Giacomo Renno,Stefan Matile
Giacomo Renno
Supramolecular chemistry promises that insights into contact between molecules will open up new directions to approach significant questions in science and society. In this spirit, Kraus et al. report the translation of fundamentally new dy...
Phenylamine-1,2-Dioxetanes: Promising Class of Chemiluminescent Luminophores for Aqueous Sensing and Bacterial Detection [0.03%]
苯胺-1,2-二氧杂环丁烷：水相传感和细菌检测的化学发光材料
Maya David,Thomas Leirikh,Noa Naama et al.
Maya David et al.
Chemiluminescence offers distinct advantages for bioimaging and sensing, notably by eliminating the need for external light excitation and minimizing background interference. While the original phenoxy-1,2-dioxetanes have served as the corn...
Enantioselective Incorporation of Amine Fragments onto Quaternary Carbons via Metallaphotoredox Catalysis [0.03%]
基于金属光氧化还原催化的四级碳上手性胺片段的构建反应
Weisai Zu,Haoran Wu,Jingwen Huo et al.
Weisai Zu et al.
The enantioselective construction of quaternary carbon stereocenters bearing amine functionalities represents a significant challenge in organic synthesis despite their prevalence in pharmaceutically active compounds. Herein, we report a ve...
A Metal-Organic Polyhedron-to-Coordination Polymer Transition Revealed by 3D Electron Diffraction [0.03%]
三维电子衍射揭示的金属有机多面体到配位聚合物的转变
Matthew P Snelgrove,Beatriz Doñagueda Suso,Calum S Sangster et al.
Matthew P Snelgrove et al.
Porous metal-organic polyhedra (MOPs) have strong covalent and coordinate bonds that define the intrinsic pore of the cage. The intermolecular interactions between cages tend to be weaker, such that they rearrange during the solvent exchang...
A Versatile DNAzyme-Amplified Protease-Sensing Platform for Accurate Diagnosis of SARS-CoV-2 and Reliable Classification of Colorectal Cancer [0.03%]
一种用于准确诊断SARS-CoV-2和可靠区分结直肠癌亚型的多功能DNA酶放大蛋白酶检测平台
Benrui Weng,Yifei Wang,Qingqing Zhang et al.
Benrui Weng et al.
Peptide-based biosensors are widely used for in vitro detection of protease activity but often suffer from the limited sensitivity, poor accuracy, and incompatibility with point-of-care testing (POCT) devices. Herein, we developed a versati...
Cold-Captured Dynamic Hydration Networks in Oxime-Based Photoswitches: A Theoretical Challenge Uncovered by Rotational Spectroscopy [0.03%]
肟基光开关中的冷捕获动态水合作用网络：旋转光谱发现的理论挑战
Rita J C Roque,Nuno M Campos,Marcos Gouveia et al.
Rita J C Roque et al.
With the goal of manipulating (bio)chemical processes, photoswitches emerge as important assets in molecular nanotechnology. To guide synthetic strategies toward increasingly more efficient systems, conformational dynamics studies performed...
Synergistic t2g-to-π* Electron Transfer and Nanotube Engineering in Spinal Catalysts for Ultra-Efficient Chloride Evolution [0.03%]
用于超高效氯演化反应的脊状催化剂的协同t2g到π*电子转移和纳米管工程
Zhen Zhang,Fengming Zhou,Yupeng Wang et al.
Zhen Zhang et al.
Facing the massive energy consumption of over 200 TWh y-1 of chlor-alkali industry, developing high-activity and durable non-precious CER (chlorine evolution reaction) catalysts is urgently needed to address the high overpotentials and supp...
A Facile and Efficient Route to Achieve Polythiophene-Based Nanoparticles With Various Morphologies [0.03%]
一种实现基于聚噻吩的具有各种形态的纳米粒子的简单而有效的途径
Tianyu Zhang,Qingqing Hu,Jiaqi Yu et al.
Tianyu Zhang et al.
Polythiophene-based nanoparticles (PTNPs), a prominent class of conjugated polymer nanoparticles (CPNs) with remarkable optical and electronic properties, have gained significant attention in applications such as electronics and bioimaging....
Unveiling an Innovative Pathway for Enhancing Lithium-ion Conductivity of Li3PW12O40 Electrolyte via Pressure Modulation Strategy [0.03%]
通过压力调节策略增强Li3PW12O40电解质锂离子导电性的创新路径探究
Susu Duan,Hao Ma,Yan Li et al.
Susu Duan et al.
Solid-state lithium-ion batteries have raised considerable attention due to their great potential for the development of new energy storage devices with high energy density and safety. However, enhancing ion conductivity in solid-state elec...
Amorphous Silica Induced Loose CeO2 Clusters with Isolated Pt Atoms for Efficient Reverse-Water Gas Shift Reaction [0.03%]
无定形二氧化硅诱导类蜂窝状CeO₂载体负载孤立Pt位点高效催化逆水气变换反应
Jiwei Lei,Zihe Wu,Daoping Ye et al.
Jiwei Lei et al.
Pt-based catalysts exhibit extraordinary potential in reverse-water gas shift (RWGS) reactions, but often fail to possess a high reaction rate and high durability at the same time under high temperature. Herein, we designed a SiO2-induced l...