A Chemical Glycoproteomic Approach Decrypts Urinary Extracellular Vesicle Surfaceome for Prostate Cancer Diagnosis and Grading [0.03%]
基于化学糖组学解析尿源外泌体表面蛋白的前列腺癌诊断与分级新方法
Yuhan Cai,Aixiang Bu,Shanying Han et al.
Yuhan Cai et al.
Extracellular vesicle (EV) surface proteins serve as the fundamental signaling mediators, determining the communication function of EVs. The selective and in-depth exploration of EV surface proteome (surfaceome) is highly compelling but rem...
Late-Stage Oxidation of C(sp3)─H Bonds with High Efficiency and Alkyl Group Dihydroxylation of Complex Molecules [0.03%]
高效C(sp3)─H键的后期氧化及复杂分子的烷基二羟基化反应
Yi Cheng Kang,Dmitriy M Volochnyuk,Serhiy V Ryabukhin et al.
Yi Cheng Kang et al.
The late-stage oxidation of C(sp3)─H bonds is highly valuable for modulating the solubility and binding of bioactive compounds and for diversification of complex molecules. Undirected methods for C(sp3)─H oxidation are valuable for the in...
Tuning the Adsorption of H and OH on Ruthenium Aerogel to Boost the Alkaline Hydrogen Evolution [0.03%]
调控钌气凝胶上H和OH吸附以提升碱性电解水制氢性能
Yuanwu Liu,Lirong Wang,Volodymyr Shamraienko et al.
Yuanwu Liu et al.
Ruthenium (Ru) is an ideal alternative to platinum for the alkaline hydrogen evolution reaction (HER) due to its exceptional catalytic performance. However, during the reaction, the excessively strong adsorption of proton (H) and hydroxyl (...
Topology Regulation of Donor-Acceptor Conjugated Polymers for Solar-Driven Hydrogen Production [0.03%]
供体-受体共轭聚合物的拓扑调节用于太阳能驱动氢气生产
Fangxin Yin,Wang Wang,Jianjun Zhang et al.
Fangxin Yin et al.
Conjugated polymers, especially those with a donor-acceptor (D-A) structure, are emerging as potent photocatalysts for solar-to-chemical energy conversion. However, even constructed with identical D-A building blocks, conjugated polymers wi...
Bi─O Bridges Trigger Lattice Strain-Electronic Synergy at Inherent In Sites in ZnIn2S4 for Boosting Solar-to-H2O2 Conversion [0.03%]
生物氧桥触发ZnIn2S4中固有In位点的晶格应变-电子协同作用以增强太阳能转化为H2O2反应
Fangyuan Chen,Gaoqing Cao,Qian Liu et al.
Fangyuan Chen et al.
Artificial H2O2 photosynthesis without sacrificial agents represents a promising yet challenging route for sustainable chemical production, hindered by low solar-to-chemical conversion (SCC) efficiency (natural photosynthesis is only ∼0.1%...
Generally Grafting Hydrophobic Polymer Brushes in Pure Water Through SIP of Phase Transfer Delivered Monomers [0.03%]
通过相转移传递单体的溶液插层聚合在纯水中嫁接疏水性聚合物刷一般化研究
Huayi Zeng,Menglu Chen,Xiaoliang Gou et al.
Huayi Zeng et al.
Hydrophilic and hydrophobic polymer brushes hold significant potential in antifouling, energy, medical, and lubrication applications. Because of rigorous polymerization conditions and requirements of organic solvents, research on hydrophobi...
Rational Synthesis of Photocatalytic Acridinium-Based Covalent Organic Frameworks via Single-Atom Skeletal Editing [0.03%]
通过单原子骨架编辑合理合成光催化吖啶基共价有机框架
Yimin Pan,Yifan Dong,Zhenze Yang et al.
Yimin Pan et al.
The rational synthesis of covalent organic frameworks (COFs) with customized functionalities and enhanced stability requires innovative bond-forming strategies beyond conventional dynamic covalent chemistry. Herein, we report a novel single...
Arun Kumar Manna,Susmita Kundu,Komal Jindal et al.
Arun Kumar Manna et al.
Gas permselective membranes are inherently constrained by a trade-off between permeability and selectivity. Overcoming this limitation is key to enabling broader industrial adoption, and advanced porous materials-particularly metal-organic ...
Site-Selective α─C─H Functionalization of Saturated Heterocycles via Copper-Photoredox Catalysis [0.03%]
基于铜光氧化还原催化饱和杂环化合物α─位碳氢的选择性官能团化反应
Yi Lu,Ya-Jing Chen,Xu-Bing Li et al.
Yi Lu et al.
Site-selective α─C─H functionalization of saturated heterocycles is of particular importance in synthetic and medicinal chemistry, but the intrinsic chemical inertness of saturated heterocycles renders the transformation difficult. Furth...
Solution-Processable and Programmable Al8 Macrocycles for Advanced Dielectrics: Uniting High Permittivity, Minimal Loss, and Robust Moisture Resistance [0.03%]
可加工和编程的Al8大环用于高级介电材料：结合高介电常数，极低损耗和强耐潮性
Li-Min Cui,Ruiduan Ji,Jian Hao et al.
Li-Min Cui et al.
The development of polymer composite dielectrics exhibiting high dielectric constant, low dielectric loss, and excellent environmental stability is essential for enhancing field-effect transistor (FET) performance and reliability. While con...