Metal-Phenolic Coatings Enable Universal Design of Spherical Nucleic Acids [0.03%]
金属酚类涂层可实现球形核酸的通用设计
Chaojian Chen,Taokun Luo,Ye Zhang et al.
Chaojian Chen et al.
Spherical nucleic acids (SNAs), structures consisting of a nanoparticle core chemically modified with a dense shell of nucleic acids, are central to the fields of structural nanomedicine and colloidal crystal engineering with DNA. However, ...
Cation-Anion Redox Co-Modulation: Unlocking the Potential of All-Electrochem-Active Sulfur-Based Solid-State Batteries [0.03%]
阴阳离子协同调节：全电化学活性硫基固态电池的潜力解析
Guoliang Jiang,Xiaolin Xiong,Weiping Li et al.
Guoliang Jiang et al.
The capacity utilization of all-solid-state sulfur cathodes reveals a significant disparity between material and electrode levels due to the high proportion of inactive components required for electro-ionic transport. While the all-electroc...
Johannes Stephan,Samia Kahlal,Jean-Yves Saillard et al.
Johannes Stephan et al.
Monovalent gallium halides are intrinsically unstable compounds at room temperature and can only be generated in the gas phase at temperatures of about 1000 °C. Although they are isoelectronic to carbon monoxide, dinitrogen, and the cyanid...
Programming Dimensional Transitions in DNA Brick Crystals via Interfacial Connectivity [0.03%]
通过界面连接在DNA砖晶体中编程维度转换
Xin Huang,Yue Wang,Wenhe Ma et al.
Xin Huang et al.
The precise control of assembly dimensionality and macroscopic structural parameters remains a fundamental challenge in molecular self-assembly. Here, we introduce a programmable strategy to govern the 1D-to-2D dimensional transition and st...
Diastereoselective Synthesis of Axially Chiral Skipped Ene-Allenes Containing a Quaternary Stereocenter by Cyclopropene-Allene Metathesis [0.03%]
环丙烯-烯基 allenoid 交换反应立体选择性合成轴手性的含有季碳的跳跃烯-烯_allenoids
Bin Chen,Yang Zhou,Chun-Yu Ho et al.
Bin Chen et al.
Functionalized skipped ene-allenes (1,4-enallenes) bearing an all‑carbon quaternary stereocenter were prepared by a diastereoselective ring-opening metathesis of mesomeric cyclopropene and allene for the first time. A strategic pairing of ...
Janus Electronic State Ni Enable High-Level CO-Tolerance in Fuel Cells Toward Crude-Hydrogen Feeds [0.03%]
用于粗氢原料的燃料电池中能使钴耐受一氧化碳的能力达到高水平的 Janus 电子态镍
Pin Meng,Hao Huang,Siyan Chen et al.
Pin Meng et al.
Maximizing the utilization efficiency of surface-active atoms is essential for improving carbon monoxide (CO) tolerance of hydrogen oxidation reaction (HOR) catalysts. However, conventional active-site regeneration strategies suffer from po...
Novel Carborane Based Metal Organic Framework for Record Electronic Specialty Gas C2F6 Purification via Molecular Sieving [0.03%]
基于卡伯烷的新金属有机框架通过分子筛分创纪录地提纯电子特气C2F6
Jianan He,Lingyao Wang,Guangzu Xiong et al.
Jianan He et al.
The production of high-purity perfluoroethane (C2F6), an essential electronic specialty gas, requires the removal of its partially-fluorinated analog, pentafluoroethane C2F5H. This separation is exceptionally challenging due to their simila...
General Electrocatalytic Plastic and Biomass Refining via Synergistic Carbon-Carbon Bond Cleavage Over Oxygen Vacancies and Ni3+-O Octahedral Motifs in Tailored Spinel Nickel Cobalt Oxide [0.03%]
通过调整的尖晶石镍钴氧化物中氧空位和Ni3+-O八面体基序协同断裂碳-碳键进行通用电催化塑料和生物质精炼
Bin Liang,Jing Zhu,Jin Zhou et al.
Bin Liang et al.
Electrooxidation of recyclable carbon resources from plastics and biomass offers a promising route for value-added conversion via C-C bond cleavage to yield small organic acids. However, developing electrocatalysts with broad substrate appl...
Ketal Protection of Glycerol for Selective Electrosynthesis of Glyceric Acid in Highly Alkaline Media [0.03%]
酮烯醇式保护剂甘油的选择性电合成甘醇酸的研究
Jiamin Wang,Baokun Zhang,Kanglei Pang et al.
Jiamin Wang et al.
Electrocatalytic glycerol oxidation represents a sustainable route for glycerol valorization, yet high selectivity toward glyceric acid (GLA) remains challenging on non-noble-metal catalysts due to competing C─C bond cleavage and complex o...
Strong Modulation of Electronic States in IrO2 by Interstitial Carbon for Highly Active Acidic Water Oxidation [0.03%]
强碳掺杂IrO2电子态的第一性原理研究及优异的酸性水电氧化性能
Jianghao Kang,Luo Huang,Xuqian Zhao et al.
Jianghao Kang et al.
IrO2 as the most stable electrocatalyst for acidic oxygen evolution reaction (OER) suffers from its low activity and the limited abundance in earth crust. Doping is one of promising strategies to enhance the OER activity and stability of Ir...