Photochemical Fluoroalkylations with Fluorinated Gases Facilitated by a Robust Metal-Organic Framework [0.03%]
通过稳健的金属有机骨架催化氟化气体进行光化学氟代烷基化反应
Jiachen He,Joharimanitra Randrianandraina,Husain Adamji et al.
Jiachen He et al.
Photochemistry has greatly advanced the sustainable synthesis of complex molecules, but its application for late-stage fluoroalkylation─crucial due to the presence of fluorine in >20% of pharmaceuticals and >65% of agrochemicals─is hinder...
Stereoselective Dihalogenation of Alkynes to Access Enantioenriched Z-Vicinal Dihaloalkene Atropisomers [0.03%]
用于获得Z-位邻卤烯烃异构体的炔烃立体选择性双卤化反应以 enrich enantiomer 丰富
Yu Chang,Da Xu,Guojie Zhou et al.
Yu Chang et al.
The stereoselective construction of Z-configured olefins remains a fundamental challenge in synthetic chemistry, particularly when additional stereogenic elements with high enantioselectivity are simultaneously introduced. Furthermore, vici...
Collective Total Synthesis of 12 C4-Oxygenated Cladiellins and Structure Elucidation of Cladieunicellin D and Cladielloides A/C [0.03%]
十二个氧代克拉地菌素的群组全合成及克拉地菌素D和克拉地洛伊德A/C的结构鉴定
Kyohei Oga,Yutaro Yamada,Masanori Nagatomo et al.
Kyohei Oga et al.
Cladiellins are a group of marine natural products found in octocorals inhabiting Indo-Pacific reefs, and some members exhibit medically relevant biological activity. The 6/5/9-membered tricyclic ring skeleton of cladiellins comprises hydro...
Correction to "Solvent-Assisted Self-Assembly of a Metal-Organic Framework Based Biocatalyst for Cascade Reaction Driven Photodynamic Therapy" [0.03%]
“溶剂辅助自组装金属有机框架基生物催化剂驱动的连续反应光动力治疗”的更正通知
Liangcan He,Qianqian Ni,Jing Mu et al.
Liangcan He et al.
Published Erratum
Journal of the American Chemical Society. 2025 Dec 30. DOI:10.1021/jacs.5c21749 2025
Electrocatalytic Semi-Hydrogenation of Pyridine Derivatives over an In Situ Assembled Cu Cathode [0.03%]
原位形成铜催化剂电催化吡啶类化合物的半氢化反应
Liping Chen,Tongbo Zhong,Ziyan Li et al.
Liping Chen et al.
Selective electrochemical hydrogenation of pyridine derivatives to piperidines, two of the most prevalent nitrogen heterocycles in pharmaceuticals, is essential for accessing structurally diverse and isotopically labeled analogs in drug dis...
Post-Transition-State Dynamics Induced Product Diversity in the Thermal Rearrangement of Cyclopropenyl Azides [0.03%]
环丙基叠氮热重排反应过渡态后的动态效应导致产物多样化
Chandralekha Hajra,Gourab Saha,Ayan Datta
Chandralekha Hajra
Cyclopropenyl azides (1) are known to undergo three major thermal rearrangements, namely, 3,3-sigmatropic rearrangement to form 1,2,3-triazine (2), allylic arrangement to form the degenerate product (3), and N2 elimination to form azete (4)...
Dispersion-Controlled Excited-State Dynamics in Azobenzene Photoisomerization [0.03%]
氮苯光异构化过程中控制散裂的激发态动力学研究
Torben Sassmannshausen,Nils Oberhof,Marcel A Strauss et al.
Torben Sassmannshausen et al.
Weak interactions, like London dispersion forces, are cumulative in nature and have been thought to be essential for only the structure and stability of large molecular systems. Only recently has their relevance for chemical reactivity been...
Homochiral Metal-Organic Framework Featuring Transformable Helical and Sheeted Structures [0.03%]
手性金属有机框架:螺旋结构和层状结构可转换材料
Xiang-Shuai Li,Peiqi Zhang,Fang-Yu Ren et al.
Xiang-Shuai Li et al.
Pursuing artificial mimics of natural protein structures is a critical research area with broad implications in biochemistry, synthesis, and materials science. A key objective is to understand and validate the chirality transfer process fro...
Fast Discharging Stabilizes Electrochemical Interfaces: Achieving Close-to-Unity Reversibility in "Dendrite-Forming" Battery Electrodes [0.03%]
快速放电稳定电化学界面：“枝晶不稳定”电池电极中接近100%的可逆性取得获得实现达成
Wen-Yang Jao,Aakriti Aggarwal,Tushar K Telmasre et al.
Wen-Yang Jao et al.
Developing resilient aqueous energy storage systems, such as Zn batteries, is essential for advancing energy sustainability. A key challenge in these systems is the dendritic growth of metals, which causes poor rechargeability in battery el...
Harnessing CO2 Radical Anion-Mediated Electron Transfer for Scalable Copper-Catalyzed Cross-Coupling [0.03%]
利用CO2阴离子介导的电子转移实现大规模铜催化交叉偶联反应
Shuo Wu,Chia-Jung Yang,Mu-Jeng Cheng et al.
Shuo Wu et al.
The inherently sluggish single-electron transfer from copper(I) complexes to alkyl halides remains a central bottleneck in copper-catalyzed cross-coupling chemistry. Here, we introduce a conceptually distinct strategy that overcomes this li...