Generalizing Vinyl Halide Cross-Coupling Reactions with Photoredox and Photoredox/Nickel Dual Catalysis [0.03%]
光氧化还原和光氧化还原/镍双催化促进的 vinyl 卤化物交叉偶联反应的研究
Kousik Das,Nayan Saha,Zhuofan Li et al.
Kousik Das et al.
Reliable, broadly applicable cross-coupling conditions that deliver the desired products with minimal optimization are essential in pharmaceutical research, where efficient synthesis accelerates lead discovery and late-stage diversification...
"Twisted" Terpolymer Donor Enabling High-Performance Intrinsically Stretchable Organic Solar Cells [0.03%]
“扭曲”型三元共聚物给体实现高性能本征可拉伸有机太阳能电池
Di Zhang,Zhi Wang,Junfeng Liu et al.
Di Zhang et al.
Intrinsically stretchable organic solar cells (is-OSCs) hold great potential for next-generation wearable power generators. Currently, high-efficiency polymeric donor materials are based on rigid planar conjugated backbones, which limits th...
Sustained, Reversible, and Adaptive Non-Equilibrium Steady States of a Dissipative DNA-Based System [0.03%]
耗散DNA系统的持续、可逆和自适应非平衡稳态
James D Nicholas,Erica Del Grosso,Andrew J deMello et al.
James D Nicholas et al.
Inspired by nature, researchers have developed several chemical fuel-driven supramolecular systems aimed at achieving improved kinetic control over their formation and functions. Alongside, DNA-based systems regulated by energy-dissipating ...
A Universal Voltage-Enhancement Strategy Based on Multifunctional Ligand-Mediated Modulation for Na-Layered Oxide Cathode [0.03%]
一种基于多功能配体介导调节的用于钠层状氧化物正极的通用电压提升策略
Yonglin Huo,Hao Guo,Zhuozheng Hong et al.
Yonglin Huo et al.
Sodium-ion batteries (SIBs) have emerged as promising energy storage solutions due to resource abundance and low cost, yet their practical deployment is hindered by limited operating voltages of cathode materials. Herein, we propose a unive...
Heteroporous Donor-Acceptor Covalent Organic Framework Cathode for High-Rate-Capacity Lithium-Ion Battery [0.03%]
用于高容量锂电池的杂孔给体-受体共价有机框架正极材料
Ju Duan,Likuan Teng,He Liu et al.
Ju Duan et al.
Covalent organic frameworks (COFs), a conspicuous porous material, harvest great promise for rechargeable batteries, owing to well-defined pore structure and structural precision. However, designing high-rate-capacity COF cathode by balanci...
Transforming Crowded Coacervates into Multi-Compartmental Hybrid Microreactors for Practical Enzymatic Catalysis [0.03%]
用于实际酶催化的拥挤液滴聚集体向多隔室杂化微反应器的转化
Xiaoting Hao,Jing Li,Bing Zhang et al.
Xiaoting Hao et al.
Advancing the design and construction of artificial protocells with organized complexity, diverse functionality and practical applicability is urgently demanded in vitro synthetic biology and bioengineering but remains a grand challenge. He...
Tailor-Made Host-Guest Organic-Inorganic Hybrid Antimony Halide Enables Efficient Light-Emitting Diodes [0.03%]
客体-主体有机无机杂化化合物抗imony卤素材料实现高效发光二极管
Weihong Chu,Zhuangzhuang Ma,Qicong Zhou et al.
Weihong Chu et al.
Organic-inorganic antimony (Sb) halides are garnering increasing interest for lead-free perovskite light-emitting diodes (LEDs), but the non-radiative recombination and poor charge transport are hard-treat case to restrict their electrolumi...
Cyclometalating Ligand Affords NIR Absorption in Ruthenium Complexes for Type-I Photodynamic Therapy [0.03%]
cyclometallating配体使钌配合物在I型光动力治疗中获得NIR吸收
Zongwei Zhang,Xiaolong Zeng,Xiao Zhou et al.
Zongwei Zhang et al.
The development of NIR photosensitizers (PSs) based on Ru complexes with Type-I process holds substantial promise for photodynamic therapy (PDT) of cancer, though this breakthrough remains unrealized to date. Herein, a pair of cyclometalate...
Sustained Release of Underpotential Deposition Initiators for Ah-Level Zinc Metal Batteries [0.03%]
用于Ah级锌金属电池的欠电位沉积引发剂的持续释放技术
Junjie Ba,Xiaoyan Li,Junpeng Li et al.
Junjie Ba et al.
Electrolyte additives effectively stabilize aqueous zinc-ion batteries (AZIBs), yet their depletion during long-term cycling leads to eventual battery failure. Here, we address this common issue through sustained release of underpotential d...
Olefin Ligand Metathesis for Colloidal Emissive Nanocrystals with Enhanced Stability and Photosensitivity [0.03%]
用于增强稳定性和光敏感性的胶体发光纳米晶体的烯基配体元化反应
Seongbeom Yeon,Yoseph Kim,Abdessamad El Adel et al.
Seongbeom Yeon et al.
High-resolution patterning of colloidal perovskite nanocrystals (PNCs) is essential for next-generation display technologies, yet conventional approaches relying on exogenous photosensitive ligands or additives often compromise optical prop...