Casey M. Platnich [0.03%]
克莱西·M·普拉蒂尼克
Casey M Platnich
Casey M Platnich
"My motto is: "Perfect is the enemy of good." I think it's really important as a scientist and it honestly has become a guiding tenet in other areas of my life as well… The advice I wish I had received is that it is okay not to know…" Fin...
Molecular-Locking Strategy Enables Volatile Ether Organic Electrolytes to Achieve High-Energy Lithium Battery [0.03%]
分子锁策略使易挥发的醚类有机电解质实现高能量锂金属电池
De-Hui Guan,Xin-Yuan Yuan,Jian-You Li et al.
De-Hui Guan et al.
High-energy lithium (Li) metal batteries are constrained by safety and lifespan owing to the lack of suitable electrolyte solutions. Here, we report a synergy of molecular-locking and gelation treatment by cations-bridged polyoxometalate su...
Proton-Resistant N-Heterocycle-Linked TEMPO Catholytes for Long-Lasting Neutral Aqueous Organic Redox Flow Batteries [0.03%]
用于长寿命中性水系有机液流电池的质子耐受型N-杂环连接TEMPO阴极电解质
Yujie Zhao,Xu Liu,Zengrong Wang et al.
Yujie Zhao et al.
TEMPO is a widely studied catholyte for aqueous organic redox flow batteries (AORFBs) but suffers from proton-induced ring-opening degradation when its solubility is enhanced via hydrophilic substitution at the 4-position, leading to struct...
Air-Stable Allyl Radicals and Heterocoupled Dimer: Synthesis, Characterization, and Near-Infrared Emissions [0.03%]
稳定的烯丙基自由基和杂交二聚体：合成、表征及近红外发光性能研究
Yihao Jiang,Zekun Tong,Shuai Tian et al.
Yihao Jiang et al.
Air-stable luminescent monoradical remains rare. Herein, we report novel stable allyl radicals (ARS) achieved by conjugated extension of benzo[b]thiophene 1,1-dioxide and steric protection of 1,3,5-trichlorobenzene. The reactivity and photo...
Programmable Bio-Derived Noncovalent Glass via Reconfigurable H-Bonding Networks [0.03%]
基于可重构氢键网络的生物衍生非共价玻璃及其程序化制备
Wei Fan,Ruirui Xing,Peng Zhou et al.
Wei Fan et al.
Glass has served as a cornerstone of modern civilization due to its exceptional optical transparency and structural integrity. Yet, its static covalent/ionic network fundamentally restricts environmental adaptability, presenting a critical ...
Carlos Fumero-Medina,Yaiza Pérez-Pérez,Lidia A Pérez-Márquez et al.
Carlos Fumero-Medina et al.
Rotaxanation is an efficient method to control the tetrazine-mediated inverse electron demand Diels-Alder (IEDDA) reaction. Tetrazine rotaxanes were synthesized in high yield by crown ether active template applied to the nucleophilic aromat...
Solvent Channels and Electric Fields Guide Proton Delivery to the Active Site of Heme Peroxidases [0.03%]
溶剂通道和电场引导质子向血红素过氧化物酶活性位点递送
Reynier Suardíaz,Shakir Ali Siddiqui,Hanna Kwon et al.
Reynier Suardíaz et al.
The active sites of heme enzymes have evolved to control the formation of highly reactive intermediates in oxidative catalysis. Proton delivery to the heme is essential, yet the mechanisms of proton delivery remain poorly understood. Here, ...
Sub-2 Nm Palladium Phosphide: A Highly Active and Selective Catalyst for the Hydrogenation of Furfural to Furfuryl Alcohol [0.03%]
亚2nm钯磷化物：戊二醛加氢制备糠醇的高效高选择性催化剂
Sifan Bi,Shuang Zhou,Tao Liu et al.
Sifan Bi et al.
Phosphidation offers a promising approach to tailor noble metal properties for high catalytic selectivity, yet achieving highly dispersed noble metal phosphides with efficient atom utilization remains challenging. Herein, we report the cont...
Synthesis, Biological Activity, and Molecular Dynamics Simulations of LNA-Charge Neutral Linkages for Enhanced Splice-Switching Antisense Oligonucleotides [0.03%]
LNA-电荷中性连接体的合成、生物活性及分子动力学模拟用于增强剪接转换反义寡核苷酸
Alice Kennett,Lillian Lie,Martin Flerin et al.
Alice Kennett et al.
Antisense oligonucleotides are promising therapeutic agents for a range of diseases, having found special clinical success for splice-switching genetic conditions such as spinal muscular atrophy and Duchenne muscular dystrophy. However, nov...
Unlocking Cryogenic Flexibility in Organic Crystals via Photoinduced E→Z Isomerization [0.03%]
利用光诱导E→Z异构化提高有机晶体的低温塑性
Jiang Peng,Jing Yang,Chengde Ding et al.
Jiang Peng et al.
Dynamic tuning of mechanical properties in organic crystals remains a major challenge due to their intrinsic brittleness and rigidity, especially at cryogenic temperatures. Herein, we report the first example of light-induced cryogenic elas...