R Graham Cooks,Thalappil Pradeep
R Graham Cooks
We suggest that accelerated reactions in confined volumes, specifically in microdroplets that contain water in contact with air, represent a remarkable, indeed a revolutionary chemical phenomenon. This strong claim is justified by the magni...
Formal Hydride Abstraction: A Unified Photoredox Platform for Nucleophilic C(sp3)-H Functionalization [0.03%]
阳离子氢负离子 abstraction策略促进的中性自由基生成及其在sp3-C-H键氨氧化反应中的应用
James Mortimer,Patricia Z Musacchio
James Mortimer
ConspectusCarbocations are among the most versatile reactive intermediates in organic synthesis. Serving as the electrophilic linchpin for fundamental transformations such as SN1 substitutions, Friedel-Crafts alkylations, Ritter reactions, ...
Guang-Rui Si,Lin-Hua Xie,Xin Zhang et al.
Guang-Rui Si et al.
ConspectusThe development of adsorbents acting as "molecule traps" for advanced adsorption and separations on specific molecular recognition has garnered increasing attention over the past decade. Molecule trapping can be understood as stro...
Why Single-Atom Alloys (SAAs) Outperform Their Individual Metal Components in Catalysis [0.03%]
单原子合金的催化活性和选择性优于其组分金属的原因分析
Francisco Zaera
Francisco Zaera
ConspectusMuch industrial catalysis employs noble metals such as Pt, Pd, and Rh to facilitate the activation of key diatomic reactants such as H2 and O2, a requisite for the promotion of hydrogenation and oxidation reactions, respectively. ...
Ofri Goldenberg,Dafei Xiao,Yoav Shechtman
Ofri Goldenberg
ConspectusSuper-resolution microscopy has fundamentally transformed our ability to observe biological structures, allowing nanoscale observation into biological samples such as fixed and live cells and tissues, and has been notably recogniz...
Upgrading of Biomass-Derived Oxygen-Containing Chemicals for Nitrogen-Containing Chemicals: Moving from Nanoparticles to Single Metal Sites and Metal Oxides [0.03%]
生物质含氧化学品到含氮化学品的提升：从纳米粒子到单金属位点和金属氧化物
Peng Zhou,Ziliang Yuan,Xixi Liu et al.
Peng Zhou et al.
ConspectusHighly valued N-containing compounds are important and widely applied in the agricultural, pharmaceutical, and material industries. Oxidative or reductive coupling of oxygen-containing chemicals with ammonia or amines is one of th...
Synthetic Framework Evolution: A Scaffold-Centric Perspective on Iterative Chemical Space Expansion [0.03%]
基于支架的迭代化合物空间扩展合成框架演化的支架中心视角
Kalliopi Mazaraki,George Karageorgis,Alexandros L Zografos
Kalliopi Mazaraki
ConspectusThe efficient exploration of natural product-like chemical space remains a central challenge in synthetic chemistry and chemical biology. Despite major advances, many synthetic strategies remain organized around individual targets...
Hierarchical Microporous Anion Pillared Metal-Organic Frameworks (APMOFs) for Gas Separation [0.03%]
分级微孔阴离子柱撑金属有机框架材料用于气体分离
Yunjia Jiang,Lingyao Wang,Yuanbin Zhang
Yunjia Jiang
ConspectusAs an emerging class of porous materials, metal-organic frameworks (MOFs) have attracted considerable interest for their designable structures and tailorable functionality. Among them, anion-pillared MOFs (APMOFs) represent an imp...
Arvind Sathyavageeswaran,Júlia Bonesso Sabadini,Sarah L Perry
Arvind Sathyavageeswaran
Published Erratum
Accounts of chemical research. 2026 Jul 22. DOI:10.1021/acs.accounts.6c00539 2026
Selectivity by the Clock: Programming Reactivity with Alternating Current Frequency [0.03%]
时钟选择性：使用交替电流频率进行反应性编程
Diptangshu Datta Mal,Nibedita Behara,Long Luo
Diptangshu Datta Mal
ConspectusElectrochemical reactions are inherently programmable through the applied potential. However, conventional direct current (DC) electrolysis provides only limited control over reaction selectivity because it generates a static redo...