Elizabeth Santos,Wolfgang Schmickler
Elizabeth Santos
Electron transfer is the most important electrochemical process. In this review, we present elements of various aspects of electron transfer theory from the early work of Marcus and Hush to recent developments. The emphasis is on the role o...
Nitrogen-Centered Radicals in Functionalization of sp2 Systems: Generation, Reactivity, and Applications in Synthesis [0.03%]
氮中心自由基在芳环官能团化反应中的生成、反应性及合成应用
Cassie Pratley,Sabine Fenner,John A Murphy
Cassie Pratley
The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic synthesis, and they continue to expand as our understanding of these reactive species increases. The utility of these reactive intermediates is demonst...
Diffusiophoresis, Diffusioosmosis, and Microfluidics: Surface-Flow-Driven Phenomena in the Presence of Flow [0.03%]
扩散光泳、扩散压渗和微流控：流动环境下的表面流动现象
Suin Shim
Suin Shim
Diffusiophoresis is the spontaneous motion of particles under a concentration gradient of solutes. Since the first recognition by Derjaguin and colleagues in 1947 in the form of capillary osmosis, the phenomenon has been broadly investigate...
Sandhya Bhatia,Jayant B Udgaonkar
Sandhya Bhatia
Proteins have dynamic structures that undergo chain motions on time scales spanning from picoseconds to seconds. Resolving the resultant conformational heterogeneity is essential for gaining accurate insight into fundamental mechanistic asp...
Sujeet Kumar,Aurelio Mollo,Daniel Kahne et al.
Sujeet Kumar et al.
The peptidoglycan (PG) cell wall is an extra-cytoplasmic glycopeptide polymeric structure that protects bacteria from osmotic lysis and determines cellular shape. Since the cell wall surrounds the cytoplasmic membrane, bacteria must add new...
Yu-Chao Yuan,Mohamed Mellah,Emmanuelle Schulz et al.
Yu-Chao Yuan et al.
Bisimine derivatives of salicylaldehyde with chiral diamines (salens) are privileged ligands in asymmetric organometallic catalysis, which can be used in cooperation with organocatalysts as additives. The latter can be a modifier of the met...
James W M Crawley,Isla E Gow,Naomi Lawes et al.
James W M Crawley et al.
The development and application of trimetallic nanoparticles continues to accelerate rapidly as a result of advances in materials design, synthetic control, and reaction characterization. Following the technological successes of multicompon...
Introduction: Smart Materials [0.03%]
智能材料概述
Yadong Yin,John A Rogers
Yadong Yin
Qiang Li,Kun Lin,Zhanning Liu et al.
Qiang Li et al.
Negative thermal expansion (NTE), referring to the lattice contraction upon heating, has been an attractive topic of solid-state chemistry and functional materials. The response of a lattice to the temperature field is deeply rooted in its ...
Marc Magre,Marcin Szewczyk,Magnus Rueping
Marc Magre
The addition of a B-H bond to an unsaturated bond (polarized or unpolarized) is a powerful and atom-economic tool for the synthesis of organoboranes. In recent years, s-block organometallics have appeared as alternative catalysts to transit...