Synthesis of Sn-Incorporated Single-Walled Zeolitic Nanotube as a Lewis Acidic Catalyst [0.03%]
合成含Sn单壁分子筛纳米管作为路易斯酸催化剂
Weihong Yan,Youran Wang,Zhenyuan Zhao et al.
Weihong Yan et al.
The single-walled zeolitic nanotube is a novel open-framework material distinguished by its hollow tubular morphology and double-layered zeolitic walls. Expanding its compositional diversity and tunability is crucial for unlocking the poten...
Unnatural Cytosine Analogs Potentiate a Customizable, Enzymatic Method for Integrated Epigenetic and Four-Base Genetic Sequencing [0.03%]
不天然胞嘧啶类似物增强了一种定制化、基于酶的表观遗传和四碱基基因组测序方法
Christian E Loo,Jared B Parker,Aleksia Barka et al.
Christian E Loo et al.
The interplay of genetic and epigenetic information shapes cell identity, development, and disease. However, standard methods for profiling DNA modifications (e.g., bisulfite sequencing) rely on selective C-to-T conversions, hindering the s...
n-Type Conjugated Polymer Based on a Carbonyl-Terminated Quinoidal Unit for Transparent Conductor [0.03%]
基于羰基封端的准闭壳单体单元的n-型共轭聚合物透明导电材料
Pengfei Pang,Mei Rao,Yilin Zhao et al.
Pengfei Pang et al.
Simultaneously achieving high electrical conductivity and optical transparency remains a formidable challenge for polymers. In this study, we addressed this challenge by preparing a conjugated polymer (PBT) using a carbonyl-terminated quino...
A Fully Artificial Molecular-Based Photoelectrochemical Cell Enabling Overall Water Splitting by Combining a Photoanode and a Dark-Cathode [0.03%]
一种全新的全人工分子基光解水电位器，通过将光电极和暗阴极组合实现整体水分解反应
Xin Yan,Yuki Tomita,Ken Sakai et al.
Xin Yan et al.
Significant efforts have been made to develop molecular-based artificial photosynthetic systems for overall solar water splitting by carefully functionalizing the photoelectrochemical cells with various molecular components serving as photo...
Electrocatalytic Oxidative Coupling of CO with Amines toward Symmetrical and Asymmetrical Urea Derivatives [0.03%]
电催化CO与胺的氧化偶联制备对称和非对称脲衍生物
Hanwen Yang,Kaiyue Zhao,Haocheng Xiong et al.
Hanwen Yang et al.
Urea derivatives have broad applications in the pharmaceutical and agricultural industries. Existing synthetic routes involve toxic reagents and multistep processes and operate at harsh conditions. In this work, we report an electrocatalyti...
Li+ Promoted the Cyanation of Unactivated C-H Bonds Catalyzed by the Manganese Porphyrin Complex through Biomimetic Oxidation [0.03%]
仿生氧化活化锰卟啉配合物催化无官能团C-H键的腈化反应：Li+促进效应
Hao Huang,Cece Wang,Weiming Shen et al.
Hao Huang et al.
Heme and nonheme oxygenases have been known to catalyze the oxidation of unactivated C-H bonds. In most cases, hydroxylated products are formed predominantly via the "oxygen rebound" pathway. Alternatively, under certain conditions where th...
Integrating Sulfate with Crown Ether To Construct Supramolecular Radium Traps in an Anionic Zirconium Metal-Organic Framework [0.03%]
将硫酸盐与冠醚整合构建超分子捕集器用于锕系金属放射性核素镭在阴离子锆基MOFs中高效选择性吸附分离研究
Wenchang Wang,Jiahao Lou,Qiang Wu et al.
Wenchang Wang et al.
Sequestration of radiotoxic 226Ra2+ is challenged by its complex coordination chemistry, which requires a precise molecular recognition strategy. Here, we report a supramolecular trap engineered within a stable zirconium metal-organic frame...
Elucidating the Acidic and Textural Properties of ZMQ-1, a 28-membered Ring Mesoporous Aluminosilicate Zeolite [0.03%]
阐明28元环介孔分子筛铝硅酸盐沸石ZMQ-1的酸性和纹理性质
Mohammad Fahda,Yiqing Sun,Petko Petkov et al.
Mohammad Fahda et al.
ZMQ-1 is a recently discovered aluminosilicate zeolite featuring atomically ordered mesopores (28 × 10-membered rings), providing a unique, intrinsically bimodal micro/mesoporous framework. This study systematically investigates how residu...
Harnessing Spatiotemporal Dynamics of Polymerized Electrolytes for Durable High-Voltage Lithium Metal Batteries [0.03%]
聚合电解质时空动力学的调控助力高压长寿命锂金属电池
Zhiye Hao,Yong Chen,Qimin Peng et al.
Zhiye Hao et al.
Despite affording conformal interfaces in solid-state and quasi-solid-state Li metal batteries (LMBs), in situ polymerized electrolytes suffer from sluggish Li+-transport kinetics and chemically reactive interphases that promote electrolyte...
A "Lung-Trap" Theranostic Strategy for Precision Management of Drug-Resistant Bacterial Pneumonia and Bacteremia [0.03%]
用于药物耐药性细菌肺炎和菌血症精准管理的“肺陷疗法”诊疗策略
Yang Qian Hou,Dingyuan Yan,Weigeng Huang et al.
Yang Qian Hou et al.
The escalating global crisis of antibiotic resistance demands the development of novel therapeutic strategies. This study proposes a "lung-trap" strategy that shifts the paradigm from systemic chemical eradication to localized physical inte...