Polyacrylate Vitrimer Network via In Situ Isocyanide Copolymerization: Synthesis and Molecular Dynamics [0.03%]
原位异氰酸酯共聚制备聚丙烯酸类仿生高分子网络材料：合成与动力学研究
Han-Li Sun,Stavros X Drakopoulos,Lejla Čamdžić et al.
Han-Li Sun et al.
Widespread plastic pollution highlights the urgent need for materials with sustainable end-of-life management. Vitrimers, cross-linked polymers containing dynamic covalent bonds, combine the durability of thermosets with their recyclability...
Toby G Johnson,Dean M Miller,Drew V Carson et al.
Toby G Johnson et al.
Applying enzymes from unique biosynthetic pathways in a combinatorial fashion to garner new-to-nature products has been a long-standing goal of synthetic biology. Ribosomally synthesized and post-translationally modified peptides (RiPPs) ar...
Macrocyclic Peptides Containing an Imidazopyridinium (IP+) Unit Display Enhanced Passive Cell Permeability [0.03%]
含有咪唑并吡啶
Bo Li,Joshua Parker,Skyler Briggs et al.
Bo Li et al.
Macrocyclic peptides (MPs) have emerged as interesting therapeutic candidates due to their ability to engage difficult protein targets with high affinity and selectivity. However, their application to intracellular targets is limited by the...
Amphoteric Behavior of Hydrogen in Lanthanum Oxyhydrides: Correlation with Electrochemical Properties [0.03%]
镧 oxyhydride中氢的两性行为：与电化学性质的相关性分析
Tomoyuki Yamasaki,Keiga Fukui,Soshi Iimura et al.
Tomoyuki Yamasaki et al.
Hydrogen incorporated into solids can adopt either protonic (H+) or hydridic (H-) characteristics depending on the position of the Fermi level of the host material. In recent years, not only proton-conducting materials but also hydride-ion-...
Jacob A Barrett,Phattananawee Nalaoh,David M Jenkins
Jacob A Barrett
Incorporating disparate functionalized ligands into phase-pure metal-organic frameworks (MOFs) has been shown to produce multivariate MOFs (MV-MOFs) whose properties often exceed those of the corresponding linker-pure MOFs. The ability to e...
Built-in Electric Field in Multivariate COFs Boosts Photocatalytic NADH Regeneration for Enzymatic Reduction [0.03%]
内置电场的多元COF强化光催化NADH再生用于酶还原反应
Zhenyang Zuo,Menglan Chen,Wei Lan et al.
Zhenyang Zuo et al.
Solar-driven in situ nicotinamide adenine dinucleotide (phosphate) [NAD(P)H] regeneration provides a sustainable route for producing high-value chemicals using NAD(P)H-dependent reductases. However, its efficiency is frequently restricted b...
HAAC Ligation-Enabled Hierarchical Assembly: Deciphering the Synergy of α-Hydroxyl Aldehydes and 2-Aminooxazoles [0.03%]
基于醛类和肼类的HAAC交联作用引导多酚自聚集成像导电纳米纤维
Xiaoqian Chen,Haojie Wang,Minxin Zhou et al.
Xiaoqian Chen et al.
We report α-hydroxyl aldehyde-2-aminooxazole conjugation (HAAC), a bioorthogonal ligation platform that enables selective biomolecular labeling and functional modulation under physiological conditions (pH 7.0, 37 °C). HAAC chemistry suppo...
Liquid Coordination Environment-Induced Liquid-Like Metal Behavior: Mobile Single-Atom Copper Catalytic Centers [0.03%]
液态配位环境诱导的金属液体行为：移动单原子铜催化中心
Rubo Fang,Longyu Xu,Yanhong Cui et al.
Rubo Fang et al.
Heterogeneous single-atom catalysts are typically stabilized by rigid anchoring to solid supports, which limits their dynamic response under the reaction conditions. Here, we demonstrate that liquid-metal-like catalytic behavior can be real...
Two-Lever Design Rule for High-Entropy Oxide Oxygen Carriers: Minimize Spin Polarization, Maximize Fe-O-Ni Covalency [0.03%]
高熵氧化物氧载体的两层设计规则：最小化自旋极化，最大化Fe-O-Ni共价性
Yihan Fan,Bo Jin,Haibo Zhao et al.
Yihan Fan et al.
What is missing in high-entropy oxide (HEO) oxygen carrier design is an actionable rule that links composition to redox performance. We advance a two-lever principle─decrease spin polarization and increase Fe-O-Ni covalency─that lowers th...
Heavy Halide Nanomaterials as Next-Generation Hosts for Lanthanide Upconversion [0.03%]
重卤化物纳米材料作为下一代稀土上转换宿主.hosts指代发光材料中用于吸收能量并激活发光离子的基质材料，即发光材料中的主体化合物。
Artiom Skripka
Artiom Skripka
Activating inorganic hosts with lanthanide ions enables nonlinear phenomena, such as photon upconversion, photon avalanche, and quantum cutting, thereby expanding the potential of nanomaterial-based technologies. To maximize the optical per...