Facet Engineering and Fe─N─Co Bridged Heterojunction Enable Fe3O4@C@ZIF67 as High-Performance Photocatalyst for Ammonia Synthesis [0.03%]
facets工程和Fe-N-Co桥联异质结使Fe3O4@C@ZIF-67成为合成氨的高性能光催化剂
Jingjing Wang,Liying Wang,Haibo Guo et al.
Jingjing Wang et al.
Ammonia synthesis is vital for global fertilizer production but traditionally relies on the energy-intensive Haber-Bosch process, a major contributor to CO2 emissions. Photocatalytic nitrogen reduction reaction (PNRR) offers a sustainable a...
Catalytic 1,2-Migratory Insertion in a Bismuth Redox Platform: Reductive Arylation of Aldehydes [0.03%]
双金属铋氧化还原平台的催化迁移插入反应：醛的还原芳基化反应
Xiangrong Liu,Hye Won Moon,Davide Spinnato et al.
Xiangrong Liu et al.
Herein, we report a catalytic defluorinative arylation of aldehydes with (per) A fluoroarenes facilitated by a pincer-based PheBox-Bi(I) under mild conditions. The protocol features various novel aspects in bismuth redox catalysis; namely, ...
Peng-Lai Wang,Peng Chen,Raorao Yang et al.
Peng-Lai Wang et al.
We report on the metal-free active template synthesis of crown ether-peptide rotaxanes. A 24-crown-8 ring is sufficiently small that the side chains of canonical branched amino acids act as barriers that trap the macrocycle on the particula...
Experimentally Guided Iterative Parameter Estimation for Predictive Chemical Oscillator Models [0.03%]
实验引导的迭代参数估计在预测化学振子模型中的应用
Maëlle Le Cacheux,Luca E Oddone,Sofiya A Runikhina et al.
Maëlle Le Cacheux et al.
Chemical oscillators are fundamental to dynamic processes in biology, from circadian rhythms to metabolic regulation, inspiring efforts to design synthetic analogues for use in responsive materials, autonomous systems, and molecular computi...
Judicious Use of Chalcogens in Multiresonant Thermally Activated Delayed Fluorescent Emitters Leads to OLEDs with Efficiencies Exceeding 36% and Showing Mild Efficiency Roll-Off [0.03%]
适量引入氧族元素的多共振室温磷光发光材料实现效率超过36%且效率滚降温和的OLED器件
Futong Liu,Zihan Su,Zhuang Cheng et al.
Futong Liu et al.
Strategies that produce OLEDs that simultaneously achieve outstanding electroluminescence efficiency, small efficiency roll-off, good stability, and high color purity remain in strong demand. Herein, we report how judicious decoration of a ...
Lili Lin
Lili Lin
"My favorite quote is from Lao Tzu: "Nature never hurries, yet everything is accomplished." It reminds me that true progress grows in silence, like bamboo building its roots underground before touching the sky… I advise my students to avoi...
Cathleen Zeymer [0.03%]
凯瑟琳·蔡默尔
Cathleen Zeymer
Cathleen Zeymer
"The most important future application of my research would be the integration of designer enzymes into biocatalytic processes in industry… If I were a piece of lab equipment, I would be a plate reader, trying to deal with 96 things in par...
Zhengyang Bin [0.03%]
宾正扬
Zhengyang Bin
Zhengyang Bin
"My worst chemistry-related nightmare is designing an interesting fluorescent emitter, only to find it doesn't emit any light at all… To improve my work-life balance, I spend time with my family, have dinner gatherings with friends, and wa...
Copper Single-Atom Catalyst for Efficient C─S Coupling in Thioether Synthesis [0.03%]
用于硫醚合成高效C─S偶联的铜单原子催化剂
Theodore A Gazis,Shilpa Palit,Luis A Cipriano et al.
Theodore A Gazis et al.
Carbon-heteroatom cross-coupling reactions have become indispensable tools in synthetic chemistry. However, the formation of carbon-sulfur (C─S) bonds, which are essential for producing thioethers used in pharmaceuticals, agrochemicals, an...
Copper-Catalyzed Asymmetric [2 + 2 + 2] Cycloaddition of Diynes via Vinyl Cations [0.03%]
铜催化下通过 vinyl cation 进行的二炔烃的不对称[2+2+2]环加成反应
Yan-Xin Zheng,Li-Gao Liu,Yu-Yao Zhou et al.
Yan-Xin Zheng et al.
Catalytic asymmetric [2 + 2 + 2] cycloaddition of diynes represents an efficient and atom-economical strategy for the assembly of valuable chiral cyclic targets in a single step. However, this strategy traditionally relies on the cyclometal...