N-Triftosylhydrazones: A New Chapter for Diazo-Based Carbene Chemistry [0.03%]
基于重氮的卡宾化学的新篇章:N-三氟甲氧基腙的作用
Zhaohong Liu,Paramasivam Sivaguru,Giuseppe Zanoni et al.
Zhaohong Liu et al.
Over recent decades, N-sulfonylhydrazones have attracted significant attention in academic and industrial contexts owing to their ease of preparation, versatile reactivity, high stability, and practicality. In particular, the use of N-sulfo...
Amrita Sikder,Cem Esen,Rachel K O&#x;Reilly
Amrita Sikder
The design and fabrication of synthetic self-assembled systems that can mimic some biological features require exquisitely sophisticated components that make use of supramolecular interactions to attain enhanced structural and functional co...
Peter B Crowley
Peter B Crowley
This Account summarizes the progress in protein-calixarene complexation, tracing the developments from binary recognition to the glue activity of calixarenes and beyond to macrocycle-mediated frameworks. During the past 10 years, we have be...
Concept of Embedded Dipoles as a Versatile Tool for Surface Engineering [0.03%]
嵌入偶极子概念在表面工程中的广泛应用工具
Egbert Zojer,Andreas Terfort,Michael Zharnikov
Egbert Zojer
Controlling the physical and chemical properties of surfaces and interfaces is of fundamental relevance in various areas of physical chemistry and a key issue of modern nanotechnology. A highly promising strategy for achieving that control ...
Solution-State Hydrostatic Pressure Chemistry: Application to Molecular, Supramolecular, Polymer, and Biological Systems [0.03%]
溶液态静水压化学：分子、超分子、聚合物和生物体系中的应用
Hiroaki Mizuno,Gaku Fukuhara
Hiroaki Mizuno
Pressure (P), as one of the most inherent state quantities, has become an academic subject of study and has attracted attention for a long time for the minute control of reaction equilibria and rates, not only in the gas phase, based on the...
Organocatalyzed Cross-Nucleophile Couplings: Umpolung of Catalytic Enamines [0.03%]
有机催化的交叉亲核试剂偶联反应：催化性烯胺的 umpolung 反应
Nomaan M Rezayee,Johannes N Lamhauge,Karl Anker Jørgensen
Nomaan M Rezayee
The concept of umpolung, or polarity reversal, introduced by Seebach and Corey nearly half a century ago, ushered a new paradigm into synthetic chemistry. Novel connections were able to be forged among functional groups that were typically ...
Plasmonic Cavities and Individual Quantum Emitters in the Strong Coupling Limit [0.03%]
强耦合条件下等离激元空腔及单量子发射体
Ora Bitton,Gilad Haran
Ora Bitton
ConspectusThe interaction of emitters with plasmonic cavities (PCs) has been studied extensively during the past decade. Much of the experimental work has focused on the weak coupling regime, manifested most importantly by the celebrated Pu...
Catalyst Engineering Empowers the Creation of Biomass-Derived Polyesters and Polycarbonates [0.03%]
催化剂工程赋能生物基聚酯和聚碳酸酯的创造
Arianna Brandolese,Arjan W Kleij
Arianna Brandolese
The introduction of circular principles in chemical manufacturing will drastically change the way everyday plastics are produced, thereby affecting several aspects of the respective value chains in terms of raw feedstock, recyclability, and...
Transition Metal-Catalyzed Biaryl Atropisomer Synthesis via a Torsional Strain Promoted Ring-Opening Reaction [0.03%]
扭曲应变促进的开环反应驱动的手性双芳基化合物合成及动态动力学拆分研究
Xue Zhang,Kun Zhao,Zhenhua Gu
Xue Zhang
Arising from the restricted rotation of a single bond caused by steric or electronic effects, atropisomerism is one of the few fundamental categories for molecules to manifest their three-dimensional characters into which axially chiral bia...
From Precision Colloidal Hybrid Materials to Advanced Functional Assemblies [0.03%]
从精准胶体杂化材料到高级功能组装体
Veikko Linko,Hang Zhang,Nonappa et al.
Veikko Linko et al.
The concept of colloids encompasses a wide range of isotropic and anisotropic particles with diverse sizes, shapes, and functions from synthetic nanoparticles, nanorods, and nanosheets to functional biological units. They are addressed in m...