In-Field Molecular Diagnostics of Plant Pathogens Using Bioluminescent CRISPR-Guided Caspase Assay [0.03%]
基于生物发光的CRISPR-Cas酶在植物病原体现场分子诊断中的应用研究
Yipin Hu,Haohao Yan,Yong Zhang et al.
Yipin Hu et al.
In-field molecular diagnostics of plant pathogens are critical for crop disease management and precision agriculture, but tools are still lacking. Herein, we present a bioluminescent molecular diagnostic assay capable of detecting viable pa...
A π-Conjugated Molecular Bridge Strategy for Constructing Efficient Hole Transport Pathways in Inverted Perovskite Solar Cells [0.03%]
一种π共轭分子桥策略在倒置钙钛矿太阳能电池中构建高效空穴传输路径
Yehua Zhang,Ying Tang,Zuhong Zhang et al.
Yehua Zhang et al.
Metal halide perovskite solar cells (PSCs) hold promise for next-generation photovoltaics but are restricted by suboptimal efficiency and poor long-term stability. In inverted PSC architectures, self-assembled monolayers (SAMs) are widely e...
Hydroalkylation of Unactivated Alkenes with Amides via Photoredox Catalysis and Triple Hydrogen Atom Transfer [0.03%]
光氧化还原催化和三氢原子转移催化的非活化烯烃与酰胺的羟基烷基化反应
Beibei Yi,He Zhang,Chunxiang Pan et al.
Beibei Yi et al.
Radical-mediated hydroalkylation of alkenes offers a more direct and atom-economical route to α-alkylated carbonyl compounds, enabling the construction of various drug scaffolds, natural products, and functional molecules. However, traditi...
Topology-Engineered Guide RNAs for Programmable Control of CRISPR/Cas Activity [0.03%]
拓扑工程引导RNA可编程调控CRISPR / Cas活性
Liang Cheng
Liang Cheng
CRISPR/Cas systems have transformed genome editing, yet achieving precise temporal and conditional control remains challenging. Traditional strategies involving linear guide RNAs (gRNAs) modified with multiple chemical groups throughout the...
Nickelaelectro-Catalyzed C─H Activation to β-Arylated Pyrroles via Multiple Dehydrogenation [0.03%]
镍催化吡咯β-芳基化脱氢反应
Kazuhiro Okamoto,Simon L Homölle,Tristan von Münchow et al.
Kazuhiro Okamoto et al.
Nickel electrocatalysis has emerged as a powerful strategy for sustainable C─H activation, offering an environmentally benign alternative to traditional methods based on stoichiometric oxidants. We, herein, report a nickela-electrocatalyze...
Host-Guest Metal Interaction in Cu-In Single Atom Alloy Switching Electrocatalytic CO2 Reduction Pathway [0.03%]
铜铟单原子合金中主机-客体金属相互作用及其对电催化二氧化碳还原路径的调控
Jia-Huan Du,Ziwei Liu,Tian Sheng et al.
Jia-Huan Du et al.
The catalytic behavior of alloy electrocatalyst is strongly influenced by host-guest metal interaction, which governs adsorption energy and product selectivity. However, in conventional bimetallic alloy systems, the catalyst composition and...
Proton Flux Engineering via Built-in Electric Fields in N-doped CuO@Co3O4@Ni(OH)2 Heterostructure for Rechargeable Zn-NO3 -/5-Hydroxymethylfurfural Multielectron Transfer Systems [0.03%]
基于内置电场的N掺杂CuO@Co3O4@Ni（OH）2异质结构在可充电锌-硝酸盐/ 5-羟甲基糠醛多电子转移系统中的质子通量调控研究
Wenbiao Wang,Fan Bai,Kaibin Chu et al.
Wenbiao Wang et al.
Electrocatalytic coupling of nitrate reduction (NO3RR) to ammonia with 5-hydroxymethylfurfural (HMF) oxidation to 2,5-furandicarboxylic acid (FDCA) enables simultaneous wastewater remediation and biomass valorization. However, developing ef...
Modulation of Interfacial Water at Gas-Liquid-Solid Interface for Water Electrolysis [0.03%]
调控气-液-固三相界面水结构促进水电解反应
Bin Wu,Kun Qi,Tristan Petit et al.
Bin Wu et al.
Renewable electricity-driven water electrolysis stands at the forefront of clean hydrogen production, playing a crucial role in achieving a net-zero carbon future. Interfacial water is fundamental to this process, dictating reaction kinetic...
Dynamic Fe─F Coordination Triggered Structure-Adaptive Fe-N-C for Efficient Oxygen Reduction Electrocatalysis [0.03%]
动态Fe─F配位调控结构适应型铁电催化剂高效氧还原性能研究
Xue Wang,Kai Li,Youze Zeng et al.
Xue Wang et al.
The sustainable and widespread developments of fuel cells require material innovation toward the sluggish oxygen reduction reaction (ORR). Although iron and nitrogen co-doped carbon material (Fe-N-C) is a promising alternative to scarce and...
Mechanistic Insight into Para-Substituent Control of Thermal Half-Lives in Arylazopyrazole Photoswitches [0.03%]
研究取代基对芳基吡唑𬭩光开关热寿命控制的机制洞察
Katharina Schlögl,Nadja K Singer,Dominik Dreier et al.
Katharina Schlögl et al.
Arylazopyrazoles are versatile photoswitches with excellent photochromic properties and tunable thermal half-lives, yet the mechanistic role of substituents in controlling thermal stability remains poorly understood. Here, we synthesized an...