Arene Incorporation and Ring Expansion in the Thermal Decomposition of a Divanadium(III) Complex With Four Bridging Methyl Groups [0.03%]
含四个桥连甲基的二钒(III)配合物热分解中的芳环形成及扩环反应
Adrián Calvo-Molina,Rodrigo González-Prieto,Jesús Jover et al.
Adrián Calvo-Molina et al.
Open-shell vanadium organometallic species with unprecedented structures and reactivity patterns are reported. Divanadium(III) complexes with four symmetric pyramidal bridging methyl or parent amido ligands, [{VCp*(µ-X)2}2] (Cp* = η5-C5Me...
Self-Assembled Luminescent Au(I)-Adamantylamine Coordination Polymer Needles With Thermoresponsive Optical Properties [0.03%]
一种具有温度响应光学性质的金(I)季胺配位聚合物纳米针_self组装制备与发光机制研究
Miguel Justo-Tirado,Jorge Escorihuela,Elena Zaballos-García et al.
Miguel Justo-Tirado et al.
A luminescent Au(I) coordination polymer, [AuCl(1-AdmNH2)]n was synthesized under mild conditions via spontaneous reduction of HAuCl4 by excess 1-adamantylamine (1-AdmNH2). The resulting needle-like, hydrophobic solid exhibits intense red p...
Synergistic Degradation of Toluene/Styrene Binary VOCs by a Monolithic α-MnO2/Cordierite Heterogeneous Catalyst Coupled With Non-Thermal Plasma: Mechanisms and By-Products Suppression [0.03%]
二维金属氧化物/陶瓷单体催化剂耦合非热等离子体协同降解卤代烃和二元VOCs:机制及副产物抑制研究
Jixing Liu,Jiaoyang Ma,Li Xu et al.
Jixing Liu et al.
The practical application of non-thermal plasma-catalysis hybrid systems for industrial off-gas treatment faces significant challenges due to unavoidable generation of deleterious by-products. In this study, a novel post-plasma catalytic sy...
Preparing an Exsolvable Ru-Substituted LaFeO3 Perovskite With High Surface Area From a Self-Sacrificial Polymer Template: A Versatile Strategy for Enhanced Catalytic Performance [0.03%]
以自牺牲聚合物模板法制备高比表面积Ru取代的可解离型LaFeO₃钙钛矿:用于提升催化性能的普适策略
Jaime Gallego,Yu Wang,Alexander Santamaría et al.
Jaime Gallego et al.
Exsolvable LaFe0.9Ru0.1O3 perovskite mixed oxides with a specific surface area of 270 m2·g-1 are prepared via nano-casting (infiltration), using porous Amberlite XAD16 polymer beads infiltrated with metal nitrate precursors, followed by a ...
Hierarchical Bi@Ni Foam as a Self-Supporting Anode for Superior Magnesium Storage [0.03%]
分层Bi@Ni泡沫作为镁存储的自支撑阳极材料
Andi Li,Dexing Wang,Pei Liu et al.
Andi Li et al.
Rechargeable magnesium-ion batteries (MIBs) are regarded as promising electrochemical energy storage systems due to their inherent safety and cost-effectiveness. However, the incompatibility between Mg metal anodes and conventional electrol...
Promoted Cadmium Catalysts Supported on TiO2 for Efficient CO2 Hydrogenation to Methanol [0.03%]
高性能Cd/TiO2催化剂用于CO2氢化制甲醇反应
Furan Guo,Yifan Cai,Liang Ge et al.
Furan Guo et al.
Among various CO2 utilization strategies, methanol synthesis via hydrogenation has been extensively studied due to its technological maturity and broad downstream applications. However, the development of catalysts that simultaneously provi...
Advanced Anodes and Compatible Electrolyte Strategies for Next-Generation Li/Na Batteries [0.03%]
下一代锂/钠电池的先进阳极及匹配电解液策略
Rui Tian,Minggang Xie,Zhan Shi
Rui Tian
The accelerating demand for efficient and high-performance energy storage solutions has positioned lithium-ion and sodium-ion batteries at the forefront of technological innovation. While the rapid structural evolution of high-capacity anod...
Better Material Properties and Faster Catalyzed Chemical Recycling for Poly(L-Lactide) Using a Simple Commercial Glycerol Ethoxylate Additive [0.03%]
一种简单的商用甘油乙氧基化物添加剂可提高聚L-乳酸的材料性能并加快其催化化学回收速度
Madeleine L Smith,Thomas M McGuire,Kam C Poon et al.
Madeleine L Smith et al.
Poly(L-lactide) (PLLA) is the largest volume commercial bio-derived plastic, but its brittleness and end-of-life recycling remain challenges. Here, glycerol ethoxylate (GEO), a branched ethylene glycol derivative, both toughens commercial P...
Synthesis of Confined HPW@ZIF-8 for Ambient Catalytic Oxidation of Aromatic Sulfides in Diesel [0.03%]
限域HPW@ZIF-8微反应器的合成及其在柴油中芳香硫醚常温氧化脱硫研究中的应用
Lai Wei,Zhendong Yu,Haofeng Wu et al.
Lai Wei et al.
The catalytic oxidation of aromatic sulfides under mild, ambient conditions facilitates the high-value utilization of diesel fuel, free from external heating sources. Herein, a high-performance confined catalyst through a simple one-pot met...
Plasma-Engineered LaMO3 Perovskites as Catalysts for the Oxygen Evolution Reaction: Unlocking Potential by Oxygen Vacancy Modification [0.03%]
氧空位修饰的等离子工程LaMO3型钙钛矿催化剂用于析氧反应
Junbo Wang,Lei Fu,Sijie He et al.
Junbo Wang et al.
The development of efficient and cost-effective electrocatalysts for the oxygen evolution reaction (OER) is crucial for advancing green hydrogen production via water electrolysis. While perovskite oxides represent promising non-noble metal ...