Unravelling the Functional Diversity of Type III Polyketide Synthases in Fungi [0.03%]
解开真菌III型聚酮合酶功能多样性的秘密
Nika Sokolova,Stepan S Denisov,Thomas Hackl et al.
Nika Sokolova et al.
Type III polyketide synthases (T3PKSs) are enzymes that produce diverse compounds of ecological and clinical importance. While well-studied in plants, only a handful of T3PKSs from fungi have been characterised to date. Here, we developed a...
Photoactivatable Synthetic Exosomes for RNA-Based Communication Between Artificial Cells and Living Cells [0.03%]
可用于人工细胞与活细胞间基于RNA通信的光激活合成外泌体
Alexander B Cook,Siwen Sun,Yudong Li et al.
Alexander B Cook et al.
Artificial cells are self-assembled microstructures engineered to replicate the functions of natural cells, such as the capacity to interact and communicate. Until now, communication between artificial and living cells has mainly been based...
Competitive Chirality Induction in Two-dimensional Germanium Iodide Perovskites Enabling Highly Anisotropic Nonlinear Optical Response [0.03%]
二维锗碘钙钛矿中的竞争性手性诱导实现高度各向异性的非线性光学响应
Yan Fu,Kai Li,Xiaoqi Li et al.
Yan Fu et al.
Chiral metal halide perovskites (CMHPs) are a promising class of chiroptical materials with significant potential applications in chiral-optoelectronic and chiral-spintronic devices. However, their chirality induction generally stems from t...
Circumventing Radical Generation on Fe-V Atomic Pair Catalyst for Robust Oxygen Reduction and Zinc-Air Batteries [0.03%]
用于稳定氧还原和锌空气电池的Fe-V原子对催化剂及其抑制活性位点突变的机制研究
Lan Ran,Yichen Zhang,Wenming Tong et al.
Lan Ran et al.
Iron-nitrogen-carbon (Fe-N-C) catalysts are considered the most active platinum-free alternative for oxygen reduction reaction (ORR), yet the generated reactive oxygen species (ROS) from general mechanistic pathway rapidly impair the ORR ac...
Photochemistry-Enabled Nitrogen-Assisted Organostibines as an Efficient Alkyl Radical Precursor: Mechanistic Insights and Synthetic Applications [0.03%]
基于光化学的氮助有机砷烷作为高效的烷基自由基前体：机制见解及合成应用
Niu Tang,Xinyu Li,Chenghan Li et al.
Niu Tang et al.
Organostibines exhibit significant potential as functional handles for the construction of C─C-rich scaffolds owing to their orthogonal and robust reactivity features. At present, the transformation of C(sp2)/C(sp)─Sb bonds into C─C bond...
Reduced Pressure Ionization Enhances Native Mass Spectrometry of Proteins and Protein Complexes [0.03%]
减压电离增强蛋白质和蛋白质复合物的本征质谱分析
Jake P Violi,Chong Zhang,William A Donald
Jake P Violi
Native mass spectrometry (MS) enables the analysis of protein interactions in complex biological mixtures. However, nonvolatile salts and buffers commonly present in such samples can cause ion adduction, peak broadening, and reduced signal ...
Distinct Hole and Electron Transport Anisotropy in Ambipolar Nickel Dithiolene-Based Semiconductor [0.03%]
基于镍二硫醇烯的本征半导体中载流子双极输运的各向异性
Masatoshi Ito,Tomoko Fujino,Toshiki Higashino et al.
Masatoshi Ito et al.
Understanding anisotropic charge transport in molecular semiconductors is crucial for device optimization, yet its intricate dependence on orbital-specific intermolecular interactions and molecular packing remains a challenge, especially in...
Reem Nsouli,Gaurav Galiyan,Laura K G Ackerman-Biegasiewicz
Reem Nsouli
High-throughput experimentation (HTE), the miniaturization and parallelization of reactions, is a valuable tool for accelerating diverse compound library generation, optimizing reaction conditions, and enabling data collection for machine l...
Fluorine Modified Zeolitic Imidazolate Framework Enables Long-Life Zn-I2 Batteries by Suppression of Polyiodide Shuttle [0.03%]
氟改性斜方沸石咪唑酸酯框架通过抑制多碘化物穿梭作用实现长寿命锌碘电池
Haoxiang Di,Yongling An,Jiarui Yang et al.
Haoxiang Di et al.
Aqueous zinc-iodine (Zn-I2) batteries have emerged as a promising candidate for large-scale energy storage applications, owing to their inherent safety, cost-effectiveness, and high specific capacity. However, their commercial implementatio...
Selective Chemical Manipulation of Mannosyl- and Galactosyl-Queuosine in tRNAs of Living Cells [0.03%]
活细胞中tRNA甘露糖基和半乳糖基-队苷酸的选择性化学操控
Alexander Pichler,Elsa Peev,Qingyi Ge et al.
Alexander Pichler et al.
Queuosine is a hypermodified nucleoside found in the anticodon loop of tRNAs decoding the amino acids His, Asn, Tyr, and Asp. In tRNATyr, the homoallylic 2-hydroxyl group of the cyclopentene ring carries an additional β-galactose, while in...