High-Fidelity Profiling of Multiple Nearby Mutations via Cooperative Recognition [0.03%]
基于协同识别的多重临近突变高保真谱图绘制方法
Xuhan Xia,Hao Yang,Zhen Zeng et al.
Xuhan Xia et al.
Detection methods with single-nucleotide specificity are essential tools for nucleic acid analysis in diverse clinical and biological settings. However, both hybridization-based and enzyme-based methods are only effective for discriminating...
Dihydroxanthene-Derived Dioxetane Chemiluminophores for Activatable in Vivo Imaging [0.03%]
用于活体激活型成像的二羟基ксанthen衍生的二氧杂环丁烷化学发光剂
Kongke Liao,Lina Zhang,Jie Jiang et al.
Kongke Liao et al.
Chemiluminophores with optimal chemiluminescence properties and versatile structures adaptable into activatable chemiluminescent probes are of particular interest for biosensing and imaging owing to their high sensitivity and signal-to-nois...
A Broadly Applicable Strategy to Aminate Azines Enabled by Electronically Tuned Phosphine Reagents [0.03%]
一类电子可调磷试剂促进的叠氮𬭩盐胺化反应通用策略
Ren-Rong Liu,Jeffrey N Levy,Andrew McNally
Ren-Rong Liu
We describe a strategy for aminating pyridines and other azines via phosphonium salt intermediates. Precisely tuning the electronic properties of the phosphonium ion was key for C─N bond formation via an SNAr-halogenation, SNAr-amination s...
Nikolai Diukarev,Erik Boinowitz,Jonas Feldmann et al.
Nikolai Diukarev et al.
The origin of life in the Hadean eon required the formation of amino acids and nucleosides among the key molecules of life. It is assumed that highly unsaturated carbon and nitrogen containing feedstock molecules, which form in a strongly r...
Stereoselective Self-Assembly of a Topologically Chiral [6]Catenane with 18 Crossings [0.03%]
拓扑手性[6]索烃的对映选择性自组装（具有18个交叉点）
Zheng Cui,Li-Yan Hao,Yi-Fan Yuan et al.
Zheng Cui et al.
Mechanically interlocked molecules (MIMs) exhibit unique properties and functions arising from their structural entanglement, features of which are absent in their individual components. However, synthesizing topologically complex architect...
Photo-Mediated Silacyclization by Wavelength-Dependent Selective C─F or C─H Functionalization [0.03%]
波长依赖的C-F或C-H选择性官能团化介导的光硅环化反应
Gan Wang,Ye Yuan,Chu Wang et al.
Gan Wang et al.
Silacycles have gained significant attention within the synthetic community due to their pivotal roles in medicinal chemistry and materials science. Despite recent advancements, the defluorosilylation of aryl fluorides with hydrosilanes and...
Ion-Mediated Self-Healing Strategy Enabling Efficient and Stable ETL-Free Perovskite Solar Cells [0.03%]
阳离子介导的自愈策略实现高效稳定的无ETL钙钛矿太阳能电池
Mengjiao Lan,Jiakang Zhang,Cheng Peng et al.
Mengjiao Lan et al.
Perovskite solar cells without electron transport layers (ETL-free PSCs) have garnered increasing attention in recent years due to their simplified fabrication process and low production costs. However, non-radiative recombination of charge...
Acid-Alkaline Double Electrolytes for High-Energy Aqueous Proton Batteries [0.03%]
用于高能量水电解质质子电池的酸碱双电解质
Ziyue Li,Fengmei Wang,Jinyu Yang et al.
Ziyue Li et al.
Aqueous proton batteries offer a promising energy storage solution due to their inherent safety, rapid ion mobility, and low cost. However, their performance is largely constrained by water's limited electrochemical stability, restricting o...
Chiral Molecules Induce Enantiomorphic Lattice Helicity in Chiral 0D Tin Bromide Crystals [0.03%]
手性分子诱导的手性零维溴化锡晶体对映异型晶格螺旋度
Ramavath Babu,Haoyuan Xu,Berta Covelo et al.
Ramavath Babu et al.
Chiral organic-inorganic hybrid metal halides have emerged as a promising class of materials for spin-controlled optical and optoelectronic effects and related applications. Chiral hybrid metal halides generally crystallize in non-helical s...
Tuning Surface Concentrations of Building Units to Enable the Cathodic Deposition of Metastable ZIF-L Films for Gas Separations [0.03%]
通过调节构建单元的表面浓度实现不稳定的ZIF-L薄膜的阴极沉积以用于气体分离
Sijie Xie,Xiaoyu Tan,Nicolas Chanut et al.
Sijie Xie et al.
Cathodic deposition is an emerging technique for the preparation of metal-organic framework (MOF) films. However, monitoring and controlling the concentrations of MOF building units (i.e., metal nodes and ligands) on the electrode surface r...