Two-Dimensional Chiral Perovskites for Integrated High-Performance Ultraviolet Full-Stokes Polarization Detection [0.03%]
二维手性钙钛矿用于高性能紫外光全 Stokes 参数检测集成器件
Zhirong Liu,Tianyu Sun,Xiaoting Ma et al.
Zhirong Liu et al.
Full Stokes polarization detection is indispensable for the advancement of multidimensional optoelectronic systems; however, conventional polarimeters are often limited by architectural complexity and parasitic optical losses stemming from ...
Selectivity Reversal from CO to Ethylene Products in CO2 Photoreduction via Electronic Modulation of SnS2 Using a Vinyl-Bridged Porous Organic Polymer [0.03%]
电子调控SnS2用于乙烯选择性光电催化二氧化碳还原
Subhajit Chakraborty,Bishal Boro,S A Keishana Navodye et al.
Subhajit Chakraborty et al.
Developing an efficient and robust photocatalyst for optimal C2+ product generation from carbon dioxide (CO2) is a pressing need in advancing solar fuel production. In this study, we designed an ionic vinylene-bridged conjugated porous orga...
Benzene Ring Expansion to Borepins via Borylene Insertion Enabled by Thorium-Arene Cooperativity [0.03%]
配位的 thorium 促进的 borylene 插入苯环扩环反应构筑 borepin 类化合物研究
Jue Wang,Jingliang Zhao,Jiefeng Liang et al.
Jue Wang et al.
Cleaving aromatic C-C bonds of unfunctionalized arenes remains a formidable challenge in synthetic chemistry. Here, we report room-temperature benzene ring expansion to a seven-membered borepin via formal borylene insertion. Treatment of an...
Adsorption and Sulfur-Selective Photooxidation of Cysteine on Anatase TiO2(101) [0.03%]
半胱氨酸在锐钛矿TiO₂（101）表面的吸附及选择性硫光氧化
Miguel Blanco Garcia,Daniele Perilli,Chiara Daldossi et al.
Miguel Blanco Garcia et al.
Understanding how multifunctional amino acids interact with photocatalytic oxide surfaces is essential to controlling their interfacial redox chemistry. Here, we combine scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy ...
Atomic Evolution of Hydrogen Intercalation Wave Dynamics in Palladium Nanocrystals Revealed by Liquid-Phase Transmission Electron Microscopy [0.03%]
液相透射电子显微学观察到的钯纳米晶中氢插层波动力学的原子演化规律研究
Daewon Lee,Sam Oaks-Leaf,Sophia B Betzler et al.
Daewon Lee et al.
Solute-intercalation-induced phase separation creates spatial heterogeneities in host materials, a phenomenon ubiquitous in batteries, hydrogen storage, and other energy devices. Despite many efforts, probing intercalation processes at the ...
Structurally Encoded Mixed Proton-Electron Transport in Tetrathiafulvalene-Based Lanthanide MOFs [0.03%]
基于四硫富瓦烯的镧系金属有机框架中结构编码的质子-电子混合传输
Fabio Manna,Zhentao Yang,Mariangela Oggianu et al.
Fabio Manna et al.
A family of 2D tetrathiafulvalene tetracarboxylate (TTFTC)-based lanthanide (LnIII = Dy III, Er III, and Yb III) metal-organic frameworks (MOFs) is reported as a robust platform for mixed proton-electron conduction. Electronic transport ari...
Iron-Catalyzed Chemodivergent Sequential Reactions of Alkynes and Organozinc Reagents [0.03%]
铁催化炔烃与有机锌试剂的化学多样化连续反应
Tao Cai,Peng He,Shen-Ao Xie et al.
Tao Cai et al.
Although enzymes easily achieve significant changes in reactivity through mutating only a single or a few residues reminiscent of "butterfly effect", achieving selectivity modulation in chemical catalysis requires major structural modificat...
Late-Stage Carboranylation of Nucleos(t)ides Enabled by Minisci and Pd-Catalyzed B-N Cross-Coupling Reactions: Toward the Synthesis of Carboranyl-Modified Oligonucleotides [0.03%]
基于Minisci和Pd催化的B-N交叉偶联反应的核苷（酸）晚期卡博烷基化：合成卡博烷基修饰的寡核苷酸的研究
Yutong Zhou,Raghunath Bag,Dazhi Zhou et al.
Yutong Zhou et al.
Carboranyl-modified nucleosides are promising boron-10 (10B) delivery agents for boron neutron capture therapy (BNCT), yet methods for directly forming B-C/B-N bonds at unprotected nucleosides are scarce. We report herein two operationally ...
Bembe C Mackintosh,Marcello Righetto,G Krishnamurthy Grandhi et al.
Bembe C Mackintosh et al.
Effective charge-carrier transport is a key requirement of next-generation thin-film materials developed for solar cells. Perovskite-inspired materials (PIMs), including metal chalcohalides, show great promise as lead-free solar absorbers. ...
Pressure-Induced Superconductivity in the Thermoelectric Semiconductor Mg3Sb2 [0.03%]
镁金属间化合物Mg₃Sb₂中的压力诱导非常规超导电性研究
Cuiying Pei,Yasong Wu,Airan Li et al.
Cuiying Pei et al.
The intrinsic electronic structures of narrow bandgap thermoelectric (TE) materials serve as a platform for the investigation of coupling effects of quasi-particles under high pressure, enabling the exploration of emerging electronic and ph...