Energy-Transfer-Enabled Dearomative Cycloaddition Reactions of Indoles/Pyrroles via Excited-State Aromatics [0.03%]
基于激发态芳香性的吲哚/吡咯类化合物去芳构化环加成反应研究：能量传递的作用
Min Zhu,Xiao Zhang,Chao Zheng et al.
Min Zhu et al.
Exploring the enormous chemical space through an expedient building-up of molecular diversity is an important goal of organic chemistry. The development of synthetic methods toward molecules with unprecedented structural motifs lays the fou...
Pilar Hoyos,Almudena Perona,Teodora Bavaro et al.
Pilar Hoyos et al.
Molecules containing carbohydrate moieties play essential roles in fighting a variety of bacterial and viral infections. Consequently, the design of new carbohydrate-containing drugs or vaccines has attracted great attention in recent years...
Environmental Biodegradation of Water-Soluble Polymers: Key Considerations and Ways Forward [0.03%]
水溶性高分子的环境生物降解：关键因素及发展方向
Michael Zumstein,Glauco Battagliarin,Andreas Kuenkel et al.
Michael Zumstein et al.
Water-soluble polymers (WSPs) have unique properties that are valuable in diverse applications ranging from home and personal care products to agricultural formulations. For applications that result in the release of WSPs into natural envir...
How Do Metalloproteins Tame the Fenton Reaction and Utilize •OH Radicals in Constructive Manners? [0.03%]
金属蛋白质如何驯服芬顿反应并以建设性的方式利用羟基自由基？
Binju Wang,Xuan Zhang,Wenhan Fang et al.
Binju Wang et al.
This Account describes the manner whereby nature controls the Fenton-type reaction of O-O homolysis of hydrogen peroxide and harnesses it to carry out various useful oxidative transformations in metalloenzymes. H2O2 acts as the cosubstrate ...
Seulki Kang,Ga-Hyun Kim,So-Jung Park
Seulki Kang
Conjugated polymers have been actively studied as an alternative to inorganic semiconductors for their unique optical and electrical properties and low-cost solution processability. However, typical conjugated polymer films contain numerous...
Achmatowicz Rearrangement-Inspired Development of Green Chemistry, Organic Methodology, and Total Synthesis of Natural Products [0.03%]
阿奇马托维奇重排反应在绿色化学、有机方法学和天然产物全合成中的启发式发展研究
Lixin Liang,Lian-Dong Guo,Rongbiao Tong
Lixin Liang
The six-membered heterocycles containing oxygen and nitrogen (tetrahydropyrans, pyrans, piperidines) are among the most common heterocyclic structures ubiquitously present in bioactive molecules such as carbohydrates, small-molecule drugs, ...
Supramolecular Organic Frameworks: Exploring Water-Soluble, Regular Nanopores for Biomedical Applications [0.03%]
超分子有机框架：用于生物医学应用的水溶性规则纳米孔的研究
Zhan-Ting Li,Shang-Bo Yu,Yamin Liu et al.
Zhan-Ting Li et al.
In past decades, regular porous architectures have received a great amount of attention because of their versatile functions and applications derived from their efficient adsorption of various guests. However, most reported porous architect...
Lighting Up Nucleic Acid Modifications in Single Cells with DNA-Encoded Amplification [0.03%]
利用DNA编码扩增技术在单细胞水平上点亮核苷酸修饰
Feng Chen,Jing Xue,Min Bai et al.
Feng Chen et al.
Nucleic acids are naturally decorated with various chemical modifications at nucleobases. Most nucleic acid modifications (NAMs) do not alter Watson-Crick base pairing but can regulate gene expression known as "epigenetics". Their abundance...
Ke Li,Jian Yang,Jinlou Gu
Ke Li
The past few decades have been witnessing the rapid research boom of metal-organic frameworks (MOFs), which are assembled from metal nodes and multitopic organic linkers. In virtue of their modular assembly mode, they can be tailored accord...
Deconstructive Synthesis of Bridged and Fused Rings via Transition-Metal-Catalyzed "Cut-and-Sew" Reactions of Benzocyclobutenones and Cyclobutanones [0.03%]
通过过渡金属催化的苯并环丁酮和环丁酮的“裁剪缝合”反应构建螺环和稠环化合物
Yibin Xue,Guangbin Dong
Yibin Xue
Bridged and fused rings are commonly found in biologically important molecules. Current tactics to construct these ring systems are primarily based on stepwise ring formation (i.e., making one ring first followed by making another) and cycl...