al.
We present an asymmetric formal total synthesis of pseudolaric acid B (PAB), based on the intramolecular (4+3) cycloaddition of a new class of epoxy enolsilane substrates. This substrate type has the epoxide geminally-substituted on the tet...
Embedding Metallosalen Active Sites in Zr-MOF for Enhanced Selective Syngas Production from CO2 Photoreduction [0.03%]
通过光还原CO2制备化学品：含金属Salen活性位点的Zr-MOFs材料用于提升一氧化碳的选择性生成反应性能研究
Mei Li,Cha Li,Yawen Shi et al.
Mei Li et al.
Selective photocatalytic CO2 reduction to product syngas remains a great challenge. Herein, we proposed a novel strategy by integration of metallosalen (M-Salen) active sites and Zr-MOF, to promote the selective production of syngas through...
Electrostatic Potential-Dominated Weak Solvation Chemistry for Synergistic Optimization of V2O5 Cathode and Zn Anode [0.03%]
静电势主导的弱溶剂化化学在V2O5正极和锌负极协同优化中的应用
Jingzhu Chen,Fan Bu,Qinghe Cao et al.
Jingzhu Chen et al.
Practical aqueous zinc-ion batteries face severe challenges from cathodic dissolution and anodic dendrite growth. Herein, we report a novel electrostatic potential-dominated weakly solvated electrolyte that correlates molecular charge aniso...
Metabolic Engineering of the 5-Aminolevulinate Biosynthetic Pathway in E. coli Improves Efficiency of Hemoprotein-Based Biocatalysis [0.03%]
代谢工程改善大肠杆菌中铁蛋白生物催化效率
Shunsuke Kato,Miteki Abe,Nobuyuki Okahashi et al.
Shunsuke Kato et al.
Biocatalysis using heme-dependent enzymes provides a powerful synthetic platform to facilitate a variety of chemical transformations required for organic synthesis. Despite recent advances in biocatalysis, recombinant expression systems for...