Room Temperature Giant Magnetoelectric Coupling in {CoIII3DyIII} Molecular Single Crystal Derived Nanogenerator [0.03%]
基于分子单晶纳米发电机的室温巨磁电效应研究
Deepanshu Chauhan,Dalip Saini,Dipanti Borah et al.
Deepanshu Chauhan et al.
Magnetoelectric (ME) materials are sought for next-generation memory, spintronics, and energy harvesting, but strong ME coupling at room temperature (RT) in single-phase systems remains rare due to the mutual exclusivity of ferroelectricity...
Siqiang Fang,Peiqi Zhang,Guanwen Hu et al.
Siqiang Fang et al.
Hydroboration is one of the most widely utilized reactions for olefin functionalization and organoboron synthesis. While asymmetric hydroboration is well established for creating homochiral alkanes with stereogenic carbon centers, catalytic...
Ultrahigh-Nickel Cathodes with B/Al Codoped Gradient Interface for High-Energy All-Solid-State Lithium Batteries [0.03%]
用于高能量全固态锂电池的B / Al共掺杂梯度界面超高镍正极
Xiangqun Xu,Sheng Xu,Shuqi Kang et al.
Xiangqun Xu et al.
Ultrahigh-nickel layered oxide cathodes (LiNixCoyMn1-x-yO2, NCM, x ≥ 0.9) offer exceptionally high energy density essential for next-generation and safe all-solid-state batteries (ASSBs). However, severe interfacial side reactions (e.g., e...
Proton-Mediated Kinetic Equilibrium Synthesis of High-Crystalline Vinylene-Linked Covalent Organic Frameworks for Efficient Oxygen Reduction Reaction [0.03%]
质子介导的结晶联乙烯连接的共价有机框架的动力学平衡合成及其高效氧还原性能
Helin Xu,Minghui Liu,Shengcong Shang et al.
Helin Xu et al.
Vinylene-linked covalent organic frameworks (COFs) are considered as one of the most promising COF materials due to their full π-conjugation and excellent stability. However, the irreversibility of carbon-carbon double bond formation can l...
Divergent Syntheses of the Euphorbia Diterpenoids Pepluanol A and Pepluacetal [0.03%]
独叶菜二萜类化合物Pepluanol A和Pepluacetal的发散式合成
Dongyuan Qiu,Zihan Zhao,Leyi Liu et al.
Dongyuan Qiu et al.
Pepluanol A (1) and pepluacetal (2) belong to a structurally unique class of pepluanol-type Euphorbia diterpenoids, exhibiting immunosuppressive activity via targeting Kv1.3 channels. Herein, we report a divergent synthetic strategy that en...
Enantioselective Copper-Catalyzed Synthesis of Hydroxylamines via Hydrofunctionalization of Alkenes using Nitroalkanes [0.03%]
手性铜催化体系通过使用硝基烷烃的烯烃氢功能化反应合成羟胺类化合物
James A Law,Binh Khanh Mai,Hsuan-Min Hung et al.
James A Law et al.
Herein, we report that nitroalkanes are competent electrophiles for the enantioselective copper hydride (CuH)-catalyzed alkene hydrofunctionalization of vinyl(hetero)arenes to generate hydroxylamines in good yields and with high levels of e...
Synthesis of an o-Benzoquinone Arsenic Mononitride (As≡N) Complex and Its Reaction to Singlet Arsinonitrene [0.03%]
邻苯醌氨基化砷(III)氮簇的合成及生成单线态亚胂亚氮烯的研究
Weiyu Qian,Maria Eugenia Sandoval-Salinas,Rachel Crespo-Otero et al.
Weiyu Qian et al.
The generation and stabilization of heavier analogues of dinitrogen (N2) remain fundamental challenges in modern inorganic and materials chemistry. In marked contrast to N2, these species exhibit extremely high reactivities and transient li...
Practical Rh-ZhangPhos Catalyzed Asymmetric Hydrogenation of Enamides: From Scalable Access to Mechanistic Insight [0.03%]
实用的Rh-张手性膦催化的 enamides 不对称氢化：从规模化制备到机理洞察
Heng Wang,Longxue Xiang,Yu Chen et al.
Heng Wang et al.
Herein, we report a simple, one-pot, scalable process for the preparation of a series of enamides, which were subsequently hydrogenated with high efficiency and excellent enantioselectivity to the corresponding chiral amides using the Rh-Zh...
Xiaomei He,Jun Yuan,Lin Li et al.
Xiaomei He et al.
R-loops play critical roles in gene regulation and genome stability. To elucidate the protein-mediated mechanisms governing R-loop dynamics, we leveraged APEX-based proximity labeling to profile the R-loop proximal proteome. By integrating ...
Emergent Heavy-Fermion Physics in a Family of Topological Insulators R AsS (R = Y, La, and Sm) [0.03%]
拓扑绝缘子RAsS(R=Y，La和Sm)中的重费米子物理现象
Iñigo Robredo,Yuan Fang,Lei Chen et al.
Iñigo Robredo et al.
Realizing topological phases in strongly correlated materials has become a major impetus in condensed matter physics. Although many compounds are now classified as topological insulators, f-electron systems provide an especially fertile pla...