Bioinspired Peptide-Phosphonium Salt Catalysis Unlocks Asymmetric Desymmetrization of Phosphoryl Acids: Programmable Synthesis of P(V)-Stereogenic Molecules [0.03%]
受生物启发的肽-磷𬭩盐催化解锁磷酸的不对称脱对称化：P(V)手性分子的程序化合成
Siqun Yang,Xingjie Luo,Zanjiao Liu et al.
Siqun Yang et al.
Enantioselective desymmetrization of prochiral phosphorus(V) compounds represents a pivotal strategy for constructing P(V)-stereogenic skeletons, yet existing methods face limitations in structural diversification and metal-free catalytic s...
Deep Eutectic Solvent Binder Facilitating Reaction Kinetics of Lithium Sulfur Batteries [0.03%]
一种促进锂硫电池反应动力学的深 eutectic 键合剂溶剂
Chen Li,Zhaokun Wang,Zuohang Li et al.
Chen Li et al.
Existing binders fail to integrate all designed functionalities, including the polysulfide shuttle effect, sluggish kinetic transformation, electrode volume variation, slow Li⁺ transfer, and flammable characteristics. Herein, the microwave...
Efficient Electronic-Structure Methods Toward Catalyst Screening: Projection-Based Embedding Theory for CO2 Reduction Reaction Intermediates [0.03%]
高效的电子结构方法在催化剂筛选中的应用——基于投影的嵌入理论在二氧化碳还原反应中间体中的应用研究
Elena Kolodzeiski,Christopher J Stein
Elena Kolodzeiski
Catalyst screening is a demanding task for computational chemistry since the profound diversity of surface structures under operando conditions is accompanied by high demands on the accuracy to predict the relevant kinetics. Embedding appro...
Molecular Design of Asymmetric Difluorinated Ether Electrolytes for Stable Operation of High-Voltage Lithium Metal Batteries [0.03%]
用于高压锂金属电池稳定运行的不对称双氟代醚电解质的分子设计
Guangzhao Zhang,Tong Zhang,Yuqi Liu et al.
Guangzhao Zhang et al.
Fluorination of electrolyte solvents is key to improving the cycling stability of high-voltage lithium metal batteries (LMBs), yet the critical role of fluorinated alkyl chain length in governing solvation and interphase chemistries remains...
The ConPET Mechanism Remains Veiled: Reply to "Unlocking the ConPeT Mechanism" [0.03%]
论ConPET机制：“解锁ConPET机制”的回应
Yan Zhang,Zhenbo Guo,Ronghui Qiu et al.
Yan Zhang et al.
In this journal, a Correspondence by Ventura, Cozzi, and Ceroni reported time-resolved absorption spectroscopy studies in the electron transfer process from cyanoarene photocatalyst 3,4,5,6-tetrakis(diphenyl amino)phthalonitrile (4DPAPN) in...
Falk Ebeler,Yury V Vishnevskiy,Jan-Hendrik Lamm et al.
Falk Ebeler et al.
The synthesis, structure, and reactivity of the bicyclo[1.1.0]tetragermane-2,4-diide compound [(ADC)Ge2]2 (3), which features a Ge4 core bridged by two anionic dicarbene frameworks (ADC = PhC{N(Dipp)C}2; Dipp = 2,6-iPr2C6H3), are reported. ...
Transforming Chemiluminescence from Flash to Glow by Breaking the Catalytic Limitation with a Medium-Entropy Nanozyme [0.03%]
一种中熵纳米酶打破催化限制将化学发光从闪光转变为荧光
Shuai Luo,Weiwei Chen,Yuru Wang et al.
Shuai Luo et al.
Intensive and persistent chemiluminescence (CL) emission is highly desired in biological imaging and is also a conundrum for most CL systems. Catalysts can efficiently improve the flash intensity but scarcely achieve persistent enhancement ...
Aqueous Separation of Styrene from Ethylbenzene Using a Water-Soluble Cyclophane [0.03%]
用水溶性环糊精从乙苯中分离苯乙烯的水溶液体系相平衡研究
Medha Aggarwal,Sailendra Pradhan,Partha Sarathi Mukherjee
Medha Aggarwal
The selective separation of hydrocarbons such as styrene (ST) and ethylbenzene (EB) remains a formidable challenge in the petrochemical industry due to their nearly identical molecular structures and physicochemical properties. Herein, we r...
CO2 Photoreduction by H2O: Cooperative Catalysis of Palladium Species on Poly(triazine imide) Crystals [0.03%]
Palladium晶上聚三嗪均三苯齐催化剂高效光催化二氧化碳还原
Xinyu Xu,Bo Su,Sibo Wang et al.
Xinyu Xu et al.
Photocatalytic CO2 reduction coupled with H2O oxidation has been pursued extensively, albeit facing challenges in efficiency and selectivity. Herein, we develop a PdSAs+NPs/PTI catalyst by co-anchoring atomic and nanoparticulate Pd species ...
Promoting Ampere-Level Nitrate Reduction to Ammonia Through Strong Oxide-Oxide Interaction [0.03%]
通过强氧化物-氧化物相互作用促进铵离子水平的硝酸盐还原为氨
Haitao Xu,Yang Yang,Ali Han et al.
Haitao Xu et al.
The electrochemical reduction of nitrate to value-added ammonia offers a promising approach for removing nitrate pollutants from wastewater, combining energy efficiency, and environmental sustainability. However, developing industrially via...