Creating Abundant Open Metal Sites in MOFs by Dual-Coordination Design for Enhanced Electrocatalytic Activity [0.03%]
通过双配位设计在MOF中创建丰富的开放金属位点以增强电催化活性
Danyu Guo,Jieting Ding,Chenghong Hu et al.
Danyu Guo et al.
Metal-organic frameworks (MOFs) with well-defined crystalline structures offer ideal platforms to unravel structure-property relationships, but their low density of accessible metal sites limits catalytic activation. Efforts to generate ope...
Polymerization of L-Arginine into Nanomicelles for Immunometabolic Engineering of Adoptive Macrophages in Solid Tumor Therapy [0.03%]
L-精氨酸聚合形成纳米胶束以用于免疫代谢工程在固态肿瘤疗法中适应巨噬细胞
Jia-Xin An,You-Teng Qin,Ying Tang et al.
Jia-Xin An et al.
The therapeutic efficacy of adoptive cell therapy is highly dependent on the status and function of the infused cells. However, insufficient nutrient availability within the immunosuppressive tumor microenvironment (TME) often impedes these...
Iva Manasi,Marco Bortoli,Daniel T Bowron et al.
Iva Manasi et al.
Due to their high reactivity, organolithium and organomagnesium addition to ketones is usually performed under inert atmosphere at low temperature. Recent work has shown that, by dissolving the substrate in deep eutectic solvents (DES), the...
A New Phase Indium Tin Oxide (ITO) Activated Selective CO2 Reduction into Formate for Underwater Antifouling Glass [0.03%]
一种新型的掺锡氧化铟（ITO）活化二氧化碳选择性还原为甲酸的玻璃用于水下防污
Jinxin Chen,Wenxiang Zhu,Mengling Zhang et al.
Jinxin Chen et al.
Designing unique electrocatalysts that utilizes carbon dioxide reduction reaction (CO2RR) for real applications is highly appreciated, yet still suffers from low selectivity, stability, and compatibility. Herein, we first report a new two-d...
Cationic-Zwitterionic Polymer Electrolytes with Enhanced Ionic Conductivity and Lithium-Ion Selectivity for Solid-State Batteries [0.03%]
用于固态电池的具有增强离子电导率和锂离子选择性的阳离子两性离子聚合物电解质
Tuo Xiao,Jinlin Xian,Zehua Yu et al.
Tuo Xiao et al.
Polymer electrolytes are attractive for solid-state lithium-metal batteries owing to their favorable interfacial compatibility and scalable processability. However, the concurrent realization of high ionic conductivity and a high lithium-io...
Selectively Modulating the Donor and Acceptor Aggregation Behaviors Through Solid Additive Isomerization Engineering for Organic Solar Cells Exceeding 20% Efficiency [0.03%]
基于固相添加剂异构化工程的受体和给体分子取向调控实现超过20%效率的有机光伏电池
Keli Shi,Haicui Liu,Shucheng Qin et al.
Keli Shi et al.
Regulating the film morphology is essential for achieving high-performance organic solar cells (OSCs). Given the distinct features of donor and acceptor materials, designing solid additives to selectively control the aggregation behaviors o...
Photocatalytic H2O2 Production with a Nearly 2% Solar-to-Chemical Conversion Efficiency via a Dedicated Construction of Redox Centers in Metal-Organic Frameworks [0.03%]
通过构建金属有机框架中的氧化还原中心进行高效光催化产生双氧水（接近2％的太阳能化学转化效率）
Xiangjian Meng,Fangshuai Chen,Anwang Dong et al.
Xiangjian Meng et al.
Hydrogen peroxide (H2O2) is a green oxidant widely used in a variety of industries. Photocatalytic generation of H2O2 from water and oxygen by sunlight is an appealing strategy compared to the high energy consumption of the industrial anthr...
Dendritic Pillar[6]Arenes with Fixed Planar Chirality for Stereoselective Inclusions in Water: A Case of Facile Differentiation of Cocaine Adulterants, Levamisole and Dexamisole [0.03%]
具有固定平面手性的树状支柱六聚苯并稠环化合物：水相中对可卡因掺杂物levamisole和dexamisole的便捷区分与立体选择性包合研究
Nitesh Kumar,Pratik Karmakar,Matthew D Politeski et al.
Nitesh Kumar et al.
We describe the preparation, conformational dynamics, and stereoselective recognition characteristics of water-soluble pillar[6]arenes pS-212- and pR-212-. These two novel and diastereomeric cavitands comprise a 2,5-bis(ethoxy)pillar[6]aren...
Intramolecular Phosphinyl-Zincation of Alkynes: A Powerful Entry to Benzophosphole Oxides [0.03%]
分子内膦基锌化-炔氢官能团化反应合成苯并磷杂环化合物
Liyao Ma,Sonia Mallet-Ladeira,Julien Monot et al.
Liyao Ma et al.
Upon reacting ortho-alkynylated secondary arylphosphine oxides with Et2Zn, we discovered that P(O)─H activation is followed upon gentle heating by phosphinyl-zincation. This unprecedented transformation stands as a phosphorus version of th...