Wensheng Fang,Mingzhi Wang,Lebin Cai et al.
Wensheng Fang et al.
ConspectusGlobal energy's continuous reliance on fossil fuels has driven unprecedented CO2 emission growth, intensifying climate volatility through heightened frequency and severity of extreme weather events. These crises underscore the cri...
Patrick Tseng,Mia L Huang
Patrick Tseng
ConspectusGlycans are now recognized as essential biomolecules for life, and an increasing number of investigators and studies continue to reveal the myriad ways in which these post-translational modifications regulate important biological ...
Microenvironment Engineering of Mesoporous Metals for Ammonia Electrosynthesis from Nitrate: Advances, Mechanisms, and Prospects [0.03%]
介孔金属微环境工程在硝酸盐电还原制氨中的研究进展、机制及展望
Lizhi Sun,Ben Liu
Lizhi Sun
ConspectusElectrocatalytic nitrate reduction to ammonia (NO3--to-NH3) offers a promising pathway to convert NO3- wastewater to high-value-added NH3 under ambient conditions with renewable electricity. The design of robust electrocatalysts t...
Direct Reductive Transformation of Amides: From Methodology Development to Applications in Total Synthesis [0.03%]
酰胺的直接还原转化：从方法学研究到全合成中的应用
Wei Ou,Pei-Qiang Huang
Wei Ou
ConspectusEfficiency, selectivity, versatility, and practicality are major goals in current organic synthesis. Carboxamides are among the most prevalent and versatile functional groups in organic and medicinal chemistry, prominently feature...
Tan-Hao Shi,Qing-Hui Guo,Shuo Tong et al.
Tan-Hao Shi et al.
ConspectusSince Heilbronner proposed cyclacenes as hypothetical molecules in 1954, zigzag hydrocarbon belts and their heteroatom-doped analogs have captivated chemists and materials scientists with their aesthetically appealing structures, ...
Glycosyl ortho-(1-Phenylvinyl)benzoates as Donors for Streamlined One-Pot Assembly of Carbohydrates from Oligosaccharides to Polysaccharides [0.03%]
用于从寡糖到多糖的单锅组装的糖基邻位-(1-苯基乙烯基)苯甲酸酯
Guozhi Xiao
Guozhi Xiao
ConspectusCarbohydrates are essential and the most abundant biomolecules, with pivotal roles in numerous biological processes. However, in comparison with proteins and DNA, the biosynthesis of carbohydrates is not a template-driven process ...
Novel Mannich-Type Multicomponent Reactions: Discovery, Mechanism, and Application [0.03%]
新型曼尼希型多组分反应：发现、机理及应用
Xianjing Zhou,Zhencheng Lai,Jiaming Li et al.
Xianjing Zhou et al.
ConspectusThe development of efficient multicomponent reactions (MCRs) represents a vital frontier for the rapid construction of structurally sophisticated molecules from simple precursors in an atom- and step-economic manner. In particular...
The Role of Anions in Guanidinium-Catalyzed Chiral Cation Ion Pair Catalysis [0.03%]
阴离子在胍催化的手性阳离子离子对催化的中的作用
Wentao Wu,Chu Liu,Choon-Hong Tan et al.
Wentao Wu et al.
ConspectusCatalysts drive asymmetric transformations by orchestrating a network of covalent and noncovalent interactions that precisely regulate the reactivity and stereoselectivity. Ion pair catalysis, developed based on the inherent stren...
Yingying Ning,Eman A Akam-Baxter,Peter Caravan
Yingying Ning
ConspectusCarbonyl-ligation reactions are considered to be largely bioorthogonal due to the rarity of ketones and aldehydes in normal mammalian biology, especially in the extracellular space. However, during development, in wound healing, o...
Isaiah W Gilley,Taylor E Wiggins,Edward H Sargent et al.
Isaiah W Gilley et al.
ConspectusFollowing the development of perovskite solar cells, the synthesis of hybrid Pb, Sn, and Ge halides exploded in popularity, with more than 3000 such crystal structures uploaded to the Cambridge Structural Database since the start ...