Regulation of Relay Catalytic Mechanism for Efficient Methanol Oxidation Reaction [0.03%]
高效甲醇氧化反应的继电器催化机制调控研究
Guangliang Lin,Hongye Qin,Xuejie Cao et al.
Guangliang Lin et al.
The methanol oxidation reaction serves as a representative model for multistep catalytic processes involving diverse intermediates. Catalyst design strategies that spatially arrange discrete active sites, analogous to relay runners, facilit...
Halogenation-Engineered Acceptor Enables 20.14% Efficiency in Hydrocarbon-Solvent Processed OSCs: From Binary Trade-Offs to Ternary Synergy in Exciton and Energy Loss Management [0.03%]
卤素工程化受体使非氯溶剂处理的OSC效率突破20%，从二元权衡到三元协同的激子和能量管理研究
Jun Zhang,Weifei Wei,Zhenghui Luo et al.
Jun Zhang et al.
Halogenation emerges as a key strategy to enhance the performance of organic solar cells (OSCs) by tuning molecular packing, energy levels, and charge dynamics. Here, we report three new benzo[a]phenazine-core small-molecule acceptors, name...
Encapsulation Enhances the Quantum Coherence of a Solid-State Molecular Spin Qubit [0.03%]
封装增强固态分子自旋量子比特的量子相干性
Abinash Swain,Leoní A Barrios,Yulia Nelyubina et al.
Abinash Swain et al.
Spins within molecules benefit from the atomistic control of synthetic chemistry for the realization of qubits. One advantage is that the quantum superpositions of the spin states encoding the qubit can be coherently manipulated using elect...
Full P4 to P3- Reduction with a Redox-Active Metal Crown Complex [0.03%]
全P4到P3的还原，具有氧化还原活性金属冠醚配合物参与
Johannes Maurer,Marcel A Schmidt,Michael Nägel et al.
Johannes Maurer et al.
Traditional bulk syntheses of phosphorus compounds start with P4 to PCl3 oxidation but more sustainable methods cleave P─P bonds reductively. This generally results in larger polyphosphide Zintl anions: Pm n-. We report a relatively select...
Cobalt Polypyridyl-Enabled Highly Regioselective α-Heteroarylation of N,O-Containing Aliphatics Through Photoelectrocatalysis [0.03%]
光介电催化N,O杂原子含活泼亚甲基的α-芳基化反应研究
Wen Lin,Ting Lv,Zhizi Wang et al.
Wen Lin et al.
The regioselective functionalization of C─H bonds at positions with nearly identical chemical environments remains a pivotal challenge in synthetic chemistry. While conventional hydrogen atom transfer (HAT) strategies dominate current meth...
Discrete Actuation of Water-Responsive Crystalline Metal-Peptide Frameworks [0.03%]
具有水分响应结晶金属-肽框架的离散致动能力
Hui Yuan,Yiming Tang,Elma Naranjo et al.
Hui Yuan et al.
Engineering guest-responsive materials capable of controlled and precise sorption behavior and structural deformation in response to external stimuli is imperative for various applications. However, existing systems often exhibit complex, u...
Susana Ibáñez,Mercè Alemany-Chavarria,Louise N Dawe et al.
Susana Ibáñez et al.
Gaining insight into the dynamic behavior of supramolecular systems is essential for understanding selective guest encapsulation and for the rational design of nanodevices capable of precise, controllable motion at the molecular scale. In t...
Ligand Engineering-Enhanced Catalytic Activity of Octanuclear Zn(II)-Siloxane Clusters for Advanced Lithium-Sulfur Batteries [0.03%]
配体工程增强八核Zn(II)-硅氧烷簇在锂硫电池中的催化活性
Peng Wang,Tianyang Xu,Shenglin Xiong et al.
Peng Wang et al.
Polynuclear metal clusters (PMC) with atomically defined architectures exhibit unique electrochemical catalytic behaviors in lithium-sulfur battery (LSB). Nevertheless, the precise fabrication of PMC with tailored configurations, and a comp...
Gadolinium and Europium Doped Chiral Perovskite Films with Magnetic Circular Dichroism and Circularly Polarized Luminescence for Information Encryption Applications [0.03%]
用于信息加密应用的具有磁圆二色性和圆偏振发光的手性钙钛矿薄膜 gadolinium 和 europium 掺杂
Dan Liang,Fang Peng,Qiaodan Du et al.
Dan Liang et al.
All inorganic lead halide perovskite (CsPbX3) has become a hot topic in chiral optics for its high quantum yield and tunable luminescence. The environmental degradation tendency and lack of magneto-optical coupling mechanism of lead-based p...