Spontaneous Reaction between CO2 and Organic Acids in Water Microdroplets: Implications for the Formation of Secondary Organic Aerosols [0.03%]
二氧化碳与有机酸在水微滴中自发反应形成二次有机气溶胶的机制研究
Jing He,Qiaojing Zhao,Hong Zhang et al.
Jing He et al.
Secondary organic aerosols (SOAs) are key components of aerosols, but their formation pathways remain incompletely elucidated. This study reveals a new pathway for SOA formation in water microdroplets by employing both experimental and theo...
Automated Nanocrystalline Sponge Workflow Enabled by 3D Electron Diffraction [0.03%]
基于三维电子衍射的纳米晶海绵自动化工作流程
Sofiia Butonova,Yinlin Chen,Jung Cho et al.
Sofiia Butonova et al.
The crystalline sponge (CS) method utilizes a crystalline porous material to arrange target molecules within its periodic pores. This enables the determination of the 3D atomic structures of organic molecules without the need for crystalliz...
Engineering Intrinsically Chiral Gold Nanostructures with Tailored Near-Infrared Optical Activity via a Multistep Growth Strategy [0.03%]
通过多步生长策略定制近红外光学活性的固有手性金纳米结构工程化研究
Anannya Mandal,Jatish Kumar
Anannya Mandal
Inherently chiral nanoparticles attract tremendous interest as they unfold the mystery behind symmetry breaking, chiral amplification, and chiral transmission, processes key to understanding homochirality and the origin of life. In this con...
Regulating Na-Ion Occupations of P-Type Na0.67Ti0.10Fe0.05Mn0.85O2 for Improving Electrochemical Reversibility and Kinetics [0.03%]
通过调节P型Na0.67Ti0.10Fe0.05Mn0.85O2中钠离子的占位来提高其电化学可逆性和动力学性能研究
Meijing Xiao,Ce Zhou,Wujie Dong et al.
Meijing Xiao et al.
P'2-type manganese-based layered oxides (NaxMnO2, 0.5 < x < 0.8 usually) have emerged as promising cathode materials for sodium-ion batteries (SIBs), primarily due to their ability to deliver higher capacity compared to P2-type layered oxid...
Resolving Ionic Liquid Electrolyte-Mediated Microscopic Electrified Interface for Stable Lithium Metal Anode [0.03%]
通过离子液体电解质解决微电极界面问题以获得稳定锂金属负极
Haifeng Tu,Zhiyong Tang,Shiqi Zhang et al.
Haifeng Tu et al.
Ionic liquids (ILs), renowned for their exceptional safety features, have become promising candidates for developing next-generation electrolyte systems in high-safety, high-energy-density lithium metal batteries (LMBs). However, the abilit...
Benchmarking Cantilever Torque Magnetometry as a Platform for Characterizing Molecular Qubits: A Case Study on Ni(II) Complexes [0.03%]
悬臂扭矩磁强计表征分子量子比特的基准测试——Ni(II)配位化合物的案例研究
Jett T Janetzki,Arsen Raza,Matteo Briganti et al.
Jett T Janetzki et al.
Precise and experimentally accessible determination of the electronic structure of transition metal complexes remains a challenge in the development of molecular qubits, particularly for leading candidates with integer spin. Existing techni...
Efficient and Selective Hydroxyl-Mediated Photocatalytic Ethane Oxidation to Acetic Acid [0.03%]
高效且具有选择性的羟基介导光催化乙烷氧化制醋酸反应
Siyuan Yang,Guangyao Zhai,Junchi Xu et al.
Siyuan Yang et al.
Ethane offers a promising feedstock for sustainable acetic acid production. However, the chemical inertness of ethane and the multiple ethane oxidation steps greatly restrict the acetic acid productivity and selectivity. In this work, we re...
Unsymmetric α,ω-Diol Oxidation into Aliphatic Hydroxyaldehydes: Active Organic Intermediates with Exceptionally High Value [0.03%]
不对称ω-二醇氧化制备链状羟基醛：高活性有机合成中间体及其特殊价值研究
Yezi Hu,Chumin Yan,Duoyue Tang et al.
Yezi Hu et al.
Hydroxyaldehydes are terminally differentiated building blocks and key intermediates for organic synthesis. Unsymmetric oxidation of α,ω-diols to aliphatic hydroxyaldehydes is rarely developed due to the tremendous difficulties and challe...
Multiresponsive and Tunable Circularly Polarized Luminescence in Aggregation-Induced Emission Static Helical Supramolecular Polyisocyanides [0.03%]
聚集诱导发射静态手性超分子聚异氰酸酯中的多响应性和可调圆偏振发光
Beiming Yu,He Li,Ruoling Li et al.
Beiming Yu et al.
The realization of stimuli-responsive dynamic CPL in static helical polymers remains highly challenging. Herein, a novel, covalent, and green synthetic strategy is developed to construct AIE-featured static helical supramolecular polyisocya...
Biomolecular Condensates Power Nitrogen Cycling via Concurrent Redox Activities [0.03%]
生物分子凝聚物通过同时氧化还原活性驱动氮循环
Xiaowei Song,Lecheng Lyu,Chao Li et al.
Xiaowei Song et al.
The role of the inherent chemical activities of biomolecular condensates in metabolism remains underexplored. We discovered that biomolecular condensates, the constituents of which do not possess any intrinsic enzymatic activities, can modu...