Photochromic Donor-Acceptor Naphthalenediimides Enabling Near-Infrared Photothermal Conversion for Seawater Desalination [0.03%]
用于海水淡化的近红外光热转换的光致变色给体-受体萘二酰亚胺
Sotaro Kusumoto,Soushi Kurihara,Masaya Shimabukuro et al.
Sotaro Kusumoto et al.
Photochromic donor-acceptor molecules that produce near-infrared (NIR) absorption upon light activation offer promising platforms for organic photothermal materials. Here, neutral naphthalene diimide (NDI) derivatives with tertiary amine su...
Atomically Dispersed Pd Promotes Water Activation and Electrochemical CO2 Reduction to Formate on Bismuth Catalysts [0.03%]
原子分散的钯促进铋催化剂活化水和电化学二氧化碳还原制甲酸反应
Wenjing Tian,Fei Fan,Hui-Zi Huang et al.
Wenjing Tian et al.
Electrocatalytic CO2 reduction reaction (CO2RR) offers a sustainable route for converting CO2 into value-added chemicals, but its efficiency is limited by sluggish kinetics and poor selectivity. Herein, we report the controlled synthesis of...
New Insights into Poly(Dichlorophosphazene) Synthesis via Me3Si─N═PCl3 Polymerization: An Experimental and Theoretical Study [0.03%]
关于Me_3Si─N═PCL_3聚合制备聚(二氯磷氮烯)的新见解——实验与理论研究
Cornelius Knuth,Paul Strasser,Carmen Hoth et al.
Cornelius Knuth et al.
Polyphosphazenes are a unique class of polymers, notable for their versatile functionalization and distinctive properties arising from their alternating phosphorus-nitrogen backbone. However, the synthesis of their primary precursor, poly(d...
Mechanochemical One-Pot Transformation of Indium from ITO into Functional Materials: A Coordination-Based Approach to Selective Metal Separation [0.03%]
基于配位的一锅法机械化学转化制备氧化物基底中铟的功能材料：选择性分离金属的新方法研究
Chiaki Hotta,Masayuki Gon,Kazuo Tanaka
Chiaki Hotta
Recycling of rare metals with lower environmental burden is increasingly required. Herein, we report that an azobenzene ligand selectively complexes specific metal species through mechanochemical reactions among multiple metal species. We e...
Microstructure Engineered Ultrahigh-Nickel Cathode With Enhanced Mechanical Strength and Cycle Performance [0.03%]
微观结构工程的高镍正极材料具有优异的机械强度和循环性能
Guihui Yu,Bi Luo,Shilin Su et al.
Guihui Yu et al.
In ultrahigh-nickel layered cathode materials, regulating the morphology and arrangement of primary particles is a strategy that effectively to mitigate particle microcrack formation and enhance structural stability during electrochemical c...
Organoboron- and DMSO-Mediated Ring-Opening of Cyclopropenones for the Acrylation of Alkyl (Pseudo)Halides [0.03%]
有机硼和DMSO介导的环丙烯酮开环反应用于烷基(Pseudo)卤化物的丙烯酸衍生物制备反应
Jingyuan Song,Xulin Zeng,Yiming Luo et al.
Jingyuan Song et al.
Herein, we disclose a three-component tandem reaction wherein organoboron and DMSO mediate the ring-opening of cyclopropenones to trigger the subsequent acrylation of alkyl (pseudo)halides. A series of cyclopropenones with various aryl grou...
Synthesis, Physicochemical Characteristics, Self-Assembly and Encapsulation Ability of per-Ethylene-Glycol-Functionalized Resorcin[4]Arenes and Their Molecular Capsules: On the Road to Liquid Capsules [0.03%]
全乙二醇功能化联苯[4]芳烃及其分子胶囊的合成、理化性质、自组装及封装能力：通向液体胶囊之路
Gangadhara Angajala,Inbar Horin,Tamar Evan-Salem et al.
Gangadhara Angajala et al.
Self-assembled molecular cages and capsules attracted considerable attention, owing to their unique structures and ability to function as nano-reactors and catalysts. In recent years, porous liquids have emerged into an intriguing class of ...
Integrated Flexible Supercapacitors Fabricated by Biocompatible Self‑Adhesive Polyacrylamide/Chitosan Quaternary/Polydopamine Components [0.03%]
一种由生物相容性自粘聚丙烯酰胺/壳聚糖季铵盐/多巴胺组成的柔性超级电容器
Rong Zhang,Suting Zhou,Yumeng Wang et al.
Rong Zhang et al.
A self‑adhesive supercapacitor is developed based on a biocompatible hydrogel matrix integrated with poly(3, 4‑ethylenedioxythiophene): poly(styrene sulfonate) as the conductive material. For biomedical devices, achieving stable adhesion ...
Anion-Selective Channels Formed by Synthetic 13-Mer Chimeric α -Peptide-Oligourea Foldamers [0.03%]
由合成嵌合α-肽-寡脲折叠分子组成的阴离子选择性通道
Chiranjit Dutta,Dandan Su,Pannaga Krishnamurthy et al.
Chiranjit Dutta et al.
Attempts to design transmembrane channels with selective transport properties using advanced chemistry and computational tools have had limited success. Previously, we characterized 15-mer α-peptide-oligourea chimeric foldamers that form a...
Difunctionalization of Alkenes via Photoinduced Oxidative Radical-Polar Crossover [0.03%]
光诱导氧化自由基/极性交叉双官能团化反应合成含氧杂环化合物
Yiman Gao,Zhen Chen,Lingchao Cai
Yiman Gao
Alkene difunctionalization represents one of the most powerful and straightforward tools for the rapid assembly of structurally diverse organic molecules. This review provides a comprehensive overview of recent developments in the difunctio...