Underscoring Covalent-Organic Frameworks As Nanoengines for Zinc Anode Protection Coating [0.03%]
共价有机框架作为锌负极保护涂层的纳米发动机的研究
Can Guo,Pan Xue,Fengxue Duan et al.
Can Guo et al.
ConspectusRechargeable aqueous zinc-ion batteries (AZIBs) have emerged as promising energy storage systems owing to their high energy density, environmental benignity, and low cost. Nevertheless, the rough surface of the Zn metal anode can ...
Yi-Qi Zhang,Jonas Björk,Johannes V Barth
Yi-Qi Zhang
ConspectusBottom-up approaches combining tailor-made molecular precursors and surface-mediated reactions under ultrahigh-vacuum (UHV) conditions attracted significant attention over the past decade as a promising strategy for synthesizing n...
Gino Occhialini,Alison E Wendlandt
Gino Occhialini
ConspectusThe selective formation of one stereoisomer over another is a long-standing challenge in organic chemistry. Conventionally, the configuration of a stereogenic center is defined during bond forming molecular assembly steps and ther...
Yinyin Wang,Jie Ding,Chenliang Su et al.
Yinyin Wang et al.
ConspectusSingle-atom catalysts (SACs) represent a revolutionary paradigm in heterogeneous catalysis and display exceptional atom utilization efficiency with well-defined active sites. These distinctive characteristics position SACs as pivo...
Ona Ambrozaite,Reynolds Dziobek-Garrett,Thomas J Kempa
Ona Ambrozaite
ConspectusTwo-dimensional (2D) crystals have had a sweeping influence on the condensed matter physics and materials science communities for over two decades. Their thinness and ability to be configured into layered and twisted heterostructu...
Induced-Fit Chiral N-Heterocyclic Carbene Ligands for Asymmetric Catalysis [0.03%]
用于不对称催化的诱导拟合手性N-杂环卡宾配体
Zi-Chao Wang,Shi-Liang Shi
Zi-Chao Wang
ConspectusAsymmetric transition-metal catalysis stands as a cornerstone in the construction of molecules with stereogenic centers, profoundly impacting modern organic synthesis. Over the past decades, catalytic asymmetric synthesis has witn...
Quantum Tunneling of Photogenerated Charges for Artificial Photosynthesis [0.03%]
用于人工光合成的光生电荷量子隧穿效应
Ying Wang,Shuowen Wang,Xianzhi Fu et al.
Ying Wang et al.
ConspectusPhotocatalytic conversion of CO2 and H2O to high-value chemicals or fuels provides a crucial pathway for efficiently achieving the conversion and storage of solar-to-chemical energy; however, the overall efficiency is severely res...
Primary Amine-Based Photoclick Chemistry: From Concept to Diverse Applications in Chemical Biology and Medicinal Chemistry [0.03%]
基于 primary amine 的光点击化学：从概念到化学生物学及药物化学的多样化应用
Hao Hu,Hui-Jun Nie,Xiao-Hua Chen
Hao Hu
ConspectusClick chemistry has significantly impacted many fields. The emergence of photoclick chemistry, which harnesses light-driven processes under mild conditions, has introduced distinct advantages, including precise spatiotemporal cont...
Selective Oxidation of Disparate Functional Groups Mediated by a Common Aspartic Acid-Based Peptide Catalyst Platform [0.03%]
一种基于天冬氨酸的肽催化剂体系实现不同基团的选择性氧化反应
Susannah E Huth,Elizabeth A Stone,Scott J Miller
Susannah E Huth
ConspectusAs drug molecules become increasingly complex, the need to develop new or improved strategies for the efficient and selective synthesis and editing of bioactive compounds grows. Inspired by the high selectivity and fast rates exhi...
Water-Enhanced Catalysis: A Broadly Applicable Strategy for Promoting Reactivity and Selectivity in Diverse Chemical Reactions [0.03%]
增水催化的普适策略促进多种化学反应的活性及选择性增强
Soo Bok Kim,Byeong Jun Koo,Sun Bu Lee et al.
Soo Bok Kim et al.
ConspectusWater, an environmentally friendly and benign reaction medium, has traditionally been underestimated for its use in organic synthesis because it offers limited substrate solubility and can lead to undesired side reactions. However...