Transition Metal-Catalyzed Regioselective Direct C-H Amidation: Interplay between Inner- and Outer-Sphere Pathways for Nitrene Cross-Coupling Reactions [0.03%]
过渡金属催化的区域选择性直接C-H氨化反应：氮烯交叉偶联反应中内球与外球路径的相互作用
Bingnan Du,Chun-Ming Chan,Chi-Ming Au et al.
Bingnan Du et al.
Catalytic C-N bond cross-coupling reactions have been a subject of fundamental importance in synthetic organic and medicinal chemistry because amides and amines are ubiquitous motifs in natural products, functional materials, and pharmaceut...
A New Paradigm in Pincer Iridium Chemistry: PCN Complexes for (De)Hydrogenation Catalysis and Beyond [0.03%]
用于(脱)氢化催化等的PCN配合物：夹心铱化学的新范式
Yulei Wang,Zhidao Huang,Guixia Liu et al.
Yulei Wang et al.
The discovery and development of organometallic catalysts is of paramount importance in modern organic synthesis, among which the ligand scaffolds play a crucial role in controlling the activity and selectivity. Over the past several decade...
Well-Ordered Nanonetwork Metamaterials from Block Copolymer Templated Syntheses [0.03%]
由嵌段共聚物模板合成的有序纳米网络型超材料
Kai-Chieh Yang,Puhup Puneet,Po-Ting Chiu et al.
Kai-Chieh Yang et al.
Through the morphological evolution to give highly optimized complex architectures at different length scales, fine-tuned textures for specific functions in living organisms can be achieved in nature such as a bone core with very complicate...
Persistent Radicals Derived from N-Heterocyclic Carbenes for Material Applications [0.03%]
基于N-杂环卡宾的持久自由基材料体系的研究进展与发展瓶颈
Hayoung Song,Ewa Pietrasiak,Eunsung Lee
Hayoung Song
Persistent radicals are potential building blocks of novel materials in many fields. Recently, highly stable persistent radicals are considered to be within reach, thanks to several radical stabilization strategies such as spin delocalizati...
Potential of Functionalized Polyolefins in a Sustainable Polymer Economy: Synthetic Strategies and Applications [0.03%]
功能化聚烯烃在可持续聚合物经济中的潜力：合成策略及应用
Lidia Jasinska-Walc,Miloud Bouyahyi,Rob Duchateau
Lidia Jasinska-Walc
Polymers play a crucial role in our modern life as no other material exists that is so versatile, moldable, and lightweight. Consequently, the demand for polymers will continue to grow with the human population, modernization, and technolog...
Biodegradability as an Off-Ramp for the Circular Economy: Investigations into Biodegradable Polymers for Home and Personal Care [0.03%]
可降解性作为循环经济的出路：家庭和个人护理用可降解聚合物的研究
Scott A Backer,Lyndsay Leal
Scott A Backer
Consumer pressure for globe-conscious products is pushing brand-owners big and small to provide transparency on the origin and fate of their ingredients. One such market where sustainable product growth has outpaced market growth is in home...
Chi Yao,Junhan Ou,Jianpu Tang et al.
Chi Yao et al.
Facing increasing demand for precision medicine, materials chemistry systems for bioanalysis with accurate molecular design, controllable structure, and adjustable biological activity are required. As a genetic biomacromolecule, deoxyribonu...
Nucleic Acids as a Playground for the Computational Study of the Photophysics and Photochemistry of Multichromophore Assemblies [0.03%]
核酸作为多发色团组装体光物理和光化学的计算研究游乐场
Lara Martínez Fernández,Fabrizio Santoro,Roberto Improta
Lara Martínez Fernández
The interaction between light and multichromophoric assemblies (MCAs) is the primary event of many fundamental processes, from photosynthesis to organic photovoltaics, and it triggers dynamical processes that share remarkable similarities a...
Guy Mann,Pradeep Sadhu,Ashraf Brik
Guy Mann
There is a continuous demand to improve our understanding of fundamental processes that underlie human health and disease. Therefore, novel strategies that can assist in these efforts are required. For example, molecular biology and genetic...
Chiral Amines via Enantioselective π-Allyliridium- C, O-Benzoate-Catalyzed Allylic Alkylation: Student Training via Industrial-Academic Collaboration [0.03%]
通过产学研合作培训学生进行亚胺基环丙烷铱-C,O-苯甲酸盐不对称π-烯丙基配合物的制备： allylic alkylation合成手性胺的方法
Craig E Stivala,Jason R Zbieg,Peng Liu et al.
Craig E Stivala et al.
Cyclometalated π-allyliridium-C,O-benzoate complexes discovered in the Krische laboratory display unique amphiphilic properties, catalyzing both nucleophilic carbonyl allylation and electrophilic allylation of diverse amines as well as nit...