Dissimilar Reactions and Enzymes for Psilocybin Biosynthesis in Inocybe and Psilocybe Mushrooms [0.03%]
裸盖菇素生物合成在裸盖菇属和迷走蘑菇中的不同途径及酶学机制
Tim Schäfer,Fabian Haun,Bernhard Rupp et al.
Tim Schäfer et al.
Psilocybin (4-phosphoryloxy-N,N-dimethyltryptamine, 1) is the main indolethyl-amine natural product of psychotropic (so-called "magic") mushrooms. The majority of 1-producing species belongs to the eponymous genus Psilocybe, for which the b...
Shen-Yi Guo,Miguel Paraja,Augustina Jozeliūnaitė et al.
Shen-Yi Guo et al.
Ideas to use external electric fields to enable, accelerate and direct the movement of electrons during chemical reactions are not new. Theory and experiments under special conditions predict that electric-field catalysis (EFC) from externa...
Facile Synthesis of 20-nm-Thick ZIF-67 Films for Hydrogen Sieving Using β-Co(OH)2 Precursor Nanosheets [0.03%]
以β-Co(OH)₂前驱体纳米片为原料的ZIF-67薄膜的简易合成及氢气分离性能研究
Xuekui Duan,Yueqing Shen,Kumar Varoon Agrawal
Xuekui Duan
Zeolitic imidazolate framework-67 (ZIF-67) is an important class of nanoporous materials for high-performance membranes for gas separation, offering uniform-sized gas-selective pores. However, the fabrication of high-quality sub-100-nm-thic...
In-Situ Probing CO Activation in Sulfur-Enhanced Paired Electrocatalysis for CO2-to-C2+ Conversion with Alcohol Oxidation [0.03%]
用于CO2到C2+转化的醇氧化的硫增强型配对电催化的原位CO活化探测
Feng Ming Yap,Shaoyu Yuan,Jian Yiing Loh et al.
Feng Ming Yap et al.
In a world striving for sustainable energy, advanced electrocatalysts are pivotal to enabling efficient chemical transformations with minimal energy costs. Herein, we uncover a practical approach for the simultaneous electrochemical CO2 red...
Hydrogen-Bond-Stabilized Organic Potassium-Ion Full Cell Operating at -40°C [0.03%]
一种可在-40℃工作的氢键稳定有机钾离子全电池
Wei-Sheng Zhang,Xian-He Chen,Chen-Xing Zhang et al.
Wei-Sheng Zhang et al.
Low-temperature energy storage systems confront severe operational constraints due to sluggish ion kinetics and electrolyte solidification. While potassium-ion batteries (PIBs) offer potential for low-cost energy storage, the absence of via...
Atroposelective Synthesis of Enamine-Based Axially Chiral Styrenes via CuH-Catalyzed Hydroamination of Internal Alkynes [0.03%]
通过CuH催化内部炔烃氢胺化构建基于烯胺的轴手性茋
Zuyu Liang,Yijian Ma,Huanfeng Jiang et al.
Zuyu Liang et al.
Despite the significant potential of axially chiral enamines, their efficient synthesis remains a challenge. Herein, we report a new approach for the diverse synthesis of enamine-based axially chiral styrenes via a copper-catalyzed atropose...
On the Viability of Carbonyl Hydroboration Catalysed by Aluminium Hydrides [0.03%]
铝氢化物催化羰基羟硼化的可行性研究
Alexa Caise,Barnabé Berger,Aidan Murray et al.
Alexa Caise et al.
The hydroboration of aldehydes and ketones by pinacolborane (HBpin) catalysed by (Nacnac)DippAl(OTf)H ((Nacnac)Dipp = HC(MeCDippN)2; Dipp = C6H3 iPr2-2,6; Tf = SO2CF3) was first reported in 2015. This study represented a landmark in main gr...
Anhydride-form Cellulose Derivatives: Synthesis, in Situ Reactive Separation, and Solvent Recycling [0.03%]
酐化形式的纤维素衍生物：合成、原位反应分离及溶剂回收
Chenxin Yun,Chenhao Liu,Guangzhi Zhao et al.
Chenxin Yun et al.
The utilization of cellulose remains underexploited due to the use of toxic solvents, high energy consumption, difficulty in separation, and environmental concerns during dissolution, processing, and separation processes. Herein, we present...
Constructing Sari-Topology Covalent Organic Frameworks from Pseudo-C5-Symmetric Core for Enhanced Oxygen Reduction Reaction [0.03%]
通过伪C5对称核心构建萨里拓扑学共价有机框架以增强氧还原反应性能
Xiaoyu Xu,Shuai Bi,Shuang Zheng et al.
Xiaoyu Xu et al.
Developing new topologies for two-dimensional covalent organic frameworks (2D COFs) remains challenging due to the scarcity of geometrically comparable building blocks. Herein, we report the construction of COFs exhibiting an unprecedented ...
Coordination Reconstruction Enhanced Synergistic Nonradical Oxidation Pathways in Cobalt Single-Atom Catalysts for Sustained Pollutant Destruction [0.03%]
用于持久性污染物降解的单原子催化剂中的协同非自由基氧化路径的协调重建增强作用
Lin Liu,Bo Chen,Tong Wu et al.
Lin Liu et al.
Limited synthetic efficiency and high costs constrain industrial production of single-atom catalysts (SACs) despite their superior catalytic performance. We report a scalable and economical solid-state pyrolysis strategy for cobalt single-a...