Preferential Texture of Surface Coating on Zn Anodes for Advanced Aqueous Batteries: Small Change but Big Gain [0.03%]
用于先进水系电池的锌阳极表面涂层的择优纹理：小变化带来大收益
Xiaohan Zhao,Zelong Gong,Gulian Wang et al.
Xiaohan Zhao et al.
Zinc metal, as the mainstream anode material of aqueous batteries, faces severe side reactions and notorious dendrite growth. Surface passivation of Zn anodes with a protective layer is one of the effective strategies to address these issue...
P450 Enzyme LyoI Performs Hydro-2,2'-Bifuran Oxidation in the Polyether Ionophore Lysocellin [0.03%]
P450酶Lyoi能催化多醚类离子载体石菌素的羟基-2，2'-联呋喃氧化反应
Michelle H Rasmussen,Søren L B Møller,Esben B Svenningsen et al.
Michelle H Rasmussen et al.
Polyether ionophores are potent antimicrobials, albeit also cytotoxic against mammalian cells. We have identified several polyether ionophores containing a common hydro-2,2'-bifuran-2-ol (hemiketal) moiety, which cannot be derived from the ...
Exercise Modulates Exocytosis: Chemical Insights from the Intracellular Vesicle Perspective [0.03%]
运动调节胞外运输：来自细胞内囊泡的化学见解
Ran Liu,Xiulan He,Jing Liu et al.
Ran Liu et al.
The systemic benefits of exercise are partially attributed to exerkines release via extracellular vesicles, prompting extensive research on the effects of exercise on these vesicles. However, whether and how exercise modulates intracellular...
Enhancement of Emission Efficiency and Color Tuning by Mixing Platinum(II) and Palladium(II) Complexes in a One-dimensional Chain [0.03%]
通过一维链中混合铂(ii)和钯(ii)配合物来提高发射效率和调节颜色
Kaito Segawa,Masaki Yoshida,Hiroto Kise et al.
Kaito Segawa et al.
A series of mixed metal crystals comprising square-planar platinum(II) and palladium(II) complexes, K[M(CN)2(dFppy)]·H2O (M = Pt2+, Pd2+; dFppy = 2-(4,6-difluorophenyl)pyridinate), were prepared, and their unique luminescence properties-em...
Bio-Transport Regulation Inspired 5-Fluorouracil Keto to Enol Tautomerism Achieving High Proton Conductivity [0.03%]
生物传输调控启发的5-氟尿嘧啶酮式到烯醇式互变异构实现高强度质子传导性
Hui Gao,Hao Zhang,Jian Zhang et al.
Hui Gao et al.
The strategic modulation of proton transport kinetics and precise control of migration energy barriers in metal-organic frameworks (MOFs) are essential for developing next-generation proton conductors. Inspired by biological proton channels...
Yige Guo,Tianfu Liu,Minggao Xu et al.
Yige Guo et al.
Catalytic methane (CH4) upgrading to C2+ products has attracted widespread interest. However, non-oxidative coupling and oxidative coupling of CH4 are limited by coking and over-oxidation, respectively. In this work, we propose an efficient...
Nitrogen-Induced Hydrogen Bonding Supramolecular Network for Ultra-Stable Ammonium Ion Storage [0.03%]
氮诱导的氢键分子网络用于超稳定存储铵离子
Shaopei Yang,Wenkai Zhao,Yongqi Mi et al.
Shaopei Yang et al.
Aqueous ammonium ion batteries (AAIBs) are emerging as sustainable energy storage systems due to their inherent safety and eco-friendliness. Organic electrode materials demonstrate significant potential as anode materials due to their struc...
Machine Learning Guided Assembly of a Nested Gd20@Gd32 @Ni36 Cluster via Urea Controlled Carbonate Release [0.03%]
基于尿素控制碳酸盐释放的机器学习指导的巢合物Gd20@Gd32@Ni36组装
Ming-Qiang Qi,Rui-Le Yang,Jing-Zhou Wu et al.
Ming-Qiang Qi et al.
Lanthanide-based polyhedral clusters are of great interest due to their unique geometries and functional properties, but their controlled synthesis remains a major challenge. Here, we report a nested three-shell cluster, [Gd52Ni36(MeIDA)36(...
Adjusting Chemical Hardness-Softness Balance of Electrolyte to Enable High-Voltage Reversible Fluoride Ion Batteries [0.03%]
通过调节电解液的化学硬度和软度实现高电压可逆氟离子电池
Guyue Li,Huiyan Zha,Decheng Li et al.
Guyue Li et al.
Fluoride ion batteries (FIBs), as a promising next-generation high-energy-density storage technology, have attracted significant attention. However, developing an ideal fluoride-ion electrolyte that suppresses the β-H abstraction (caused b...
Regiodivergent Ligand-Controlled Cobalt-Catalyzed Reductive Hydroxymethylation of Alkynes with Aqueous Formaldehyde [0.03%]
区域特异的配体调控钴催化炔烃有水甲醛的选择性羟甲基化反应
Ning-Xin Guo,Zheng-Yang Gu,Meng-Wei Zhu et al.
Ning-Xin Guo et al.
Allylic alcohols are versatile and essential building blocks in synthetic chemistry, widely used for the preparation of complex molecules, pharmaceuticals, and materials. We report here a regiodivergent reductive hydroxymethylation of termi...