Harnessing Electrocatalytic Coupling of Carbon Dioxide and Methanol for High-Efficiency Formic Acid Production [0.03%]
利用电催化CO₂与甲醇偶联高效制备甲酸
Zhikeng Zheng,Xiaobo Zheng,Ligang Wang et al.
Zhikeng Zheng et al.
The coupling of electrocatalytic CO2 reduction (ECR) and methanol oxidation reaction (MOR) presents a promising strategy for simultaneous cogeneration of formic acid (FA) at both cathode and anode. However, sluggish kinetics, low selectivit...
Selective Catalysis-Mediated Interface to Stabilize Antimony Atom-Cluster Anode for Robust Potassium-Ion Batteries [0.03%]
用于钾离子电池的稳定锑原子簇阳极的选择性催化介导界面
Song Chen,Fangrui Yu,Hongli Deng et al.
Song Chen et al.
Controlling the electrode-electrolyte interfacial behavior is crucial for achieving a high-quality solid electrolyte interphase (SEI) and ensuring sustainable battery performance. Here, we propose a selective catalysis strategy to stabilize...
Electrochemistry-Accelerated Water-Gas Shift Reaction on IrN4-RhN4 Dual Sites Catalysts for Efficient Hydrogen Production [0.03%]
电化学加速IrN4-RhN4双位点催化剂上水气变换反应高效制氢
Qie Liu,Liyuan Gong,Jingjing Wang et al.
Qie Liu et al.
The water-gas shift reaction (WGSR) is crucial to the hydrogen economy, which is hampered by the harsh conditions and complicated purification process. In this work, the spatially separated efficient CO conversion and high-purity H2 product...
Multifunctional Binding Interface Drives Near-Unity CO Selectivity in Acidic CO2 Electrolysis [0.03%]
多功能结合界面驱动酸性二氧化碳电解选择还原为一氧化碳
Zhengyuan Li,Yuting Xu,Xing Li et al.
Zhengyuan Li et al.
The electrocatalytic carbon dioxide (CO2) reduction is challenged by the parasitic hydrogen evolution reaction (HER) especially in acidic media. Here, we elaborate that redox-active isoindigo, acting as a multifunctional co-catalyst, can pr...
In-Built Compatible Electrode-Electrolyte Interphases for Quasi-Solid-State Li-SPAN Batteries [0.03%]
准固态锂-SPAN电池的内置兼容电极-电解质界面
Tao Zhang,Zhengyuan Shen,Xinhui Pan et al.
Tao Zhang et al.
Lithium-sulfur batteries have been regarded as a promising candidate for next-generation energy storage systems owing to their high energy density and low cost. Sulfurized polyacrylonitrile (SPAN) as a cathode material has received wide int...
Rare Mononuclear Lithium-Carbene Complex for Atomic Layer Deposition of Lithium Containing Thin Films [0.03%]
用于沉积含锂薄膜的罕见单核锂卡宾配合物
Jorit Obenlüneschloß,Nils Boysen,Karl Rönnby et al.
Jorit Obenlüneschloß et al.
Lithium is the core material of modern battery technologies and fabricating the lithium-containing materials with atomic layer deposition (ALD) confers significant benefits in control of film composition and thickness. In this work, a new m...
Tibor Szilvási [0.03%]
蒂博尔·席尔瓦西
Tibor Szilvási
Tibor Szilvási
"I am most proud of my group when they are the strongest critics of their own data… My favorite podcast is PodCAT (I do not listen to podcasts except this one because I know the people in it)…" Find out more about Tibor Szilvási in his I...
Mechanistic Divergence in Sulfur-Ligated Iron(III)-Alkylperoxo Reactivity: Aldehyde Oxidation Prevails over Deformylation [0.03%]
机理分歧：硫配位铁(III)烷氧基过氧化物催化醛氧化优先于脱甲酰基反应
Jagnyesh K Satpathy,Rolly Yadav,Payal Panwar et al.
Jagnyesh K Satpathy et al.
Metalloenzymes activate molecular oxygen within their catalytic cycles to generate a reactive species capable of substrate transformation. In many iron-containing enzymes, it is a high-valent iron(IV)-oxo complex that is synthesized from an...
Self-Medicating Molten-Salt Synthesis of Bulk-Stabilized High-Energy Cathodes for Li-Ion Batteries [0.03%]
用于锂离子电池的高能 cathodes 的自药熔盐合成法Bulk-Stabilized 高能阴极材料的自调法制备用于锂离子电池的高能量密度阴极材料
Xiaoqiao Li,Fanxiu Feng,Taiping Hu et al.
Xiaoqiao Li et al.
High-energy lithium-ion batteries necessitate stable Ni-rich layered cathodes, yet critical challenges such as lattice distortion and surface structure collapse remain unresolved. While conventional high-valence doping greatly alleviates su...
Dynamics of Metal-Metal Bond Dissociation in Pd-Pd and Ni-Ni Complexes: Reorganization and Redistribution Reactions of the Metalloradicals [0.03%]
金属-金属键断裂的动态过程——Pd-Pd和Ni-Ni配合物中金属自由基的重组与重分布反应
Tim Bruckhoff,Vincenz J Kohler,Felix Braun et al.
Tim Bruckhoff et al.
Dinuclear M(I)-M(I) complexes (M = Ni, Pd) may serve as stable reservoir forms for highly reactive mononuclear metalloradicals, which are of interest as potential catalytic species. However, their dissociation dynamics as well as the factor...